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A. Loiseau

Bio: A. Loiseau is an academic researcher from Centre national de la recherche scientifique. The author has contributed to research in topics: Carbon nanotube & Medicine. The author has an hindex of 23, co-authored 38 publications receiving 10808 citations. Previous affiliations of A. Loiseau include Office National d'Études et de Recherches Aérospatiales & Free University of Berlin.


Papers
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Journal ArticleDOI
21 Aug 1997-Nature
TL;DR: In this article, it was shown that the growth mechanism for SWNTs must be independent of the details of the technique used to make them, and that the ready availability of large amounts of SWNT can make them much more accessible for further study.
Abstract: Single-walled carbon nanotubes (SWNTs) offer the prospect of both new fundamental science and useful (nano)technological applications1. High yields (70–90%) of SWNTs close-packed in bundles can be produced by laser ablation of carbon targets2. The electric-arc technique used to generate fullerenes and multi-walled nanotubes is cheaper and easier to implement, but previously has led to only low yields of SWNTs3,4. Here we show that this technique can generate large quantities of SWNTs with similar characteristics to those obtained by laser ablation. This suggests that the (still unknown) growth mechanism for SWNTs must be independent of the details of the technique used to make them. The ready availability of large amounts of SWNTs, meanwhile, should make them much more accessible for further study.

2,568 citations

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TL;DR: An overview of the key aspects of graphene and related materials, ranging from fundamental research challenges to a variety of applications in a large number of sectors, highlighting the steps necessary to take GRMs from a state of raw potential to a point where they might revolutionize multiple industries are provided.
Abstract: We present the science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems, targeting an evolution in technology, that might lead to impacts and benefits reaching into most areas of society. This roadmap was developed within the framework of the European Graphene Flagship and outlines the main targets and research areas as best understood at the start of this ambitious project. We provide an overview of the key aspects of graphene and related materials (GRMs), ranging from fundamental research challenges to a variety of applications in a large number of sectors, highlighting the steps necessary to take GRMs from a state of raw potential to a point where they might revolutionize multiple industries. We also define an extensive list of acronyms in an effort to standardize the nomenclature in this emerging field.

2,560 citations

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TL;DR: This chemistry is investigated using in situ Raman and transmission electron spectroscopies to highlight a thickness-dependent photoassisted oxidation reaction with oxygen dissolved in adsorbed water, consistent with a phenomenological model involving electron transfer and quantum confinement as key parameters.
Abstract: The degradation of exfoliated black phosphorus in ambient conditions may limit its use in electronic devices. The combined effects of light irradiation and exposure to oxygen on mono- and multilayers of this material are now investigated.

1,138 citations

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TL;DR: In this paper, a new route to the successful arc-discharge synthesis of pure boron nitride (BN) nanotubes is presented, where carbon-free plasma is established between the electrodes in a nitrogen atmosphere.
Abstract: A new route to the successful arc-discharge synthesis of pure boron nitride (BN) nanotubes is presented. The carbon-free plasma is established between ${\mathrm{HfB}}_{2}$ electrodes in a nitrogen atmosphere. This technique leads to the formation of BN nanotubes with very few layers including single- and double-layer tubes. Electron-energy-loss spectroscopy yields a B:N ratio of approximately 1. Most tube ends are closed by flat layers perpendicular to the tube axis. A closure by a triangular facet, resulting from three 120\ifmmode^\circ\else\textdegree\fi{} disclinations, is proposed to account for this specific shape.

719 citations

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TL;DR: In this article, the first magnetization measurements of individual ferromagnetic nanoparticles (15-30 nm) at very low temperatures (0.1-6 K) were presented.
Abstract: Presented are the first magnetization measurements of individual ferromagnetic nanoparticles (15--30 nm) at very low temperatures (0.1--6 K). The angular dependence of the hysteresis loop evidenced the single domain character of the particles. Waiting time, switching field, and telegraph noise measurements showed for the first time that the magnetization reversal of a well prepared ferromagnetic nanoparticle can be described by thermal activation over a single-energy barrier as originally proposed by N\'eel and Brown. The ``activation volume'' estimated by these measurements was close to the particle volume.

525 citations


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TL;DR: The state of the art, future directions and open questions in Raman spectroscopy of graphene are reviewed, and essential physical processes whose importance has only recently been recognized are described.
Abstract: Raman spectroscopy is an integral part of graphene research. It is used to determine the number and orientation of layers, the quality and types of edge, and the effects of perturbations, such as electric and magnetic fields, strain, doping, disorder and functional groups. This, in turn, provides insight into all sp(2)-bonded carbon allotropes, because graphene is their fundamental building block. Here we review the state of the art, future directions and open questions in Raman spectroscopy of graphene. We describe essential physical processes whose importance has only recently been recognized, such as the various types of resonance at play, and the role of quantum interference. We update all basic concepts and notations, and propose a terminology that is able to describe any result in literature. We finally highlight the potential of Raman spectroscopy for layered materials other than graphene.

5,673 citations

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TL;DR: A review of recent advances in carbon nanotubes and their composites can be found in this article, where the authors examine the research work reported in the literature on the structure and processing of carbon Nanotubes.

4,709 citations

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TL;DR: The unique advances on ultrathin 2D nanomaterials are introduced, followed by the description of their composition and crystal structures, and the assortments of their synthetic methods are summarized.
Abstract: Since the discovery of mechanically exfoliated graphene in 2004, research on ultrathin two-dimensional (2D) nanomaterials has grown exponentially in the fields of condensed matter physics, material science, chemistry, and nanotechnology. Highlighting their compelling physical, chemical, electronic, and optical properties, as well as their various potential applications, in this Review, we summarize the state-of-art progress on the ultrathin 2D nanomaterials with a particular emphasis on their recent advances. First, we introduce the unique advances on ultrathin 2D nanomaterials, followed by the description of their composition and crystal structures. The assortments of their synthetic methods are then summarized, including insights on their advantages and limitations, alongside some recommendations on suitable characterization techniques. We also discuss in detail the utilization of these ultrathin 2D nanomaterials for wide ranges of potential applications among the electronics/optoelectronics, electrocat...

3,628 citations

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TL;DR: Arc-synthesized single-walled carbon nanotubes have been purified through preparative electrophoresis in agarose gel and glass bead matrixes and promise to be interesting nanomaterials in their own right.
Abstract: Arc-synthesized single-walled carbon nanotubes have been purified through preparative electrophoresis in agarose gel and glass bead matrixes. Two major impurities were isolated: fluorescent carbon and short tubular carbon. Analysis of these two classes of impurities was done. The methods described may be readily extended to the separation of other water-soluble nanoparticles. The separated fluorescent carbon and short tubule carbon species promise to be interesting nanomaterials in their own right.

3,357 citations

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TL;DR: In this paper, a review of nitrogen-doped graphene is presented, including various synthesis methods to introduce N doping and various characterization techniques for the examination of various N bonding configurations.
Abstract: Nitrogen doping has been an effective way to tailor the properties of graphene and render its potential use for various applications. Three common bonding configurations are normally obtained when doping nitrogen into the graphene: pyridinic N, pyrrolic N, and graphitic N. This paper reviews nitrogen-doped graphene, including various synthesis methods to introduce N doping and various characterization techniques for the examination of various N bonding configurations. Potential applications of N-graphene are also reviewed on the basis of experimental and theoretical studies.

3,075 citations