Author
A.W. Webb
Bio: A.W. Webb is an academic researcher from United States Naval Research Laboratory. The author has contributed to research in topics: Magnetic susceptibility & Band gap. The author has an hindex of 3, co-authored 3 publications receiving 77 citations.
Topics: Magnetic susceptibility, Band gap
Papers
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TL;DR: In this paper, the effect of pressure on the energy gap E, was found to agree well with previous work, and the variations in dE dP reported in the literature were found to be an apparent result of sample orientation.
36 citations
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TL;DR: In this paper, four high pressure phases of silver mercury iodide, Ag 2 HgI 4, were studied to pressures of 75-100 kbar at 25°C.
26 citations
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TL;DR: A new member of the family ofemiconducting transition metal dichalcogenides, rhenium disulphide (ReS2), where such variation is absent and bulk behaves as electronically and vibrationally decoupled monolayers stacked together.
Abstract: Monolayers of transition metal dichalcogenides have emerged as interesting two-dimensional materials. Here, the authors show that in a new member of this family of compounds, rhenium disulphide, the layers in the bulk are vibrationally and electronically decoupled, so that they behave almost as monolayers.
907 citations
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TL;DR: The structural changes within the copper(I) halides induced by hydrostatic pressure have been investigated using the powder neutron-diffraction technique and the evolution of the structures of these I-VII compounds is very different from that observed in the more covalent II-VI and III-V systems.
Abstract: The structural changes within the copper(I) halides induced by hydrostatic pressure have been investigated using the powder neutron-diffraction technique. The expected transition from the ambient zinc-blende structure with tetrahedral coordination to the octahedrally coordinated rocksalt structure is observed in both CuCl and CuBr. No rocksalt phase is observed in CuI, presumably due to the limited maximum pressure of our apparatus (\ensuremath{\sim}10 GPa). The lower symmetry phases which occur as intermediate structures between the zinc-blende and rocksalt phases have been studied in detail. CuCl and CuI undergo abrupt transitions whilst CuBr has three sluggish transitions, involving extensive coexistence of neighboring phases. There is one intermediate phase in CuCl (CuCl-IV), two in CuBr (CuBr-IV and CuBr-V) and at least two in CuI (CuI-IV and CuI-V). Three different structure types have been identified, in space groups Pa3\ifmmode\bar\else\textasciimacron\fi{} (CuCl-IV and CuBr-V), P4/nmm (CuBr-IV and CuI-V) and R3\ifmmode\bar\else\textasciimacron\fi{}m (CuI-IV). The intermediate structures all retain the tetrahedral cation coordination of the ${\mathrm{Cu}}^{+}$, though the environment is rather more distorted in CuCl and CuBr than in CuI. The evolution of the structures of these I-VII compounds is very different from that observed in the more covalent II-VI and III-V systems.
157 citations
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155 citations
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TL;DR: In this article, it is shown that there is significant and unexplained disagreement between the value of the low temperature specific heat Debye temperature of NbSe2 and the value determined on the basis of the elastic constants, but that the model predictions of c33 and c44 are in satisfactory agreement with the values extracted from the neutron data for both MoS2, and NbSE2.
144 citations
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TL;DR: The barrier-free, row-by-row assembly of peptides on a MoS2 surface confirms a prediction of classical nucleation theory, and investigates nucleation of 2D arrays by molecularly resolved in situ atomic force microscopy and compared the results to molecular dynamics simulations.
Abstract: Assembly of two-dimensional (2D) molecular arrays on surfaces produces a wide range of architectural motifs exhibiting unique properties, but little attention has been given to the mechanism by which they nucleate. Using peptides selected for their binding affinity to molybdenum disulfide, we investigated nucleation of 2D arrays by molecularly resolved in situ atomic force microscopy and compared our results to molecular dynamics simulations. The arrays assembled one row at a time, and the nuclei were ordered from the earliest stages and formed without a free energy barrier or a critical size. The results verify long-standing but unproven predictions of classical nucleation theory in one dimension while revealing key interactions underlying 2D assembly.
141 citations