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A. Wahid Mesbah

Bio: A. Wahid Mesbah is an academic researcher from University of Marburg. The author has contributed to research in topics: Aldol condensation & Diethylamine. The author has an hindex of 10, co-authored 25 publications receiving 285 citations.

Papers
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Journal ArticleDOI
TL;DR: In this article, a thermodynamic equilibrium analysis of reforming of methane with carbon dioxide and in combination with steam reforming (mixed reforming) was performed using constrained Gibbs free energy minimization method and the results were compared with that of a commercial plant reactor and their experimental data over Ni/MgO catalysts tested in a fixed bed quartz reactor.

76 citations

Journal ArticleDOI
TL;DR: In this paper, the influence of calcination temperature (500, 600 and 700°C) on NiO-MgO solid solution formation and the performance of the resulting catalysts in CO2 reforming of methane was studied.
Abstract: The influence of calcination temperature (500, 600 and 700 °C) on NiO–MgO solid solution formation and the performance of the resulting catalysts in CO2 reforming of methane was studied. The solid solutions and resulting catalysts were characterized by Brunauer–Emmett–Teller, XRD, temperature-programmed reduction (TPR), TEM and thermal gravimetric analysis techniques. Catalytic performance tests were carried out under 550–750 °C, 1 bar, CO2/CH4 = 1–3 mol/mol and space velocities of 30,000–120,000 ml/(h gcat). The catalyst calcined at 600 °C exhibited the best performance in terms of catalytic activity and stability and showed lowest amount of coke formation after 50 h-on-stream. The effect of calcination temperature on degree of NiO–MgO solid solution formation was demonstrated by both XRD and TPR profiles. The 600 °C calcination temperature was found to be an optimum as it caused modest NiO–MgO interaction, which is responsible for complete formation of the NiO–MgO solid solution with high nickel dispersion and resistant to coke formation.

54 citations

Journal ArticleDOI
TL;DR: In this article, a series of NiO-MgO solid solution catalysts with different NiO contents (5, 10, 15 and 20 %) were prepared by one-pot sol-gel/evaporation method.

38 citations

Journal ArticleDOI
TL;DR: An aqueous medium containing catalytic amounts of a tertiary amine was employed to direct the chemoselectivity of the reaction of aldehydes with 1a to form syn/anti mixtures of 3 with the syn isomers being the major products.

30 citations

Journal ArticleDOI
TL;DR: A series of 2,4-disubstituted derivatives of 1,5-benzothiazepines were prepared via a one-pot thia-Michael cyclization sequence by the reaction of various 2-aminothiophenols with chalcones in ionic liquid media.

18 citations


Cited by
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10 Mar 1970

8,159 citations

Journal ArticleDOI
TL;DR: In this paper, a review provides a contemporary assessment of progresses recorded on synergistic interplay among catalyst components (active metals, support, promoters and binders) during dry reforming using state-of-the-art experimental and theoretical techniques.
Abstract: The abrupt and massive deactivation of methane dry reforming catalysts especially Ni-based is still a monumental impediment towards its industrialization and commercialization for production of value-added syngas via Fischer-Tropsch process. The need for further and more critical understanding of inherent and tailored interactions of catalyst components for performance and stability enhancement during reforming reaction cannot be over-emphasized. This review provides a contemporary assessment of progresses recorded on synergistic interplay among catalyst components (active metals, support, promoters and binders) during dry reforming using state-of-the-art experimental and theoretical techniques. Advancements achieved during interplay leading to improvements in properties of existing catalysts and discovery of novel ones were stated and expatiated. Reaction pathways, catalytic activities, selection of appropriate synthesis route and metal/support deactivation via sintering or carbon deposition have over time been successfully studied and explained using information from these crucial component interactions. This perspective describes the roles of these interactions and their applications towards development of robust catalysts configurations for successful industrial applications.

367 citations

01 Jan 2016
TL;DR: The ionic liquids in synthesis is universally compatible with any devices to read and is available in the book collection an online access to it is set as public so you can download it instantly.
Abstract: Thank you very much for reading ionic liquids in synthesis. Maybe you have knowledge that, people have search numerous times for their favorite books like this ionic liquids in synthesis, but end up in infectious downloads. Rather than enjoying a good book with a cup of coffee in the afternoon, instead they juggled with some infectious virus inside their laptop. ionic liquids in synthesis is available in our book collection an online access to it is set as public so you can download it instantly. Our books collection hosts in multiple countries, allowing you to get the most less latency time to download any of our books like this one. Merely said, the ionic liquids in synthesis is universally compatible with any devices to read.

350 citations

Journal ArticleDOI
TL;DR: In this paper, the authors summarize the recent advances in biogas dry reforming toward hydrogen production, including the preparation of catalysts, the optimization of operation conditions, and the influence of impurities in Biogas.

239 citations