Hydrogen storage alloys are of particular interest as a novel group in functional materials owing to their potential and practical applications in Ni/MH rechargeable batteries. This review is devoted to the specific alloy families developed for high-energy and high-power Ni/MH batteries in the last decades, especially for EV, HEV and PHEV applications. The scope of the work encompasses principles of Ni/MH batteries, electrochemical hydrogen storage thermodynamics and kinetics, prerequisites for hydrogen storage electrode alloys and recent advances in hydrogen storage electrode alloys. Rare earth AB5-type alloys, Ti- and Zr-based AB2-type alloys, Mg-based amorphous/nanocrystalline alloys, rare earth-Mg–Ni-based alloys and Ti–V-based alloys are highlighted. Additionally, the challenges met in developing advanced hydrogen storage alloys for Ni/MH rechargeable batteries are pointed out and some research directions are suggested.

Advanced hydrogen storage alloys for Ni/MH rechargeable batteries

Progress of hydrogen storage alloys for Ni-MH rechargeable power batteries in electric vehicles: A review

In this review article, the fundamentals of electrochemical reactions involving metal hydrides are explained, followed by a report of recent progress in hydrogen storage alloys for electrochemical applications. The status of various alloy systems, including AB₅, AB₂, A₂B₇-type, Ti-Ni-based, Mg-Ni-based, BCC, and Zr-Ni-based metal hydride alloys, for their most important electrochemical application, the nickel metal hydride battery, is summarized. Other electrochemical applications, such as Ni-hydrogen, fuel cell, Li-ion battery, air-metal hydride, and hybrid battery systems, also have been mentioned.

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A. Wu

Papers

Effects of aluminum substitution in C14-rich multi-component alloys for NiMH battery application

Optimization of Co-content in C14 Laves phase multi-component alloys for NiMH battery application