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Ajaya Kumar Singh

Bio: Ajaya Kumar Singh is an academic researcher from P.G. College. The author has contributed to research in topics: Reaction rate & Micelle. The author has an hindex of 20, co-authored 140 publications receiving 1803 citations. Previous affiliations of Ajaya Kumar Singh include Albert Einstein Institution & Allahabad University.


Papers
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Journal ArticleDOI
TL;DR: In this paper, the authors proposed a method to remove heavy metal ions in the wastewater, which is one of the most serious concerns of the world, in the pursuit of remedial action.
Abstract: Environmental pollution, particularly from heavy metal ions in the wastewater, is one of the most serious concerns of the world. In the pursuit of remedial action, various conventional methods such...

227 citations

Journal ArticleDOI
B. P. Abbott1, Richard J. Abbott1, T. D. Abbott2, Matthew Abernathy3  +978 moreInstitutions (112)
TL;DR: In this paper, the authors reported that the non-detection of gravitational waves from the merger of binary-neutron star systems and neutron star-black hole systems during the first observing run of the Advanced Laser Interferometer Gravitational-wave Observatory (LIGO).
Abstract: We report here the non-detection of gravitational waves from the merger of binary–neutron star systems and neutron star–black hole systems during the first observing run of the Advanced Laser Interferometer Gravitational-wave Observatory (LIGO). In particular, we searched for gravitational-wave signals from binary–neutron star systems with component masses $\in [1,3]\,{M}_{\odot }$ and component dimensionless spins <0.05. We also searched for neutron star–black hole systems with the same neutron star parameters, black hole mass $\in [2,99]\,{M}_{\odot }$, and no restriction on the black hole spin magnitude. We assess the sensitivity of the two LIGO detectors to these systems and find that they could have detected the merger of binary–neutron star systems with component mass distributions of 1.35 ± 0.13 M ⊙ at a volume-weighted average distance of ~70 Mpc, and for neutron star–black hole systems with neutron star masses of 1.4 M ⊙ and black hole masses of at least 5 M ⊙, a volume-weighted average distance of at least ~110 Mpc. From this we constrain with 90% confidence the merger rate to be less than 12,600 Gpc−3 yr−1 for binary–neutron star systems and less than 3600 Gpc−3 yr−1 for neutron star–black hole systems. We discuss the astrophysical implications of these results, which we find to be in conflict with only the most optimistic predictions. However, we find that if no detection of neutron star–binary mergers is made in the next two Advanced LIGO and Advanced Virgo observing runs we would place significant constraints on the merger rates. Finally, assuming a rate of ${10}_{-7}^{+20}$ Gpc−3 yr−1, short gamma-ray bursts beamed toward the Earth, and assuming that all short gamma-ray bursts have binary–neutron star (neutron star–black hole) progenitors, we can use our 90% confidence rate upper limits to constrain the beaming angle of the gamma-ray burst to be greater than $2\buildrel{\circ}\over{.} {3}_{-1.1}^{+1.7}$ ($4\buildrel{\circ}\over{.} {3}_{-1.9}^{+3.1}$).

222 citations

Journal ArticleDOI
TL;DR: In this paper, the authors present fundamental chemistry involved in various kinds of homogeneous Fenton reactions, which include classical Fenton, electro-Fenton, photo-fenton, sono-electro-Fentons, and solar photoelectron-fentons.
Abstract: Nowadays, the water ecosystem is being polluted due to the rapid industrialization and massive use of antibiotics, fertilizers, cosmetics, paints, and other chemicals. Chemical oxidation is one of the most applied processes to degrade contaminants in water. However, chemicals are often unable to completely mineralize the pollutants. Enhanced pollutant degradation can be achieved by Fenton reaction and related processes. As a consequence, Fenton reactions have received great attention in the treatment of domestic and industrial wastewater effluents. Currently, homogeneous and heterogeneous Fenton processes are being investigated intensively and optimized for applications, either alone or in a combination of other processes. This review presents fundamental chemistry involved in various kinds of homogeneous Fenton reactions, which include classical Fenton, electro-Fenton, photo-Fenton, electro-Fenton, sono-electro-Fenton, and solar photoelectron-Fenton. In the homogeneous Fenton reaction process, themolar ratio of iron(II) and hydrogen peroxide, and the pH usually determine the effectiveness of removing target pollutants and subsequently their mineralization, monitored by a decrease in levels of total organic carbon or chemical oxygen demand. We present catalysts used in heterogeneous Fenton or Fenton-like reactions, such as H2O2–Fe3+ (solid)/nano-zero-valent iron/immobilized iron and electro-Fenton-pyrite. Surface properties of heterogeneous catalysts generally control the efficiency to degrade pollutants. Examples of Fenton reactions are demonstrated to degrade and mineralize a wide range of water pollutants in real industrial wastewaters, such as dyes and phenols. Removal of various antibiotics by homogeneous and heterogeneous Fenton reactions is exemplified

218 citations

Journal ArticleDOI
TL;DR: In this article, the authors reported the non-detection of gravitational waves from the merger of binary neutron star systems and neutron-star-black-hole systems during the first observing run of Advanced LIGO.
Abstract: We report here the non-detection of gravitational waves from the merger of binary neutron star systems and neutron-star--black-hole systems during the first observing run of Advanced LIGO. In particular we searched for gravitational wave signals from binary neutron star systems with component masses $\in [1,3] M_{\odot}$ and component dimensionless spins $< 0.05$. We also searched for neutron-star--black-hole systems with the same neutron star parameters, black hole mass $\in [2,99] M_{\odot}$ and no restriction on the black hole spin magnitude. We assess the sensitivity of the two LIGO detectors to these systems, and find that they could have detected the merger of binary neutron star systems with component mass distributions of $1.35\pm0.13 M_{\odot}$ at a volume-weighted average distance of $\sim$ 70Mpc, and for neutron-star--black-hole systems with neutron star masses of $1.4M_\odot$ and black hole masses of at least $5M_\odot$, a volume-weighted average distance of at least $\sim$ 110Mpc. From this we constrain with 90% confidence the merger rate to be less than 12,600 Gpc$^{-3}$yr$^{-1}$ for binary-neutron star systems and less than 3,600 Gpc$^{-3}$yr$^{-1}$ for neutron-star--black-hole systems. We find that if no detection of neutron-star binary mergers is made in the next two Advanced LIGO and Advanced Virgo observing runs we would place significant constraints on the merger rates. Finally, assuming a rate of $10^{+20}_{-7}$Gpc$^{-3}$yr$^{-1}$ short gamma ray bursts beamed towards the Earth and assuming that all short gamma-ray bursts have binary-neutron-star (neutron-star--black-hole) progenitors we can use our 90% confidence rate upper limits to constrain the beaming angle of the gamma-ray burst to be greater than ${2.3^{+1.7}_{-1.1}}^{\circ}$ (${4.3^{+3.1}_{-1.9}}^{\circ}$).

161 citations

Journal ArticleDOI
TL;DR: New magnetic iron oxide (Fe3O4)/activated charcoal (AC)/β-cyclodextrin (CD)/sodium alginate (Alg) polymer nanocomposite materials were prepared by direct mixing of the polymer matrix with the nanofillers and showed excellent regeneration capacity.
Abstract: New magnetic iron oxide (Fe3O4)/activated charcoal (AC)/β-cyclodextrin (CD)/sodium alginate (Alg) polymer nanocomposite materials were prepared by direct mixing of the polymer matrix with the nanofillers. The obtained materials were utilized as nano-adsorbents for the elimination of methylene blue (MB), a hazardous water-soluble cationic dye, from aqueous solutions, and showed excellent regeneration capacity. The formation of the nanocomposites was followed by high-resolution transmission electron microscopy (HRTEM), scanning electron microscopy (SEM) equipped with energy dispersive X-ray spectrometry (EDX), Fourier-transform infrared spectroscopy (FTIR), vibrating sample magnetometer (VSM), X-ray diffraction (XRD) and adsorption of N2 at -196 °C. The rate of adsorption was investigated varying several factors, namely contact time, pH, amount of adsorbent and MB concentration on the adsorption process. Studies dealing with equilibrium and kinetics were carried out in batch conditions. The obtained results indicated that the removal rate of MB was 99.53% in 90 min. Langmuir's isotherm fitted better to the equilibrium data of MB. Fe3O4/AC/CD/Alg polymer beads shows amazing adsorption capacities in the elimination of cationic dyes (2.079 mg/g for polymer gel beads and 10.63 mg g-1 for dry powder beads), in comparison to other adsorbent materials. The obtained adsorbent is spherical with hydrophobic cross-linked surface properties that enable an easy recovery without any significant weight loss of in the adsorbent used.

109 citations


Cited by
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Journal ArticleDOI
B. P. Abbott1, Richard J. Abbott1, T. D. Abbott2, Fausto Acernese3  +1131 moreInstitutions (123)
TL;DR: The association of GRB 170817A, detected by Fermi-GBM 1.7 s after the coalescence, corroborates the hypothesis of a neutron star merger and provides the first direct evidence of a link between these mergers and short γ-ray bursts.
Abstract: On August 17, 2017 at 12∶41:04 UTC the Advanced LIGO and Advanced Virgo gravitational-wave detectors made their first observation of a binary neutron star inspiral. The signal, GW170817, was detected with a combined signal-to-noise ratio of 32.4 and a false-alarm-rate estimate of less than one per 8.0×10^{4} years. We infer the component masses of the binary to be between 0.86 and 2.26 M_{⊙}, in agreement with masses of known neutron stars. Restricting the component spins to the range inferred in binary neutron stars, we find the component masses to be in the range 1.17-1.60 M_{⊙}, with the total mass of the system 2.74_{-0.01}^{+0.04}M_{⊙}. The source was localized within a sky region of 28 deg^{2} (90% probability) and had a luminosity distance of 40_{-14}^{+8} Mpc, the closest and most precisely localized gravitational-wave signal yet. The association with the γ-ray burst GRB 170817A, detected by Fermi-GBM 1.7 s after the coalescence, corroborates the hypothesis of a neutron star merger and provides the first direct evidence of a link between these mergers and short γ-ray bursts. Subsequent identification of transient counterparts across the electromagnetic spectrum in the same location further supports the interpretation of this event as a neutron star merger. This unprecedented joint gravitational and electromagnetic observation provides insight into astrophysics, dense matter, gravitation, and cosmology.

7,327 citations

Journal Article
TL;DR: The first direct detection of gravitational waves and the first observation of a binary black hole merger were reported in this paper, with a false alarm rate estimated to be less than 1 event per 203,000 years, equivalent to a significance greater than 5.1σ.
Abstract: On September 14, 2015 at 09:50:45 UTC the two detectors of the Laser Interferometer Gravitational-Wave Observatory simultaneously observed a transient gravitational-wave signal. The signal sweeps upwards in frequency from 35 to 250 Hz with a peak gravitational-wave strain of 1.0×10(-21). It matches the waveform predicted by general relativity for the inspiral and merger of a pair of black holes and the ringdown of the resulting single black hole. The signal was observed with a matched-filter signal-to-noise ratio of 24 and a false alarm rate estimated to be less than 1 event per 203,000 years, equivalent to a significance greater than 5.1σ. The source lies at a luminosity distance of 410(-180)(+160) Mpc corresponding to a redshift z=0.09(-0.04)(+0.03). In the source frame, the initial black hole masses are 36(-4)(+5)M⊙ and 29(-4)(+4)M⊙, and the final black hole mass is 62(-4)(+4)M⊙, with 3.0(-0.5)(+0.5)M⊙c(2) radiated in gravitational waves. All uncertainties define 90% credible intervals. These observations demonstrate the existence of binary stellar-mass black hole systems. This is the first direct detection of gravitational waves and the first observation of a binary black hole merger.

4,375 citations

Journal ArticleDOI
B. P. Abbott1, Richard J. Abbott, T. D. Abbott, Sheelu Abraham  +1145 moreInstitutions (8)
TL;DR: In this paper, the authors presented the results from three gravitational-wave searches for coalescing compact binaries with component masses above 1 Ma during the first and second observing runs of the advanced GW detector network.
Abstract: We present the results from three gravitational-wave searches for coalescing compact binaries with component masses above 1 Ma™ during the first and second observing runs of the advanced gravitational-wave detector network. During the first observing run (O1), from September 12, 2015 to January 19, 2016, gravitational waves from three binary black hole mergers were detected. The second observing run (O2), which ran from November 30, 2016 to August 25, 2017, saw the first detection of gravitational waves from a binary neutron star inspiral, in addition to the observation of gravitational waves from a total of seven binary black hole mergers, four of which we report here for the first time: GW170729, GW170809, GW170818, and GW170823. For all significant gravitational-wave events, we provide estimates of the source properties. The detected binary black holes have total masses between 18.6-0.7+3.2 Mâ™ and 84.4-11.1+15.8 Mâ™ and range in distance between 320-110+120 and 2840-1360+1400 Mpc. No neutron star-black hole mergers were detected. In addition to highly significant gravitational-wave events, we also provide a list of marginal event candidates with an estimated false-alarm rate less than 1 per 30 days. From these results over the first two observing runs, which include approximately one gravitational-wave detection per 15 days of data searched, we infer merger rates at the 90% confidence intervals of 110-3840 Gpc-3 y-1 for binary neutron stars and 9.7-101 Gpc-3 y-1 for binary black holes assuming fixed population distributions and determine a neutron star-black hole merger rate 90% upper limit of 610 Gpc-3 y-1.

2,336 citations

01 Jan 2016

1,664 citations

Posted Content
TL;DR: The two-step solution-phase reactions to form hybrid materials of Mn(3)O(4) nanoparticles on reduced graphene oxide (RGO) sheets for lithium ion battery applications should offer a new technique for the design and synthesis of battery electrodes based on highly insulating materials.
Abstract: We developed two-step solution-phase reactions to form hybrid materials of Mn3O4 nanoparticles on reduced graphene oxide (RGO) sheets for lithium ion battery applications. Mn3O4 nanoparticles grown selectively on RGO sheets over free particle growth in solution allowed for the electrically insulating Mn3O4 nanoparticles wired up to a current collector through the underlying conducting graphene network. The Mn3O4 nanoparticles formed on RGO show a high specific capacity up to ~900mAh/g near its theoretical capacity with good rate capability and cycling stability, owing to the intimate interactions between the graphene substrates and the Mn3O4 nanoparticles grown atop. The Mn3O4/RGO hybrid could be a promising candidate material for high-capacity, low-cost, and environmentally friendly anode for lithium ion batteries. Our growth-on-graphene approach should offer a new technique for design and synthesis of battery electrodes based on highly insulating materials.

1,587 citations