Author
Akira Kinbara
Bio: Akira Kinbara is an academic researcher from University of Tokyo. The author has contributed to research in topics: Thin film & Sputtering. The author has an hindex of 26, co-authored 116 publications receiving 2211 citations.
Topics: Thin film, Sputtering, Adhesion, Carbon film, Amorphous solid
Papers published on a yearly basis
Papers
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TL;DR: In this article, an attempt was made to derive thermodynamic quantities which characterize the initial stages of film growth using reflection high energy electron diffraction, and critical temperatures for the appearance of superstructures were determined for Si(111) surfaces which were bombarded with constant-flux molecular beams of indium (J = (0.05−3.5) × 10-2 monolayers s-1).
18 citations
TL;DR: In this paper, a phase diagram of superstructures of submonolayer lead films on Si(111) surface was established using reflection high energy electron diffraction (RHEED) and molecular beam deposition.
17 citations
TL;DR: In this article, the electrical resistivities of thin bismuth films, either in step-up series or a fixed thickness, were measured between 4.2 and 320 K. This scatter became more pronounced with decreasing temperature and it was due to the variation of the TCR above liquid nitrogen temperature.
17 citations
TL;DR: In this paper, the effect of the substrate temperature and ion bombardment on the adhesion of metal and compound films has been investigated and the correlation between these quantities is discussed and the results on internal stress and Young's modulus were determined by simultaneous in situ measurements during film deposition.
16 citations
TL;DR: In this article, a diamond stylus was used to scratch thin films on glass substrates and the effect of the stylus hardness and the film thickness on adhesion measurement was discussed.
16 citations
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02 Feb 2004TL;DR: The role of stress in mass transport is discussed in this article, where the authors consider anisotropic and patterned films, buckling, bulging, peeling and fracture.
Abstract: 1. Introduction and overview 2. Film stress and substrate curvature 3. Stress in anisotropic and patterned films 4. Delamination and fracture 5. Film buckling, bulging and peeling 6. Dislocation formation in epitaxial systems 7. Dislocation interactions and strain relaxation 8. Equilibrium and stability of surfaces 9. The role of stress in mass transport.
1,562 citations
TL;DR: In this article, the metastable phase anatase has been shown to have a wider optical absorption gap than rutile thin films, which is consistent with the high mobility, bandlike conduction observed in anatase crystals.
Abstract: Electrical and optical spectroscopic studies of TiO2 anatase thin filmsdeposited by sputtering show that the metastable phase anatase differs in electronic properties from the well‐known, stable phase rutile. Resistivity and Hall‐effect measurements reveal an insulator–metal transition in a donor band in anatase thin films with high donor concentrations. Such a transition is not observed in rutile thin films with similar donor concentrations. This indicates a larger effective Bohr radius of donor electrons in anatase than in rutile, which in turn suggests a smaller electron effective mass in anatase. The smaller effective mass in anatase is consistent with the high mobility, bandlike conduction observed in anatase crystals. It is also responsible for the very shallow donor energies in anatase. Luminescence of self‐trapped excitons is observed in anatase thin films, which implies a strong lattice relaxation and a small exciton bandwidth in anatase. Optical absorption and photoconductivity spectra show that anatase thin films have a wider optical absorption gap than rutile thin films.
1,560 citations
TL;DR: In this paper, a statistical growth model based on the Central Limit Theorem has been formulated for liquid-like coalescence of particles; this theory accounts satisfactorily for all the data, as well as for most size distributions published in the literature.
Abstract: In this paper we present a novel and versatile t e c h n i q u e f o r t h e p r o d u c t i o n o f u l t r a f i n e m e t a l p a r t i c l e s by evaporation from a temperature‐regulated oven containing a reduced atmosphere of an inert gas. An extensive investigation of particles of oxidized Al, with diameters of 3 to 6 nm, has been performed. We have also studied ultrafine particles of Mg,Zn, and Sn produced in the same manner. A supplementing investigation has been carried out for particles of Cr, Fe, Co, Ni, Cu, and Ga, as well as larger Al particles, produced by ’’conventional’’ inert‐gas evaporation from a resistive filament. Diameter as a function of evaporation rate, inert‐gas pressure, and the kind of inert gas are reported. Crystalline particles smaller than 20 nm look almost spherical in the electron microscope, while larger ones often display pronounced crystal habit. S i z e d i s t r i b u t i o n s have been investigated in detail, and consistently the logarithm of the particle diameter has a Gaussian distribution to a high precision for the smallest sizes, whereas larger particles deviate from such a simple behavior. A statistical growth model, based on the Central Limit Theorem, has been formulated for liquidlike coalescence of particles; this theory accounts satisfactorily for all our data, as well as for most size distributions published in the literature. Applications of the model to colloids, discontinuous films, and supported catalysts are discussed. By comparing size distributions for particles produced by a variety of techniques we found a number of empirical rules for the width of the distributions, as defined by a (geometric) standard deviation σ. For crystalline inert‐gas‐ evaporated particles we obtained consistently 1.36?σ?1.60; for coalescing islands in discontinuous films we found 1.22?σ?1.34; and similar rules are applicable to colloids, supported catalysts, and to ultrafine droplets.
1,483 citations
TL;DR: In this article, the authors developed a surface-enhanced Raman scattering (SERS) model of adsorbates on metal surfaces, where the long-range enhancement by resonances of the macroscopic laser and Stokes field is separated quantitatively from the metal electron-mediated resonance Raman effect.
Abstract: On the basis of different types of experiments, the authors develop implicitly the model of surface-enhanced Raman scattering (SERS) of adsorbates on metal surfaces. The long-range enhancement by resonances of the macroscopic laser and Stokes field is separated quantitatively from the metal electron-mediated resonance Raman effect. The latter mechanism proceeds by increased electron-photon coupling at an atomically rough surface and by temporary charge transfer to orbitals of the adsorbates. This model can account for the chemical specificity and vibrational selectivity of SERS and (partly) for the SERS specificity of the various metals.
1,312 citations
TL;DR: In this article, the basic physics and applications of planar metamaterials, often called metasurfaces, which are composed of optically thin and densely packed planar arrays of resonant or nearly resonant subwavelength elements, are reviewed.
1,047 citations