Author
Alain Turck
Other affiliations: Institut national des sciences appliquées de Rouen, Centre national de la recherche scientifique, University of Rouen
Bio: Alain Turck is an academic researcher from Intelligence and National Security Alliance. The author has contributed to research in topics: Metalation & Regioselectivity. The author has an hindex of 22, co-authored 94 publications receiving 1393 citations. Previous affiliations of Alain Turck include Institut national des sciences appliquées de Rouen & Centre national de la recherche scientifique.
Topics: Metalation, Regioselectivity, Electrophile, Diazine, Pyridine
Papers published on a yearly basis
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176 citations
79 citations
TL;DR: Using Pd-catalyzed Stille cross-coupling reactions, the authors reported the synthesis of various mono- or bis(tri-n-butylstannyl)diazines which were reacted with various halogenated diazines to access to various polyaza heterocyclic derivatives.
58 citations
TL;DR: In this paper, the synthesis of symmetrical polyaromatic compounds with pyridine or diazine units has been achieved by homocoupling of aryl halides with Pd(OAc)2 as catalyst.
48 citations
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TL;DR: This review concludes that Etherification without Cyclization and N-Alkylation should be considered as separate science, and the proposed treatment of Etherification with Cyclization as a separate science should be reconsidered.
Abstract: 10. Patented Literature 2616 10.1. Esterification 2616 10.2. Ether Formation 2619 10.2.1. Etherification without Cyclization 2619 10.2.2. Etherification with Cyclization 2624 10.3. N-Alkylation 2625 10.4. Other Reactions 2627 11. Summary and Outlook 2628 12. Note Added in Proof 2628 13. Abbreviations Used in This Review 2629 14. Acknowledgments 2629 15. Supporting Information Available 2630 16. References 2630
909 citations
TL;DR: The method allows for consecutive cross-coupling processes in one pot, as exemplified by the efficient preparation of compound 12, and has been applied to the first synthesis of the cytotoxic marine natural product montipyridine 8.
Abstract: Simple iron salts such as FeCln, Fe(acac)n (n = 2,3) or the salen complex 4 turned out to be highly efficient, cheap, toxicologically benign, and environmentally friendly precatalysts for a host of cross-coupling reactions of alkyl or aryl Grignard reagents, zincates, or organomanganese species with aryl and heteroaryl chlorides, triflates, and even tosylates. An “inorganic Grignard reagent” of the formal composition [Fe(MgX)2] prepared in situ likely constitutes the propagating species responsible for the catalytic turnover, which occurs in many cases at an unprecedented rate even at or below room temperature. Because of the exceptionally mild reaction conditions, a series of functional groups such as esters, ethers, nitriles, sulfonates, sulfonamides, thioethers, acetals, alkynes, and −CF3 groups are compatible. The method also allows for consecutive cross-coupling processes in one pot, as exemplified by the efficient preparation of compound 12, and has been applied to the first synthesis of the cytotox...
664 citations