Author
Alan K. Burnham
Other affiliations: University of California, Lawrence Livermore National Laboratory
Bio: Alan K. Burnham is an academic researcher from Stanford University. The author has contributed to research in topics: Oil shale & Kerogen. The author has an hindex of 51, co-authored 217 publications receiving 15531 citations. Previous affiliations of Alan K. Burnham include University of California & Lawrence Livermore National Laboratory.
Papers published on a yearly basis
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TL;DR: In this article, the authors have developed recommendations for reliable evaluation of kinetic parameters (the activation energy, the preexponential factor, and the reaction model) from the data obtained by means of thermal analysis methods such as TGA, differential scanning calorimetry (DSC), and differential thermal analysis (DTA).
4,112 citations
TL;DR: In this article, a simplified version of a vitrinite maturation model, called EASY%R[o], was presented, which uses an Arrhenius first-order parallel-reaction approach with a distribution of activation energies.
Abstract: We present a simplified version of a vitrinite maturation model, complete with sample spreadsheet, based on changes in vitrinite composition with time and temperature. The simplified model, called EASY%R[o], uses an Arrhenius first-order parallel-reaction approach with a distribution of activation energies. EASY%R[o] has been calibrated to a more rigorous model of vitrinite maturation based on the chemical properties of coal vitrinite. With EASY%R[o], a profile of vitrinite reflectance vs. time can be obtained for a given stratigraphic level if the time-temperature history for that level has been estimated. When applied to multiple stratigraphic levels, EASY%R[o] can be used to compute profiles of the percent of vitrinite reflectance with depth for comparison with borehol data and to optimize thermal history models. EASY%R[o] can be used for vitrinite reflectance values of 0.3 to 4.5%, and for heating rates ranging from those in the laboratory (1 degree C/week) to those in slowly subsiding geologic basins (1 degree C/10 m.y.). Examples of model applications range from sedimentary rocks heated by an igneous intrusion to a variety of burial histories. Vitrinite maturation predicted by EASY%Ro is compared to other methods currently being used, such as the Lopatin time-temperature index, level of organic maturity, and other approaches using a single activation energy. Our model successfully estimates vitrinite reflectance due to thermal metamorphism of sedimentary rocks heated by igneous intrusions, geothermal fluids, and burial in a variety of basin setting .
1,639 citations
TL;DR: The results of the ICTAC Kinetics Project as mentioned in this paper have been used to forecast the tendencies for the future development of solid state kinetics, as well as the findings of the participants are compared.
794 citations
TL;DR: In this article, a chemical kinetic model is presented that uses Arrhenius rate constants to calculate vitrinite elemental composition as a function of time and temperature, which is valid for %Ro values from slightly less than 0.3 to slightly greater than 4.4.
596 citations
TL;DR: In this article, a variety of global kinetic models are reviewed, including first-order, nth-order and sequential models as well as models having Gaussian, Weibull, and discrete activation-energy distributions.
Abstract: A variety of global kinetic models are reviewed, including first-order, nth-order, nucleation, and sequential models as well as models having Gaussian, Weibull, and discrete activation-energy distributions. The important characteristics of these various models are outlined, with guidance in how to select the correct model. Some of the models have similar characteristics, and the parameter relationships among similar models are discussed. The comparison includes the relationship between conversion-dependent parameters determined by modified Friedman and Coats−Redfern isoconversion methods and reactivity distribution parameters determined by nonlinear regression of rate or fraction-reacted profiles. A new method for deriving discrete activation-energy distribution parameters having ln(A) = a + bE is also presented. Data accuracy requirements are discussed briefly. Kinetic analyses are given for a variety of materials, including synthetic polymers (polyethylene, polystyrene, polydimethylenenaphthalene, polys...
500 citations
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TL;DR: In this article, the authors have developed recommendations for reliable evaluation of kinetic parameters (the activation energy, the preexponential factor, and the reaction model) from the data obtained by means of thermal analysis methods such as TGA, differential scanning calorimetry (DSC), and differential thermal analysis (DTA).
4,112 citations
TL;DR: In this article, the authors estimate that the Barnett Shale has a total generation potential of about 609 bbl of oil equivalent/ac-ft or the equivalent of 3657 mcf/acft (84.0 m 3 /m 3 ).
Abstract: Shale-gas resource plays can be distinguished by gas type and system characteristics. The Newark East gas field, located in the Fort Worth Basin, Texas, is defined by thermogenic gas production from low-porosity and low-permeability Barnett Shale. The Barnett Shale gas system, a self-contained source-reservoir system, has generated large amounts of gas in the key productive areas because of various characteristics and processes, including (1) excellent original organic richness and generation potential; (2) primary and secondary cracking of kerogen and retained oil, respectively; (3) retention of oil for cracking to gas by adsorption; (4) porosity resulting from organic matter decomposition; and (5) brittle mineralogical composition. The calculated total gas in place (GIP) based on estimated ultimate recovery that is based on production profiles and operator estimates is about 204 bcf/section (5.78 × 10 9 m 3 /1.73 × 10 4 m 3 ). We estimate that the Barnett Shale has a total generation potential of about 609 bbl of oil equivalent/ac-ft or the equivalent of 3657 mcf/ac-ft (84.0 m 3 /m 3 ). Assuming a thickness of 350 ft (107 m) and only sufficient hydrogen for partial cracking of retained oil to gas, a total generation potential of 820 bcf/section is estimated. Of this potential, approximately 60% was expelled, and the balance was retained for secondary cracking of oil to gas, if sufficient thermal maturity was reached. Gas storage capacity of the Barnett Shale at typical reservoir pressure, volume, and temperature conditions and 6% porosity shows a maximum storage capacity of 540 mcf/ac-ft or 159 scf/ton.
2,418 citations
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TL;DR: The second edition of The Biomarker Guide as mentioned in this paper provides a comprehensive account of the role that biomarker technology plays both in petroleum exploration and in understanding Earth history and processes.
Abstract: The second edition of The Biomarker Guide is a fully updated and expanded version of this essential reference. Now in two volumes, it provides a comprehensive account of the role that biomarker technology plays both in petroleum exploration and in understanding Earth history and processes. Biomarkers and Isotopes in the Environment and Human History details the origins of biomarkers and introduces basic chemical principles relevant to their study. It discusses analytical techniques, and applications of biomarkers to environmental and archaeological problems. The Biomarker Guide is an invaluable resource for geologists, petroleum geochemists, biogeochemists, environmental scientists and archaeologists.
2,163 citations
TL;DR: In this article, a simplified version of a vitrinite maturation model, called EASY%R[o], was presented, which uses an Arrhenius first-order parallel-reaction approach with a distribution of activation energies.
Abstract: We present a simplified version of a vitrinite maturation model, complete with sample spreadsheet, based on changes in vitrinite composition with time and temperature. The simplified model, called EASY%R[o], uses an Arrhenius first-order parallel-reaction approach with a distribution of activation energies. EASY%R[o] has been calibrated to a more rigorous model of vitrinite maturation based on the chemical properties of coal vitrinite. With EASY%R[o], a profile of vitrinite reflectance vs. time can be obtained for a given stratigraphic level if the time-temperature history for that level has been estimated. When applied to multiple stratigraphic levels, EASY%R[o] can be used to compute profiles of the percent of vitrinite reflectance with depth for comparison with borehol data and to optimize thermal history models. EASY%R[o] can be used for vitrinite reflectance values of 0.3 to 4.5%, and for heating rates ranging from those in the laboratory (1 degree C/week) to those in slowly subsiding geologic basins (1 degree C/10 m.y.). Examples of model applications range from sedimentary rocks heated by an igneous intrusion to a variety of burial histories. Vitrinite maturation predicted by EASY%Ro is compared to other methods currently being used, such as the Lopatin time-temperature index, level of organic maturity, and other approaches using a single activation energy. Our model successfully estimates vitrinite reflectance due to thermal metamorphism of sedimentary rocks heated by igneous intrusions, geothermal fluids, and burial in a variety of basin setting .
1,639 citations
TL;DR: A broad review of the state-of-the-art biomass pyrolysis research can be found in this article, where three major components (cellulose, hemicellulose and lignin) are discussed in detail.
1,613 citations