Progress in Nuclear Magnetic Resonance Spectroscopy Vol. 2. Edited by J. W. Emsley, J. Feeney and L. H. Sutcliffe. Pp. vii + 269. (Oxford, London and New York: Pergamon Press, Ltd, 1967.) 90s. net. Advances in Magnetic Resonance Vol. 2. By John S. Waugh. Pp. xii + 269. (New York: Academic Press, Inc.; London: Academic Press, Inc. (London), Ltd, 1966.) $12.00. Guide to the NMR Empirical Method A Workbook. By Roy H. Bible jun.. Pp. xi + 305. (New York: Plenum Press, 1967.) $9.50.

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Nuclear Magnetic Resonance

Efforts to use microwaves in material processing are gradually increasing. However, the phenomena associated with the processing are less understood; popular mechanisms such as dipolar heating and conduction heating have been mostly explored. The current paper reviews most of the significant phenomena that cause heating during microwave–material interaction and heat transfer during microwave energy absorption in materials. Mechanisms involved during interaction of microwave with characteristically different materials – metals, non-metals and composites (metal matrix composites, ceramic matrix composites and polymer matrix composites) have been discussed using suitable illustrations. It was observed that while microwave heating of metal based materials is due to the magnetic field based loss effects, dipolar loss and conduction loss are the phenomena associated with the electric field effects in microwave heating of non-metals. Challenges in processing of advanced materials, particularly composites have been identified from the available literature; further research directions with possible benefits have been highlighted.

Microwave–material interaction phenomena: Heating mechanisms, challenges and opportunities in material processing

Voids, the most studied type of manufacturing defects, form very often in processing of fiber-reinforced composites. Due to their considerable influence on physical and thermomechanical properties ...

https://journals.sagepub.com/doi/pdf/10.1177/0021998318772152

Voids in fiber-reinforced polymer composites: A review on their formation, characteristics, and effects on mechanical performance:

Bonded repair of composite aircraft structures: A review of scientific challenges and opportunities

Ferromagnetic microwires enabled multifunctional composite materials

Comparison of the mechanical and physical properties of a carbon fibre epoxy composite manufactured by resin transfer moulding using conventional and microwave heating

Effect of cure cycle heat transfer rates on the physical and mechanical properties of an epoxy matrix composite

While there are reports concerning the processing and properties of materials using Quickstep technique, little attention has been paid to the hygrothermal degradation of the flexural, interfacial and glass transition behaviours of polymeric composites cured at a relatively high ramp rate of 10 K min � 1 (typical of Quickstep processing). Composite laminates were manufactured in an autoclave and using Quickstep and then conditioned in a climatic chamber at 70 C and 85% RH until reaching the limit of saturation. The interfacial (interlaminar shear strength (ILSS)), flexural (flexural strength) and glass transition (Tg) properties of the conditioned and unconditioned panels were evaluated. The results demonstrated that the moisture absorption caused the deleterious effect on the properties and that the reduction in the flexural, interfacial and glass transition properties of Quickstep panels was comparable to that observed in autoclave cured panels. Thermal stability, reversible and irreversible effects of hygrothermal conditioning using TGA, DMTA and FT-IR spectroscopy was also investigated and discussed.

Hygrothermal Degradation of 977-2A Carbon-Epoxy Composite Laminates Cured Via Autoclave and Quickstep.

While there are reports concerning the processing and properties of materials using Quickstep technique, little attention has been paid to the hygrothermal degradation of the flexural, interfacial and glass transition behaviours of polymeric composites cured at a relatively high ramp rate of 10 K min −1 (typical of Quickstep processing). Composite laminates were manufactured in an autoclave and using Quickstep and then conditioned in a climatic chamber at 70 °C and 85% RH until reaching the limit of saturation. The interfacial (interlaminar shear strength (ILSS)), flexural (flexural strength) and glass transition ( T g ) properties of the conditioned and unconditioned panels were evaluated. The results demonstrated that the moisture absorption caused the deleterious effect on the properties and that the reduction in the flexural, interfacial and glass transition properties of Quickstep panels was comparable to that observed in autoclave cured panels. Thermal stability, reversible and irreversible effects of hygrothermal conditioning using TGA, DMTA and FT-IR spectroscopy was also investigated and discussed.

Hygrothermal degradation of 977-2A carbon/epoxy composite laminates cured in autoclave and Quickstep

An instrument has been developed for monitoring cure processes under microwave heating conditions. The main function of the instrument was a calorimeter for performing microwave thermal analysis. A single mode resonant cavity was used as the heating cell in the microwave calorimeter. Thermal analysis measurements were obtained by monitoring the variation in the microwave power that was required to maintain controlled heating of the sample. The microwave thermal analysis data were analogous to conventional differential scanning calorimetry measurements. The dielectric properties of the sample, as a function of the extent of cure, have been obtained using perturbation theory from the changes in resonant frequency and quality factor of the microwave cavity during heating. Additionally, remote sensing fibre-optic probes have been employed to measure real time in situ infrared spectra of the sample during the cure reaction. In this paper, we describe the design and operation of the microwave calorimeter. Examples of experimental results are also presented.

Alan Nesbitt

Papers

Comparison of the mechanical and physical properties of a carbon fibre epoxy composite manufactured by resin transfer moulding using conventional and microwave heating

Effect of cure cycle heat transfer rates on the physical and mechanical properties of an epoxy matrix composite

Hygrothermal Degradation of 977-2A Carbon-Epoxy Composite Laminates Cured Via Autoclave and Quickstep.

Hygrothermal degradation of 977-2A carbon/epoxy composite laminates cured in autoclave and Quickstep

Development of a microwave calorimeter for simultaneous thermal analysis, infrared spectroscopy and dielectric measurements