Author
Alberto Mazzoldi
Other affiliations: University of Wollongong
Bio: Alberto Mazzoldi is an academic researcher from University of Pisa. The author has contributed to research in topics: Carbon nanotube actuators & Conductive polymer. The author has an hindex of 22, co-authored 55 publications receiving 4361 citations. Previous affiliations of Alberto Mazzoldi include University of Wollongong.
Papers
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TL;DR: Predictions based on measurements suggest that actuators using optimized nanotube sheets may eventually provide substantially higher work densities per cycle than any previously known technology.
Abstract: Electromechanical actuators based on sheets of single-walled carbon nanotubes were shown to generate higher stresses than natural muscle and higher strains than high-modulus ferroelectrics. Like natural muscles, the macroscopic actuators are assemblies of billions of individual nanoscale actuators. The actuation mechanism (quantum chemical-based expansion due to electrochemical double-layer charging) does not require ion intercalation, which limits the life and rate of faradaic conducting polymer actuators. Unlike conventional ferroelectric actuators, low operating voltages of a few volts generate large actuator strains. Predictions based on measurements suggest that actuators using optimized nanotube sheets may eventually provide substantially higher work densities per cycle than any previously known technology.
2,334 citations
TL;DR: In this article, the authors extend the electromechanical characterisation of dielectric elastomer actuators by measuring the isotonic transverse strain, the isometric transverse stress and the driving current due to a 2 s high voltage impulse.
Abstract: This work intends to extend the electromechanical characterisation of dielectric elastomer actuators. Planar actuators were realised with a 50m-thick film of an acrylic elastomer coated with compliant electrodes. The isotonic transverse strain, the isometric transverse stress and the driving current, due to a 2 s high voltage impulse, were measured for four electrode materials (thickened electrolyte solution, graphite spray, carbon grease and graphite powder), four transverse prestress values (19.6, 29.4, 39.2 and 49.0 kPa) and different driving voltages (up to the dielectric breakdown voltage). Results showed that the electrode material and prestress strongly influence the electromechanical performances of the devices. Actuators with graphite spray electrodes and transverse prestress of 39.2 kPa exhibited an isotonic transverse strain of 6% at 49 V/m, with a driving current per unit electrode area of 3.5 A/cm 2 , and an isometric transverse stress of 49 kPa at 42 V/m. An electromechanical coupling efficiency of 10% at 21 V/m was calculated for actuators with thickened electrolyte solution electrodes and a transverse prestress of 29.4 kPa. The presented data permits to choose the best electrode material and the best prestress value (among those tested), to obtain the maximum isotonic transverse strain, the maximum isometric transverse stress or the maximum efficiency for different ranges of applied electric field. © 2003 Elsevier B.V. All rights reserved.
253 citations
TL;DR: The thermal and mechanical transduction properties of the strain sensor are investigated, a geometrical parameter to invariantly codify the sensor response during aging is proposed and a brief outline of ongoing applications is reported.
Abstract: In recent years, an innovative technology based on polymeric conductors and semiconductors has undergone rapid growth. These materials offer several advantages with respect to metals and inorganic conductors: lightness, large elasticity and resilience, resistance to corrosion, flexibility, impact strength, etc. These properties are suitable for implementing wearable devices. In particular, a sensitive glove able to detect the position and the motion of fingers and a sensorized leotard have been developed. Here, the characterization of the strain-sensing fabric is presented. In the first section, the polymerization process used to realize the strain sensor is described. Then, the thermal and mechanical transduction properties of the strain sensor are investigated and a geometrical parameter to invariantly codify the sensor response during aging is proposed. Finally, a brief outline of ongoing applications is reported.
213 citations
TL;DR: In this paper, a performance analysis of a conducting polymer film actuator made of polypyrrole (PPy) is presented, where electrochemomechanical characterizations of the active displacement and the developed force of a PPy free-standing film at different loading conditions are performed and two driving signals are used: the former, a cyclic voltammetry at 1 mV/s between ± 1 V, is used to carry out an accurate on-line analysis of the film displacement; the latter, a current square wave between 0.02 and 0.1
194 citations
178 citations
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TL;DR: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects.
Abstract: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects. Some of these applications are now realized in products. Others are demonstrated in early to advanced devices, and one, hydrogen storage, is clouded by controversy. Nanotube cost, polydispersity in nanotube type, and limitations in processing and assembly methods are important barriers for some applications of single-walled nanotubes.
9,693 citations
TL;DR: The nanotubes sensors exhibit a fast response and a substantially higher sensitivity than that of existing solid-state sensors at room temperature and the mechanisms of molecular sensing with nanotube molecular wires are investigated.
Abstract: Chemical sensors based on individual single-walled carbon nanotubes (SWNTs) are demonstrated. Upon exposure to gaseous molecules such as NO 2 or NH 3 , the electrical resistance of a semiconducting SWNT is found to dramatically increase or decrease. This serves as the basis for nanotube molecular sensors. The nanotube sensors exhibit a fast response and a substantially higher sensitivity than that of existing solid-state sensors at room temperature. Sensor reversibility is achieved by slow recovery under ambient conditions or by heating to high temperatures. The interactions between molecular species and SWNTs and the mechanisms of molecular sensing with nanotube molecular wires are investigated.
5,908 citations
TL;DR: Graphene oxide paper is reported, a free-standing carbon-based membrane material made by flow-directed assembly of individual graphene oxide sheets that outperforms many other paper-like materials in stiffness and strength.
Abstract: Free-standing paper-like or foil-like materials are an integral part of our technological society. Their uses include protective layers, chemical filters, components of electrical batteries or supercapacitors, adhesive layers, electronic or optoelectronic components, and molecular storage. Inorganic 'paper-like' materials based on nanoscale components such as exfoliated vermiculite or mica platelets have been intensively studied and commercialized as protective coatings, high-temperature binders, dielectric barriers and gas-impermeable membranes. Carbon-based flexible graphite foils composed of stacked platelets of expanded graphite have long been used in packing and gasketing applications because of their chemical resistivity against most media, superior sealability over a wide temperature range, and impermeability to fluids. The discovery of carbon nanotubes brought about bucky paper, which displays excellent mechanical and electrical properties that make it potentially suitable for fuel cell and structural composite applications. Here we report the preparation and characterization of graphene oxide paper, a free-standing carbon-based membrane material made by flow-directed assembly of individual graphene oxide sheets. This new material outperforms many other paper-like materials in stiffness and strength. Its combination of macroscopic flexibility and stiffness is a result of a unique interlocking-tile arrangement of the nanoscale graphene oxide sheets.
5,117 citations
TL;DR: Graphene has emerged as a subject of enormous scientific interest due to its exceptional electron transport, mechanical properties, and high surface area, and when incorporated appropriately, these atomically thin carbon sheets can significantly improve physical properties of host polymers at extremely small loading.
Abstract: Graphene has emerged as a subject of enormous scientific interest due to its exceptional electron transport, mechanical properties, and high surface area. When incorporated appropriately, these atomically thin carbon sheets can significantly improve physical properties of host polymers at extremely small loading. We first review production routes to exfoliated graphite with an emphasis on top-down strategies starting from graphite oxide, including advantages and disadvantages of each method. Then solvent- and melt-based strategies to disperse chemically or thermally reduced graphene oxide in polymers are discussed. Analytical techniques for characterizing particle dimensions, surface characteristics, and dispersion in matrix polymers are also introduced. We summarize electrical, thermal, mechanical, and gas barrier properties of the graphene/polymer nanocomposites. We conclude this review listing current challenges associated with processing and scalability of graphene composites and future perspectives f...
2,979 citations
TL;DR: It is shown that prestraining the film further improves the performance of electrical actuators made from films of dielectric elastomers coated on both sides with compliant electrode material.
Abstract: Electrical actuators were made from films of dielectric elastomers (such as silicones) coated on both sides with compliant electrode material. When voltage was applied, the resulting electrostatic forces compressed the film in thickness and expanded it in area, producing strains up to 30 to 40%. It is now shown that prestraining the film further improves the performance of these devices. Actuated strains up to 117% were demonstrated with silicone elastomers, and up to 215% with acrylic elastomers using biaxially and uniaxially prestrained films. The strain, pressure, and response time of silicone exceeded those of natural muscle; specific energy densities greatly exceeded those of other field-actuated materials. Because the actuation mechanism is faster than in other high-strain electroactive polymers, this technology may be suitable for diverse applications.
2,969 citations