Alex K.-Y. Jen

Bio: Alex K.-Y. Jen is an academic researcher from City University of Hong Kong. The author has contributed to research in topics: Perovskite (structure) & Polymer solar cell. The author has an hindex of 128, co-authored 921 publications receiving 61811 citations. Previous affiliations of Alex K.-Y. Jen include University of Nebraska–Lincoln & Zhejiang California International NanoSystems Institute.

Materials for Loss-Based Switching in Silicon-Organic Hybrid Devices

Abstract: We determine the critical parameters to produce highly efficient all-optical switching via nonlinear-loss-based decoupling in silicon microring resonators with organic material claddings. Switching energies as low as 100 fJ are possible.

Simple reflection measurement of nonlinear optical activity using silicon as an electrode

Abstract: Future generations of photonic devices which incorporate poled organic nonlinear optical materials may be aided by, or require the use of non-traditional electrodes This report details the integration of highly doped silicon as one of the poling/modulating electrodes in the simple reflection type experiment for determination of nonlinear optical activity in a guest-host polymer system The measurements illustrate that the behavior of doped-silicon and the traditional indium tin oxide (ITO) coated glass electrodes are analogous Results demonstrate both successful poling and subsequent modulation of NLO materials using a silicon electrode, including the calculation of r 33 values comparable or exceeding those achieved using a standard ITO electrode Keywords: electro-optic polymer, nonlinear optical polymer, silicon electrode, poling 1 INTRODUCTION Recent progress has seen the electro-optic (EO) activity of specially designed polymer systems achive new highs, easily surpassing lithium-niobate by a factor of at least two with respect to the critical figure of merit for the field, the electro-optic coefficient, r

High speed electro-optic modulation in hybrid silicon on insulator slotted photonic crystal

Abstract: We demonstrate GHz electro-optic modulation in a slotted silicon photonic crystal infiltrated with nonlinear optical polymer material.

Silica/Electro-optic Polymer Optical Modulator for MMW Receiving (Preprint)

Abstract: : A silica/electro-optic (EO) polymer phase modulator is proposed for millimeter-wave (MMW) radiation receiver with the use of a bowtie antenna. Waveguide design optimization is presented for a waveguide with an EO polymer core and silica/solgel cladding. Electrode effects on the insertion loss and poling efficiency are also analyzed and conditions for low-loss and high poling efficiency established. The bowtie antenna is simulated and shows a broadband response with a maximum at 5GHz and a 3dB-bandwidth of approximately 12GHz. A fiber splicing technique is presented that reduces coupling loss between SMF-28 and the waveguide. Experimental results for a fabricated device with MMW-response between 10-14GHz are shown with carrier to first sideband intensity difference of up to -36dB.

Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber.

Abstract: Organic-inorganic perovskites have shown promise as high-performance absorbers in solar cells, first as a coating on a mesoporous metal oxide scaffold and more recently as a solid layer in planar heterojunction architectures. Here, we report transient absorption and photoluminescence-quenching measurements to determine the electron-hole diffusion lengths, diffusion constants, and lifetimes in mixed halide (CH3NH3PbI(3-x)Cl(x)) and triiodide (CH3NH3PbI3) perovskite absorbers. We found that the diffusion lengths are greater than 1 micrometer in the mixed halide perovskite, which is an order of magnitude greater than the absorption depth. In contrast, the triiodide absorber has electron-hole diffusion lengths of ~100 nanometers. These results justify the high efficiency of planar heterojunction perovskite solar cells and identify a critical parameter to optimize for future perovskite absorber development.

Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber

Abstract: Organic-inorganic perovskites have shown promise as high-performance absorbers in solar cells, first as a coating on a mesoporous metal oxide scaffold and more recently as a solid layer in planar heterojunction architectures. Here, we report transient absorption and photoluminescence-quenching measurements to determine the electron-hole diffusion lengths, diffusion constants, and lifetimes in mixed halide (CH3NH3PbI(3-x)Cl(x)) and triiodide (CH3NH3PbI3) perovskite absorbers. We found that the diffusion lengths are greater than 1 micrometer in the mixed halide perovskite, which is an order of magnitude greater than the absorption depth. In contrast, the triiodide absorber has electron-hole diffusion lengths of ~100 nanometers. These results justify the high efficiency of planar heterojunction perovskite solar cells and identify a critical parameter to optimize for future perovskite absorber development.

Interface engineering of highly efficient perovskite solar cells

Abstract: Advancing perovskite solar cell technologies toward their theoretical power conversion efficiency (PCE) requires delicate control over the carrier dynamics throughout the entire device. By controlling the formation of the perovskite layer and careful choices of other materials, we suppressed carrier recombination in the absorber, facilitated carrier injection into the carrier transport layers, and maintained good carrier extraction at the electrodes. When measured via reverse bias scan, cell PCE is typically boosted to 16.6% on average, with the highest efficiency of ~19.3% in a planar geometry without antireflective coating. The fabrication of our perovskite solar cells was conducted in air and from solution at low temperatures, which should simplify manufacturing of large-area perovskite devices that are inexpensive and perform at high levels.

Aggregation-Induced Emission: Together We Shine, United We Soar!

Abstract: Ju Mei,†,‡,∥ Nelson L. C. Leung,†,‡,∥ Ryan T. K. Kwok,†,‡ Jacky W. Y. Lam,†,‡ and Ben Zhong Tang*,†,‡,§ †HKUST-Shenzhen Research Institute, Hi-Tech Park, Nanshan, Shenzhen 518057, China ‡Department of Chemistry, HKUST Jockey Club Institute for Advanced Study, Institute of Molecular Functional Materials, Division of Biomedical Engineering, State Key Laboratory of Molecular Neuroscience, Division of Life Science, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China Guangdong Innovative Research Team, SCUT-HKUST Joint Research Laboratory, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, China

High-performance photovoltaic perovskite layers fabricated through intramolecular exchange

Abstract: The band gap of formamidinium lead iodide (FAPbI3) perovskites allows broader absorption of the solar spectrum relative to conventional methylammonium lead iodide (MAPbI3). Because the optoelectronic properties of perovskite films are closely related to film quality, deposition of dense and uniform films is crucial for fabricating high-performance perovskite solar cells (PSCs). We report an approach for depositing high-quality FAPbI3 films, involving FAPbI3 crystallization by the direct intramolecular exchange of dimethylsulfoxide (DMSO) molecules intercalated in PbI2 with formamidinium iodide. This process produces FAPbI3 films with (111)-preferred crystallographic orientation, large-grained dense microstructures, and flat surfaces without residual PbI2. Using films prepared by this technique, we fabricated FAPbI3-based PSCs with maximum power conversion efficiency greater than 20%.