Author
Alexander Aumüller
Bio: Alexander Aumüller is an academic researcher from University of Würzburg. The author has contributed to research in topics: Tetrathiafulvalene & Phase diagram. The author has an hindex of 18, co-authored 24 publications receiving 1298 citations.
Papers
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372 citations
99 citations
TL;DR: A new class of quinone derivatives, the dicyanodiimines 2, 21, and 23, has been synthesized by the reaction of the corresponding quinones with bis(trimethylsilyl) carbondiimide (8) and titanium tetrachloride as mentioned in this paper.
93 citations
83 citations
TL;DR: In this paper, a CDW driven phase transition is seen and antiferromagnetic resonance (AFMR) is found below 10 K. The lack of any ESR signal in the conducting state is due to strong spin-orbit coupling (SOC) given by the nitrogen(p)-Cu(d) admixture.
75 citations
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TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Abstract: The long-standing challenge of designing and constructing new crystalline solid-state materials from molecular building blocks is just beginning to be addressed with success. A conceptual approach that requires the use of secondary building units to direct the assembly of ordered frameworks epitomizes this process: we call this approach reticular synthesis. This chemistry has yielded materials designed to have predetermined structures, compositions and properties. In particular, highly porous frameworks held together by strong metal-oxygen-carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
8,013 citations
TL;DR: The state-of-the-art on hybrid porous solids, their advantages, their new routes of synthesis, the structural concepts useful for their 'design', aiming at reaching very large pores are presented.
Abstract: This critical review will be of interest to the experts in porous solids (including catalysis), but also solid state chemists and physicists. It presents the state-of-the-art on hybrid porous solids, their advantages, their new routes of synthesis, the structural concepts useful for their ‘design’, aiming at reaching very large pores. Their dynamic properties and the possibility of predicting their structure are described. The large tunability of the pore size leads to unprecedented properties and applications. They concern adsorption of species, storage and delivery and the physical properties of the dense phases. (323 references)
5,187 citations
TL;DR: In this paper, the development in the field of coordination polymers or metal-organic coordination networks, MOCNs (metal-organic frameworks, MOFs) is assessed in terms of property investigations in the areas of catalysis, chirality, conductivity, luminescence, magnetism, spin-transition (spin-crossover), nonlinear optics (NLO) and porosity or zeolitic behavior upon which potential applications could be based.
Abstract: The development in the field of coordination polymers or metal-organic coordination networks, MOCNs (metal-organic frameworks, MOFs) is assessed in terms of property investigations in the areas of catalysis, chirality, conductivity, luminescence, magnetism, spin-transition (spin-crossover), non-linear optics (NLO) and porosity or zeolitic behavior upon which potential applications could be based.
3,117 citations
TL;DR: A review of the synthesis, structure, and properties of metal-organic frameworks (MOFs) is presented in this paper, highlighting the important advances in their research over the past decade.
2,485 citations
TL;DR: The use of crystal engineering concepts has produced a variety of coordination networks, many of which exhibit novel and fascinating types of entanglements of individual motifs as mentioned in this paper, and the structures of a number of entangled polymeric networks reported in these years by many groups.
1,881 citations