scispace - formally typeset
Search or ask a question
Author

Alexander Titov

Bio: Alexander Titov is an academic researcher from Russian Academy of Sciences. The author has contributed to research in topics: Intercalation (chemistry) & Electronic structure. The author has an hindex of 18, co-authored 158 publications receiving 1382 citations. Previous affiliations of Alexander Titov include Ural State Technical University & Ural Federal University.


Papers
More filters
Journal ArticleDOI
TL;DR: It is found that the energy density required to melt the chargedensity wave nonthermally is substantially lower than that required for thermal suppression and is comparable to the charge density wave condensation energy.
Abstract: We use time-resolved optical reflectivity and x-ray diffraction with femtosecond resolution to study the dynamics of the structural order parameter of the charge density wave phase in TiSe2. We find that the energy density required to melt the charge density wave nonthermally is substantially lower than that required for thermal suppression and is comparable to the charge density wave condensation energy. This observation, together with the fact that the structural dynamics take place on an extremely fast time scale, supports the exciton condensation mechanism for the charge density wave in TiSe2.

111 citations

Journal ArticleDOI
TL;DR: In this article, the charge-density-wave phase transition of 1T-TiSe2 was studied by angle-resolved photo-emission over a wide temperature range.
Abstract: The charge-density-wave phase transition of 1T-TiSe2 is studied by angle-resolved photoemission over a wide temperature range. An important chemical-potential shift which strongly evolves with temperature is evidenced. In the framework of the exciton condensate phase, the detailed temperature dependence of the associated order parameter is extracted. Having a mean-field-like behavior at low temperature, it exhibits a nonzero value above the transition, interpreted as the signature of strong excitonic fluctuations, reminiscent of the pseudogap phase of high-temperature superconductors. Integrated intensity around the Fermi level is found to display a trend similar to the measured resistivity and is discussed within the model.

72 citations

Journal ArticleDOI
TL;DR: In this article, angle-resolved photoemission spectroscopy performed on 1T-TiSe2 has been used to analyze the excitonic insulator phase in the transition metal dichalcogenides.
Abstract: We present recent results obtained using angle-resolved photoemission spectroscopy performed on 1T-TiSe2. Emphasis is put on the peculiarity of the bandstructure of TiSe2 compared to other transition metal dichalcogenides, which suggests that this system is an excellent candidate for the realization of the excitonic insulator phase. This exotic phase is discussed in relation to the BCS theory, and its spectroscopic signature is computed via a model adapted to the particular bandstructure of 1T-TiSe2. A comparison between photoemission intensity maps calculated with the spectral function derived for this model and experimental results is shown, giving strong support for the exciton condensate phase as the origin of the charge density wave transition observed in 1T-TiSe2. The temperature-dependent order parameter characterizing the exciton condensate phase is discussed, both on a theoretical and an experimental basis, as well as the chemical potential shift occurring in this system. Finally, the transport properties of 1T-TiSe2 are analyzed in the light of the photoemission results.

52 citations

Journal ArticleDOI
TL;DR: In this article, the results of investigations of intercalated compounds Cr_xTiSe_2 and Co_x TiSe-2 by X-ray photoelectron spectroscopy (XPS) and X -ray emission spectro-computation (XES) are presented.
Abstract: The results of investigations of intercalated compounds Cr_xTiSe_2 and Co_xTiSe_2 by X-ray photoelectron spectroscopy (XPS) and X-ray emission spectroscopy (XES) are presented. The data obtained are compared with theoretical results of spin-polarized band structure calculations. A good agreement between theoretical and experimental data for the electronic structure of the investigated materials has been observed. The interplay between the M3d--Ti3d hybridization (M=Cr, Co) and the magnetic moment at the M site is discussed. A 0.9 eV large splitting of the core Cr2p{3/2} level was observed, which reveals a strong exchange magnetic interaction of 3d-2p electrons of Cr. In the case of a strong localization of the Cr3d electrons (for x<0.25), the broadening of the CrL spectra into the region of the states above the nominal Fermi level was observed and attributed to X-ray re-emission. The measured kinetic properties are in good accordance with spectral investigations and band calculation results.

50 citations

Journal ArticleDOI
TL;DR: In this article, the results of investigations of intercalated compounds by x-ray photoelectron spectroscopy and xray emission spectro-graphs are presented and compared with theoretical results of spin-polarized band-structure calculations.
Abstract: The results of investigations of intercalated compounds ${\mathrm{Cr}}_{x}{\mathrm{TiSe}}_{2}$ and ${\mathrm{Co}}_{x}{\mathrm{TiSe}}_{2}$ by x-ray photoelectron spectroscopy and x-ray emission spectroscopy are presented. The data obtained are compared with theoretical results of spin-polarized band-structure calculations. A good agreement between theoretical and experimental data for the electronic structure of the investigated materials has been observed. The interplay between the M $3d\char21{}\mathrm{Ti}$ $3d$ hybridization $(M=\mathrm{Cr},$ Co) and the magnetic moment at the M site is discussed. A 0.9-eV large splitting of the core $\mathrm{Cr}\phantom{\rule{0ex}{0ex}}{2p}_{3/2}$ level was observed, which reveals a strong exchange magnetic interaction of $3d\ensuremath{-}2p$ electrons of Cr. In the case of a strong localization of the Cr $3d$ electrons (for $xl0.25),$ the broadening of the Cr L spectra into the region of the states above the nominal Fermi level was observed and attributed to x-ray reemission. The measured kinetic properties are in good accordance with spectral investigations and band calculation results.

48 citations


Cited by
More filters
28 Jul 2005
TL;DR: PfPMP1)与感染红细胞、树突状组胞以及胎盘的单个或多个受体作用,在黏附及免疫逃避中起关键的作�ly.
Abstract: 抗原变异可使得多种致病微生物易于逃避宿主免疫应答。表达在感染红细胞表面的恶性疟原虫红细胞表面蛋白1(PfPMP1)与感染红细胞、内皮细胞、树突状细胞以及胎盘的单个或多个受体作用,在黏附及免疫逃避中起关键的作用。每个单倍体基因组var基因家族编码约60种成员,通过启动转录不同的var基因变异体为抗原变异提供了分子基础。

18,940 citations

Journal ArticleDOI
Kai Rossnagel1
TL;DR: It is found that the predictions of the standard mean-field model agree only semi-quantitatively with the experimental data and that there is not one generally dominant factor driving charge-density-wave formation in this family of layer compounds.
Abstract: The occurrence of charge-density waves in three selected layered transition-metal dichalcogenides-1T-TaS(2), 2H-TaSe(2) and 1T-TiSe(2)-is discussed from an experimentalist's point of view with a particular focus on the implications of recent angle-resolved photoelectron spectroscopy results. The basic models behind charge-density-wave formation in low-dimensional solids are recapitulated, the experimental and theoretical results for the three selected compounds are reviewed, and their band structures and spectral weight distributions in the commensurate charge-density-wave phases are calculated using an empirical tight-binding model. It is explored whether the origin of charge-density waves in the layered transition-metal dichalcogenides can be understood in a unified way on the basis of a few measured and calculated parameters characterizing the interacting electron-lattice system. It is found that the predictions of the standard mean-field model agree only semi-quantitatively with the experimental data and that there is not one generally dominant factor driving charge-density-wave formation in this family of layer compounds. The need for further experimental and theoretical scrutiny is emphasized.

592 citations

Journal ArticleDOI
TL;DR: The observation of room temperature ferromagnetism in manganese selenide (MnSe x) films grown by molecular beam epitaxy (MBE) holds promise for potential applications in energy efficient information storage and processing.
Abstract: Monolayer van der Waals (vdW) magnets provide an exciting opportunity for exploring two-dimensional (2D) magnetism for scientific and technological advances, but the intrinsic ferromagnetism has only been observed at low temperatures. Here, we report the observation of room temperature ferromagnetism in manganese selenide (MnSex) films grown by molecular beam epitaxy (MBE). Magnetic and structural characterization provides strong evidence that, in the monolayer limit, the ferromagnetism originates from a vdW manganese diselenide (MnSe2) monolayer, while for thicker films it could originate from a combination of vdW MnSe2 and/or interfacial magnetism of α-MnSe(111). Magnetization measurements of monolayer MnSex films on GaSe and SnSe2 epilayers show ferromagnetic ordering with a large saturation magnetization of ∼4 Bohr magnetons per Mn, which is consistent with the density functional theory calculations predicting ferromagnetism in monolayer 1T-MnSe2. Growing MnSex films on GaSe up to a high thickness (∼4...

565 citations