Ali Mani

Bio: Ali Mani is an academic researcher from Stanford University. The author has contributed to research in topics: Turbulence & Stokes number. The author has an hindex of 34, co-authored 135 publications receiving 3812 citations. Previous affiliations of Ali Mani include University of Notre Dame & Center for Turbulence Research.

Theory and experiments of concentration polarization and ion focusing at microchannel and nanochannel interfaces.

Abstract: In this tutorial review aimed at researchers using nanofluidic devices, we summarize the current state of theoretical and experimental approaches to describing concentration polarization (CP) in hybrid microfluidic–nanofluidic systems. We also analyze experimental results for these systems and place them in the context of recent theoretical developments. We then extend the theory to explain the behavior of both positively and negatively charged, low-concentration, analyte species in systems with CP. We conclude by discussing several applications of CP in microfluidics.

On the propagation of concentration polarization from microchannel-nanochannel interfaces. Part I: Analytical model and characteristic analysis.

Abstract: We develop two models to describe ion transport in variable-height micro- and nanochannels. For the first model, we obtain a one-dimensional (unsteady) partial differential equation governing flow and charge transport through a shallow and wide electrokinetic channel. In this model, the effects of electric double layer (EDL) on axial transport are taken into account using exact solutions of the Poisson−Boltzmann equation. The second simpler model, which is approachable analytically, assumes that the EDLs are confined to near-wall regions. Using a characteristics analysis, we show that the latter model captures concentration polarization (CP) effects and provides useful insight into its dynamics. Two distinct CP regimes are identified: CP with propagation in which enrichment and depletion shocks propagate outward, and CP without propagation where polarization effects stay local to micro- nanochannel interfaces. The existence of each regime is found to depend on a nanochannel Dukhin number and mobility of t...

Overlimiting Current in a Microchannel

Abstract: We revisit the classical problem of diffusion-limited ion transport to a membrane (or electrode) by considering the effects of charged sidewalls. Using simple mathematical models and numerical simulations, we identify three basic mechanisms for overlimiting current in a microchannel: (i) surface conduction carried by excess counterions, which dominates for very thin channels, (ii) convection by electro-osmotic flow on the sidewalls, which dominates for thicker channels, and (iii) transitions to electro-osmotic instability on the membrane end in very thick channels. These intriguing electrokinetic phenomena may find applications in biological separations, water desalination, and electrochemical energy storage.

Physics and Computation of Aero-Optics

Abstract: This article provides a critical review of aero-optics with an emphasis on recent developments in computational predictions and the physical mechanisms of flow-induced optical distortions. Following a brief introduction of the fundamental theory and key concepts, computational techniques for aberrating flow fields and optical propagation are discussed along with a brief survey of wave-front sensors used in experimental measurements. New physical understanding generated through numerical and experimental investigations is highlighted for a number of important aero-optical flows, including turbulent boundary layers, separated shear layers, and flow over optical turrets. Approaches for mitigating aero-optical effects are briefly discussed.

On the propagation of concentration polarization from microchannel-nanochannel interfaces. Part II: Numerical and experimental study

Abstract: We present results of a combined computational and experimental study of the propagation of concentration polarization (CP) zones in a microchannel-nanochannel system. Our computational model considers the combined effects of bulk flow, electromigration, and diffusion and accurately captures the dynamics of CP. Using wall charge inside the nanochannel as a single fitting parameter, we predict experimentally observed enrichment and depletion shock velocities. Our model can also be used to compute the existence of CP with propagating enrichment and depletion shocks on the basis of measured ion mobility and wall properties. We present experiments where the background electrolyte consists of only a fluorescent ion and its counterion. These results are used to validate the computational model and to confirm predicted trends from an analytical model presented in the first of this two-paper series. We show experimentally that the enrichment region concentration is effectively independent of the applied current, while the enrichment and depletion shock velocities increase in proportion to current density.

Numerical Heat Transfer And Fluid Flow

Abstract: Thank you for reading numerical heat transfer and fluid flow. Maybe you have knowledge that, people have search numerous times for their favorite books like this numerical heat transfer and fluid flow, but end up in infectious downloads. Rather than reading a good book with a cup of coffee in the afternoon, instead they cope with some malicious virus inside their computer. numerical heat transfer and fluid flow is available in our digital library an online access to it is set as public so you can get it instantly. Our books collection spans in multiple countries, allowing you to get the most less latency time to download any of our books like this one. Merely said, the numerical heat transfer and fluid flow is universally compatible with any devices to read.

Water desalination via capacitive deionization : What is it and what can we expect from it?

Abstract: Capacitive deionization (CDI) is an emerging technology for the facile removal of charged ionic species from aqueous solutions, and is currently being widely explored for water desalination applications. The technology is based on ion electrosorption at the surface of a pair of electrically charged electrodes, commonly composed of highly porous carbon materials. The CDI community has grown exponentially over the past decade, driving tremendous advances via new cell architectures and system designs, the implementation of ion exchange membranes, and alternative concepts such as flowable carbon electrodes and hybrid systems employing a Faradaic (battery) electrode. Also, vast improvements have been made towards unraveling the complex processes inherent to interfacial electrochemistry, including the modelling of kinetic and equilibrium aspects of the desalination process. In our perspective, we critically review and evaluate the current state-of-the-art of CDI technology and provide definitions and performance metric nomenclature in an effort to unify the fast-growing CDI community. We also provide an outlook on the emerging trends in CDI and propose future research and development directions.

Introduction To Electrodynamics

Abstract: Thank you for downloading introduction to electrodynamics. Maybe you have knowledge that, people have look numerous times for their chosen books like this introduction to electrodynamics, but end up in infectious downloads. Rather than enjoying a good book with a cup of tea in the afternoon, instead they juggled with some malicious bugs inside their computer. introduction to electrodynamics is available in our book collection an online access to it is set as public so you can get it instantly. Our book servers spans in multiple countries, allowing you to get the most less latency time to download any of our books like this one. Merely said, the introduction to electrodynamics is universally compatible with any devices to read.