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Allan J. Canty
Researcher at University of Tasmania
Publications - 319
Citations - 7619
Allan J. Canty is an academic researcher from University of Tasmania. The author has contributed to research in topics: Organopalladium & Palladium. The author has an hindex of 42, co-authored 309 publications receiving 7238 citations. Previous affiliations of Allan J. Canty include Monash University, Clayton campus & Central Science Laboratory.
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Development of organopalladium(IV) chemistry: fundamental aspects and systems for studies of mechanism in organometallic chemistry and catalysis
TL;DR: Palladium is one of the most widely studied elements in organometallic chemistry, partly owing to the important role of palladium complexes in organic synthesis and catalysis.
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Mechanisms of d8 organometallic reactions involving electrophiles and intramolecular assistance by nucleophiles
Allan J. Canty,G. van Koten +1 more
TL;DR: The most attractive and fundamental interaction between metal centers and organic molecules that could lead to new functionalization at carbon is direct activation of the C-H bonds of hydrocarbons as discussed by the authors.
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The van der Waals radius of mercury
Allan J. Canty,Glen B. Deacon +1 more
TL;DR: In this paper, the van der Waals radius of mercury compounds has been shown to be in the range 1.7-2.0 A. A general value for the radius should lie at the conservative end of the range, which corresponds to Grdenic's largely neglected upper limit for any form of bonding, is proposed.
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Organopalladium and platinum chemistry in oxidising milieu as models for organic synthesis involving the higher oxidation states of palladium
TL;DR: This perspective focuses on the higher oxidation state (III, IV) organometallic chemistry of palladium involving a range of strong oxidants, with consideration of platinum chemistry where it is informative for the evaluation of structure and mechanism.
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Connecting Binuclear Pd(III) and Mononuclear Pd(IV) Chemistry by Pd−Pd Bond Cleavage
David C. Powers,Eunsung Lee,Alireza Ariafard,Alireza Ariafard,Melanie S. Sanford,Brian F. Yates,Allan J. Canty,Tobias Ritter +7 more
TL;DR: Experimental and computational studies of the oxidation of a binuclear Pd(II) complex with electrophilic trifluoromethylating ("CF(3)(+)") reagents suggest that a mononuclear PD(IV) complex is generated by an oxidation-fragmentation sequence proceeding via fragmentation of an initially formed, formally binuclearPd(III), intermediate.