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Alois Loidl

Bio: Alois Loidl is an academic researcher from University of Augsburg. The author has contributed to research in topics: Dielectric & Antiferromagnetism. The author has an hindex of 78, co-authored 951 publications receiving 27187 citations. Previous affiliations of Alois Loidl include Max Planck Society & Darmstadt University of Applied Sciences.


Papers
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Journal ArticleDOI
TL;DR: In this article, it was shown that the largest intrinsic dielectric constant observed so far in nonferroelectric materials is of order 10 − 2 − 2, which can be explained by depletion layers at the interface between sample and contacts or at grain boundaries.
Abstract: Experimental evidence is provided that colossal dielectric constants ${\ensuremath{\varepsilon}}^{\ensuremath{'}}g~1000,$ sometimes reported to exist in a broad temperature range, can often be explained by Maxwell-Wagner-type contributions of depletion layers at the interface between sample and contacts or at grain boundaries. We demonstrate this on a variety of different materials. We speculate that the largest intrinsic dielectric constant observed so far in nonferroelectric materials is of order ${10}^{2}.$

805 citations

Journal ArticleDOI
TL;DR: In this paper, the dielectric properties of a material showing colossal values of the Dielectric constant were investigated over a broad temperature and frequency range extending up to $1.3 GHz.
Abstract: The dielectric properties of $\mathrm{Ca}{\mathrm{Cu}}_{3}{\mathrm{Ti}}_{4}{\mathrm{O}}_{12}$, a material showing colossal values of the dielectric constant, were investigated over a broad temperature and frequency range extending up to $1.3\phantom{\rule{0.3em}{0ex}}\mathrm{GHz}$. A detailed equivalent-circuit analysis of the results and two crucial experiments, employing different types of contacts and varying the sample thickness were performed. The results provide clear evidence that the apparently high values of the dielectric constant in $\mathrm{Ca}{\mathrm{Cu}}_{3}{\mathrm{Ti}}_{4}{\mathrm{O}}_{12}$ are nonintrinsic and due to electrode polarization effects. The intrinsic properties of $\mathrm{Ca}{\mathrm{Cu}}_{3}{\mathrm{Ti}}_{4}{\mathrm{O}}_{12}$ are characterized by charge transport via hopping of localized charge carriers and a relatively high dielectric constant of the order of 100.

613 citations

Journal ArticleDOI
TL;DR: A new Néel-type of SkL describable as a superposition of spin cycloids in contrast to the Bloch-type SkL in chiral magnets described in terms of spin helices is found in the polar magnetic semiconductor GaV4S8 with rhombohedral (C3v) symmetry and easy axis anisotropy.
Abstract: Following the early prediction of the skyrmion lattice (SkL)--a periodic array of spin vortices--it has been observed recently in various magnetic crystals mostly with chiral structure. Although non-chiral but polar crystals with Cnv symmetry were identified as ideal SkL hosts in pioneering theoretical studies, this archetype of SkL has remained experimentally unexplored. Here, we report the discovery of a SkL in the polar magnetic semiconductor GaV4S8 with rhombohedral (C3v) symmetry and easy axis anisotropy. The SkL exists over an unusually broad temperature range compared with other bulk crystals and the orientation of the vortices is not controlled by the external magnetic field, but instead confined to the magnetic easy axis. Supporting theory attributes these unique features to a new Neel-type of SkL describable as a superposition of spin cycloids in contrast to the Bloch-type SkL in chiral magnets described in terms of spin helices.

569 citations

Journal ArticleDOI
17 Mar 2005-Nature
TL;DR: Measurements on a simple cubic spinel compound with unusual, and potentially useful, magnetic and electric properties show ferromagnetic order coexisting with relaxor ferroelectricity, and the magnetocapacitive coupling reaches colossal values, approaching 500 per cent.
Abstract: Ferromagnets have been known since ancient times. Ferroelectrics were discovered 80 years ago, and both properties are important in many areas of technology and electronics. Materials displaying both ferroelectricity and ferromagnetism combine the potential applications of both parent phases, with a range of new applications in optics, electronic circuitry and multiple-state memory devices. Such materials are rare, but one described this week, the common sulpho-spinel CdCr2S4, shows promise. It combines reasonable ordering temperatures (the point at which magnetic properties disappear) with sizeable magnetization and polarization well suited for application. Materials in which magnetic and electric order coexist—termed ‘multiferroics’ or ‘magnetoelectrics’—have recently become the focus of much research1,2,3,4. In particular, the simultaneous occurrence of ferromagnetism and ferroelectricity, combined with an intimate coupling of magnetization and polarization via magnetocapacitive effects, holds promise for new generations of electronic devices. Here we present measurements on a simple cubic spinel compound with unusual, and potentially useful, magnetic and electric properties: it shows ferromagnetic order coexisting with relaxor ferroelectricity (a ferroelectric cluster state with a smeared-out phase transition), both having sizable ordering temperatures and moments. Close to the ferromagnetic ordering temperature, the magnetocapacitive coupling (characterized by a variation of the dielectric constant in an external magnetic field) reaches colossal values, approaching 500 per cent. We attribute the relaxor properties to geometric frustration, which is well known for magnetic moments but here is found to impede long-range order of the structural degrees of freedom that drive the formation of the ferroelectric state.

436 citations

Journal ArticleDOI
TL;DR: In this paper, a detailed overview and discussion of the dielectric properties of CaCu3Ti4O12 and related transition-metal oxides with large dielectoric constants is provided.
Abstract: Many transition-metal oxides show very large (“colossal”) magnitudes of the dielectric constant and thus have immense potential for applications in modern microelectronics and for the development of new capacitance-based energy-storage devices In the present work, we thoroughly discuss the mechanisms that can lead to colossal values of the dielectric constant, especially emphasising effects generated by external and internal interfaces, including electronic phase separation In addition, we provide a detailed overview and discussion of the dielectric properties of CaCu3Ti4O12 and related systems, which is today’s most investigated material with colossal dielectric constant Also a variety of further transition-metal oxides with large dielectric constants are treated in detail, among them the system La2−xSrxNiO4 where electronic phase separation may play a role in the generation of a colossal dielectric constant

417 citations


Cited by
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28 Jul 2005
TL;DR: PfPMP1)与感染红细胞、树突状组胞以及胎盘的单个或多个受体作用,在黏附及免疫逃避中起关键的作�ly.
Abstract: 抗原变异可使得多种致病微生物易于逃避宿主免疫应答。表达在感染红细胞表面的恶性疟原虫红细胞表面蛋白1(PfPMP1)与感染红细胞、内皮细胞、树突状细胞以及胎盘的单个或多个受体作用,在黏附及免疫逃避中起关键的作用。每个单倍体基因组var基因家族编码约60种成员,通过启动转录不同的var基因变异体为抗原变异提供了分子基础。

18,940 citations

Journal ArticleDOI
17 Aug 2006-Nature
TL;DR: A ferroelectric crystal exhibits a stable and switchable electrical polarization that is manifested in the form of cooperative atomic displacements that arises through the quantum mechanical phenomenon of exchange.
Abstract: A ferroelectric crystal exhibits a stable and switchable electrical polarization that is manifested in the form of cooperative atomic displacements. A ferromagnetic crystal exhibits a stable and switchable magnetization that arises through the quantum mechanical phenomenon of exchange. There are very few 'multiferroic' materials that exhibit both of these properties, but the 'magnetoelectric' coupling of magnetic and electrical properties is a more general and widespread phenomenon. Although work in this area can be traced back to pioneering research in the 1950s and 1960s, there has been a recent resurgence of interest driven by long-term technological aspirations.

6,813 citations

Journal ArticleDOI
26 Mar 2013-ACS Nano
TL;DR: The properties and advantages of single-, few-, and many-layer 2D materials in field-effect transistors, spin- and valley-tronics, thermoelectrics, and topological insulators, among many other applications are highlighted.
Abstract: Graphene’s success has shown that it is possible to create stable, single and few-atom-thick layers of van der Waals materials, and also that these materials can exhibit fascinating and technologically useful properties. Here we review the state-of-the-art of 2D materials beyond graphene. Initially, we will outline the different chemical classes of 2D materials and discuss the various strategies to prepare single-layer, few-layer, and multilayer assembly materials in solution, on substrates, and on the wafer scale. Additionally, we present an experimental guide for identifying and characterizing single-layer-thick materials, as well as outlining emerging techniques that yield both local and global information. We describe the differences that occur in the electronic structure between the bulk and the single layer and discuss various methods of tuning their electronic properties by manipulating the surface. Finally, we highlight the properties and advantages of single-, few-, and many-layer 2D materials in...

4,123 citations

Journal ArticleDOI
TL;DR: In this article, the most characteristic properties of spin glass systems are described, and related phenomena in other glassy systems (dielectric and orientational glasses) are mentioned, and a review summarizes recent developments in the theory of spin glasses, as well as pertinent experimental data.
Abstract: This review summarizes recent developments in the theory of spin glasses, as well as pertinent experimental data. The most characteristic properties of spin glass systems are described, and related phenomena in other glassy systems (dielectric and orientational glasses) are mentioned. The Edwards-Anderson model of spin glasses and its treatment within the replica method and mean-field theory are outlined, and concepts such as "frustration," "broken replica symmetry," "broken ergodicity," etc., are discussed. The dynamic approach to describing the spin glass transition is emphasized. Monte Carlo simulations of spin glasses and the insight gained by them are described. Other topics discussed include site-disorder models, phenomenological theories for the frozen phase and its excitations, phase diagrams in which spin glass order and ferromagnetism or antiferromagnetism compete, the Ne\'el model of superparamagnetism and related approaches, and possible connections between spin glasses and other topics in the theory of disordered condensed-matter systems.

3,926 citations