Amelia Greig

Bio: Amelia Greig is an academic researcher from University of Texas at El Paso. The author has contributed to research in topics: Plasma & Argon. The author has an hindex of 8, co-authored 25 publications receiving 223 citations. Previous affiliations of Amelia Greig include California Polytechnic State University & University of Adelaide.

Plasma Catalytic Synthesis of Ammonia Using Functionalized-Carbon Coatings in an Atmospheric-Pressure Non-equilibrium Discharge

Abstract: We investigate the synthesis of ammonia in a non-equilibrium atmospheric-pressure plasma using functionalized-nanodiamond and diamond-like-carbon coatings on α-Al2O3 spheres as catalysts. Oxygenated nanodiamonds were found to increase the production yield of ammonia, while hydrogenated nanodiamonds decreased the yield. Neither type of nanodiamond affected the plasma properties significantly. Using diffuse-reflectance FT-IR and XPS, the role of different functional groups on the catalyst surface was investigated. Evidence is presented that the carbonyl group is associated with an efficient surface adsorption and desorption of hydrogen in ammonia synthesis on the surface of the nanodiamonds, and an increased production of ammonia. Conformal diamond-like-carbon coatings, deposited by plasma-enhanced chemical vapour deposition, led to a plasma with a higher electron density, and increased the production of ammonia.

Direct measurement of neutral gas heating in a radio-frequency electrothermal plasma micro-thruster

Abstract: Direct measurements and modelling of neutral gas heating in a radio-frequency (13.56 MHz) electrothermal collisional plasma micro-thruster have been performed using rovibrational band matching of the second positive system of molecular nitrogen (N2) for operating pressures of 4.5 Torr down to 0.5 Torr. The temperature measured with decreasing pressure for 10 W power input ranged from 395 K to 530 K in pure N2 and from 834 K to 1090 K in argon with 1% N2. A simple analytical model was developed which describes the difference in temperatures between the argon and nitrogen discharges.

Volume and surface propellant heating in an electrothermal radio-frequency plasma micro-thruster

Abstract: This research was partially funded by the Australian Space Research Program (APT project) and the Australian Research Council Discovery Project (No. DP140100571).

A Short Review of Experimental and Computational Diagnostics for Radiofrequency Plasma Micro-thrusters

Abstract: Experimental and computational diagnostics for radiofrequency plasma micro-thrusters are presented, based on the low power (10–100 W) electrothermal thruster prototype, Mini Pocket Rocket, developed for use on the Cubesat nanosatellite platform Computer simulations include computer fluid dynamics simulations and particle in cell simulations while experimental results are obtained using a variety of electrostatic, optical and momentum probes The output and limitations of each diagnostic are discussed within the context of device development for space use

Simulation of main plasma parameters of a cylindrical asymmetric capacitively coupled plasma micro-thruster using computational fluid dynamics

Abstract: Computational fluid dynamics (CFD) simulations of a radio-frequency (13.56 MHz) electro-thermal capacitively coupled plasma (CCP) micro-thruster have been performed using the commercial CFD-ACE+ package. Standard operating conditions of a 10 W, 1.5 Torr argon discharge were used to compare with previously obtained experimental results for validation. Results show that the driving force behind plasma production within the thruster is ion-induced secondary electrons ejected from the surface of the discharge tube, accelerated through the sheath to electron temperatures up to 33.5 eV. The secondary electron coefficient was varied to determine the effect on the discharge, with results showing that full breakdown of the discharge did not occur for coefficients coefficients less than or equal to 0.01.

Electric propulsion for satellites and spacecraft: established technologies and novel approaches

Abstract: This contribution presents a short review of electric propulsion (EP) technologies for satellites and spacecraft. Electric thrusters, also termed ion or plasma thrusters, deliver a low thrust level compared to their chemical counterparts, but they offer significant advantages for in-space propulsion as energy is uncoupled to the propellant, therefore allowing for large energy densities. Although the development of EP goes back to the 1960s, the technology potential has just begun to be fully exploited because of the increase in the available power aboard spacecraft, as demonstrated by the very recent appearance of all-electric communication satellites. This article first describes the fundamentals of EP: momentum conservation and the ideal rocket equation, specific impulse and thrust, figures of merit and a comparison with chemical propulsion. Subsequently, the influence of the power source type and characteristics on the mission profile is discussed. Plasma thrusters are classically grouped into three categories according to the thrust generation process: electrothermal, electrostatic and electromagnetic devices. The three groups, along with the associated plasma discharge and energy transfer mechanisms, are presented via a discussion of long-standing technologies like arcjet thrusters, magnetoplasmadynamic thrusters, pulsed plasma thrusters and ion engines, as well as Hall thrusters and variants. More advanced concepts and new approaches for performance improvement are discussed afterwards: magnetic shielding and wall-less configurations, negative ion thrusters and plasma acceleration with a magnetic nozzle. Finally, various alternative propellant options are analyzed and possible research paths for the near future are examined.

Plasma Technology: An Emerging Technology for Energy Storage

Abstract: Plasma technology is gaining increasing interest for gas conversion applications, such as CO2 conversion into value-added chemicals or renewable fuels, and N2 fixation from the air, to be used for the production of small building blocks for, e.g., mineral fertilizers. Plasma is generated by electric power and can easily be switched on/off, making it, in principle, suitable for using intermittent renewable electricity. In this Perspective article, we explain why plasma might be promising for this application. We briefly present the most common types of plasma reactors with their characteristic features, illustrating why some plasma types exhibit better energy efficiency than others. We also highlight current research in the fields of CO2 conversion (including the combined conversion of CO2 with CH4, H2O, or H2) as well as N2 fixation (for NH3 or NOx synthesis). Finally, we discuss the major limitations and steps to be taken for further improvement.

Overcoming ammonia synthesis scaling relations with plasma-enabled catalysis

Abstract: Correlations between the energies of elementary steps limit the rates of thermally catalysed reactions at surfaces. Here, we show how these limitations can be circumvented in ammonia synthesis by coupling catalysts to a non-thermal plasma. We postulate that plasma-induced vibrational excitations in N2 decrease dissociation barriers without influencing subsequent reaction steps. We develop a density-functional-theory-based microkinetic model to incorporate this effect, and parameterize the model using N2 vibrational excitations observed in a dielectric-barrier-discharge plasma. We predict plasma enhancement to be particularly great on metals that bind nitrogen too weakly to be active thermally. Ammonia synthesis rates observed in a dielectric-barrier-discharge plasma reactor are consistent with predicted enhancements and predicted changes in the optimal metal catalyst. The results provide guidance for optimizing catalysts for application with plasmas. Plasma catalysis holds promise for overcoming the limitations of conventional catalysis. Now, a kinetic model for ammonia synthesis is reported to predict optimal catalysts for use with plasmas. Reactor measurements at near-ambient conditions confirm the predicted catalytic rates, which are similar to those obtained in the Haber–Bosch process.

Catalysis Enabled by Plasma Activation of Strong Chemical Bonds: A Review

Abstract: Nonthermal plasma-driven catalysis is an emerging subfield of heterogeneous catalysis that is particularly promising for the chemical transformation of hard-to-activate molecules (e.g., N2, CO2, CH4). In this Review, we illustrate this promise of plasma-enhanced catalysis, focusing on the ammonia synthesis and methane dry reforming reactions, two reactions that have received wide attention and that illustrate the potential for plasma excitations to mitigate kinetic and thermodynamic obstacles to chemical conversions. We highlight how plasma activation of reactants can provide access to overall reaction rates, conversions, product yields, and/or product distributions unattainable by thermal catalysis at similar temperatures and pressures. Particular emphasis is given to efforts aimed at discerning the underlying mechanisms at play in these systems. We discuss opportunities for and challenges to the advancement of the field.