A
Andrew E. Derome
Researcher at University of Oxford
Publications - 38
Citations - 964
Andrew E. Derome is an academic researcher from University of Oxford. The author has contributed to research in topics: Nuclear magnetic resonance spectroscopy & Hydroxymethyl. The author has an hindex of 15, co-authored 38 publications receiving 943 citations.
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Journal ArticleDOI
Rapid-pulsing artifacts in double-quantum-filtered COSY
Journal ArticleDOI
Isolation from and x-ray crystal structure of alexine, (1r,2r,3r,7s,8s)-3-hydroxymethyl-1,2,7-trihydroxypyrrolizidine [(2r,3r,4r,5s,6s)-2-hydroxymethyl-1-azabicyclo[3.3.0]octan-3,4,6-triol], a unique pyrrolizidine alkaloid
Robert J. Nash,Linda E. Fellows,Janet V. Dring,George W. J. Fleet,Andrew E. Derome,T.A Hamor,A.M. Scofield,David J. Watkin +7 more
TL;DR: The isolation from Alexa leiopetala and identification by X-ray crystal structure analysis of (1R,2R,3R,4R,5S,6S)-2-hydroxymethyl-1-azabicyclo[3.3.0]octan-3,4,6-triol], a unique pyrrolizidine alkaloid, is described in this paper.
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Methyl 5-0--butyldiphenylsilyl-2-deoxy-α β -d--pentofuranoside as a divergent intermediate for the synthesis of 3'-substituted-2',3'-dideoxynucleosides: synthesis of 3'-azido-3'-deoxythymidine, 3'-deoxy-3'-fluorothymidine and 3'-cyano-3'-deoxythymidine.
TL;DR: The use of methyl 5-0- tert -butyldiphenylsilyl-2-deoxy-α, β -D- threo -pentofuranoside, prepared from D-xylose, as a divergent intermediate for the synthesis of 3'-substituted-2',3'-dideoxynucleosides is illustrated by its conversion into 3'-azido-3'-deoxythymidine, 3'-deoxy -3'-fluorothymidine and 3'-cyano-3]-deox
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Isolation from and x-ray crystal structure of 3,8-diepialexine, (1r,2r,3s,7s,8r)-3-hydroxymethyl-1,2,7-trihydroxypyrrolizidine [(2s,3r,4r,5s,6r)-2-hydroxymethyl-1-azabicyclo[3.3.0]octan-3,4,6-triol]
Robert J. Nash,Linda E. Fellows,A. C. Plant,George W. J. Fleet,Andrew E. Derome,Peter D. Baird,M.P. Hegarty,A.M. Scofield +7 more
TL;DR: In this paper, the isolation from Castanospermum australe and identification by X-ray crystal structure analysis of (1R,2R,3S,7S,8R)-3-hydroxymethyl-1,2,7-trihydroxypyrrolizidine [(2S,3R,4R,5S,6R)-2-hydronymethyl]-1-azabicyclo[3.3.0]octan-3,4,6-triol], the second example of a p
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Hexakis(trimethylphosphine)molybdenum chemistry: dinitrogen, ethylene, butadiene, η-cyclopentadienyl, and related derivatives
Maurice Brookhart,Kevin P. Cox,F. Geoffrey N. Cloke,Jennifer C. Green,Malcolm L. H. Green,Philip M. Hare,James K. Bashkin,Andrew E. Derome,Peter D. Grebenik +8 more
TL;DR: In this article, the rate constants and activation parameters for the hydrogen-scrambling process have been determined and a mechanism is proposed and the presence of the Mo-H-C bond is shown by low-temperature n.m. spectra.