Author
Andrey V. Gerasimenko
Other affiliations: Pedagogical University
Bio: Andrey V. Gerasimenko is an academic researcher from Russian Academy of Sciences. The author has contributed to research in topics: Crystal structure & Trigonal bipyramidal molecular geometry. The author has an hindex of 16, co-authored 212 publications receiving 1305 citations. Previous affiliations of Andrey V. Gerasimenko include Pedagogical University.
Papers published on a yearly basis
Papers
More filters
TL;DR: Two new cytotoxic tetrabromodibenzo-p-dioxins were isolated from an Australian marine sponge Dysidea dendyi and established by 1D and 2D NMR spectroscopy, X-ray analysis, and synthesis of the methyl ether of spongiadioxin B from diphenyl ether isolated from dysidea herbacea.
Abstract: Two new cytotoxic tetrabromodibenzo-p-dioxins, spongiadioxins A (1) and B (2), were isolated from an Australian marine sponge Dysidea dendyi. The structures of these compounds were established by 1D and 2D NMR spectroscopy, X-ray analysis of the methyl ether of spongiadioxin A (3), and synthesis of the methyl ether of spongiadioxin B (4) from diphenyl ether (9) isolated from Dysidea herbacea.
61 citations
TL;DR: In this paper, the structural inequivalence of the unit cell of the PmDtc cadmium(II) complex was investigated by means of 15N, 113Cd CP/MAS NMR spectroscopy and single-crystal X-ray diffraction.
41 citations
TL;DR: In this article, a polycrystalline lead(II) complexes with O,O′-dipropyl- and O, O′-di-cyclo-hexyldithiophosphate ions were prepared and studied by means of 31P, 31C CP/MAS NMR spectroscopy and single-crystal X-ray diffraction.
37 citations
TL;DR: In this article, four novel heteropolynuclear and polynuclear complexes of the general formulae [Au(S2CNR2)2]2X (X = [CdCl4]2−, R = CH3 (1); X = Cd2Cl6]2+, R= C3H7 (2); R = C4H9 (3); R= CH3(4);
35 citations
Cited by
More filters
TL;DR: This review covers the literature published in 2014 for marine natural products, with 1116 citations referring to compounds isolated from marine microorganisms and phytoplankton, green, brown and red algae, sponges, cnidarians, bryozoans, molluscs, tunicates, echinoderms, mangroves and other intertidal plants and microorganisms.
4,649 citations
TL;DR: The geometries of 131 SBUs, their connectivity and composition of transition-metal carboxylate clusters which may serve as secondary building units (SBUs) towards construction and synthesis of metal-organic frameworks (MOFs).
Abstract: This critical review presents a comprehensive study of transition-metal carboxylate clusters which may serve as secondary building units (SBUs) towards construction and synthesis of metal–organic frameworks (MOFs). We describe the geometries of 131 SBUs, their connectivity and composition. This contribution presents a comprehensive list of the wide variety of transition-metal carboxylate clusters which may serve as secondary building units (SBUs) in the construction and synthesis of metal–organic frameworks. The SBUs discussed here were obtained from a search of molecules and extended structures archived in the Cambridge Structure Database (CSD, version 5.28, January 2007) which included only crystals containing metal carboxylate linkages (241 references).
2,145 citations
TL;DR: In 1981, the macrocyclic methylene-bridged glycoluril hexamer (CB[6]) was dubbed "cucurbituril" by Mock and co-workers because of its resemblance to the most prominent member of the cucurbitaceae family of plants--the pumpkin.
Abstract: In 1981, the macrocyclic methylene-bridged glycoluril hexamer (CB[6]) was dubbed "cucurbituril" by Mock and co-workers because of its resemblance to the most prominent member of the cucurbitaceae family of plants--the pumpkin. In the intervening years, the fundamental binding properties of CB[6]-high affinity, highly selective, and constrictive binding interactions--have been delineated by the pioneering work of the research groups of Mock, Kim, and Buschmann, and has led to their applications in waste-water remediation, as artificial enzymes, and as molecular switches. More recently, the cucurbit[n]uril family has grown to include homologues (CB[5]-CB[10]), derivatives, congeners, and analogues whose sizes span and exceed the range available with the alpha-, beta-, and gamma-cyclodextrins. Their shapes, solubility, and chemical functionality may now be tailored by synthetic chemistry to play a central role in molecular recognition, self-assembly, and nanotechnology. This Review focuses on the synthesis, recognition properties, and applications of these unique macrocycles.
2,074 citations
921 citations
TL;DR: Cucurbit[n]urils have become key units in various self-organizing and stimulus-controlled assemblies, as well as in advanced materials and drug carriers.
Abstract: This review highlights the past six year advances in the blossoming field of cucurbit[n]uril chemistry. Because of their exceptional recognition properties in aqueous medium, these pumpkin-shaped macrocycles have been generating some tremendous interest in the supramolecular community. They have also become key units in various self-organizing and stimulus-controlled assemblies, as well as in advanced materials and drug carriers. The scope of this review is limited to the main family of cucurbit[n]urils (n = 5, 6, 7, 8, 10). The reader will find an overview of their preparation, their physicochemical and biological properties, as well as their recognition abilities towards various organic and inorganic guests. Detailed thermodynamic and kinetic considerations, as well as multiple applications including supramolecular catalysis are also discussed.
792 citations