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Author

Anshu Bhati

Bio: Anshu Bhati is an academic researcher from Malaviya National Institute of Technology, Jaipur. The author has contributed to research in topics: Photodegradation & Carbon black. The author has an hindex of 16, co-authored 19 publications receiving 728 citations.
Topics: Photodegradation, Carbon black, Carbon, Zinc, Biochar

Papers
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Journal ArticleDOI
TL;DR: In this paper, a straightforward and simpler use of an age-old technique was utilized for the fabrication of "red-emitting magnesium-nitrogen-embedded carbon dots" (r-Mg-N-CD) from the leaves extract of Bougainvillea plant as a natural source of carbon.
Abstract: A straightforward and simpler use of an age-old technique was utilized for the fabrication of “red-emitting magnesium-nitrogen-embedded carbon dots” (r-Mg-N-CD) from the leaves extract of Bougainvillea plant as a natural source of carbon. This technique is similar to the solvent-based technique, which is used for the extraction of fragrances and essential oils from flowers and leaves. The as-derived leaves extract was further carbonized using a simple domestic microwave to obtain the small-sized red-emitting carbonaceous material as r-Mg-N-CD. The r-Mg-N-CD showed excitation-independent emissions at ∼678 nm with excellent photostability and a high quantum yield value (∼40%). Moreover, the important perspective of the present finding is to use this r-Mg-N-CD as a potential photocatalyst material for the degradation of pollutant dye (methylene blue) under the presence of sunlight. To infer the significant influence of using natural sunlight in the process of dye degradation, a comparative analysis was perfo...

107 citations

Journal ArticleDOI
TL;DR: The overall sustainability of the presented work holds the potential for the utilization of pollutant soot in real-practical applications related to the wastewater remediation and further the practical uses of treated water.
Abstract: Currently, the air and water pollutions are presenting the most serious global concerns. Despite the well known tremendous efforts, it could be a promising sustainability if the black carbon (BC) soot can be utilized for the practical and sustainable applications. For this, the almost complete aqueous phase photodegradation of the three well-known organic pollutant dyes as crystal violet (CV); rhodamine B (RhB); methylene blue (MB) and their mixture (CV + RhB + MB), by using water-soluble graphene nanosheets (wsGNS) isolated from the BC soot under the influence of natural sunlight is described. The plausible mechanism behind the photocatalytic degradation of dyes and their mixture has been critically analyzed via the trapping of active species and structural analysis of photodegraded products. The impact of diverse interfering ions like Ca2+, Fe3+, SO42−, HPO42−, NO3−, and Cl− on the photodegradation efficiency of wsGNS was also investigated. Importantly, the environmental assessment of the whole process has been evaluated towards the growth of wheat plants using the treated wastewater. The initial studies for the fifteen days confirmed that growth of wheat plants was almost the same in the photodegraded wastewater as being noticed in the control sample, while in case of dyes contaminated water it showed the retarded growth. Using the natural sunlight, the overall sustainability of the presented work holds the potential for the utilization of pollutant soot in real-practical applications related to the wastewater remediation and further the practical uses of treated water.

100 citations

Journal ArticleDOI
TL;DR: In this paper, a potential approach is described for assessing the ecological importance of graphitic nanocarbons isolated from dirty, dangerous black pollutant particulate material, and a simple experiment of photodegradation and a toxicological test were done using the natural sunlight as a source of energy and the pollutant petrol soot derived water-soluble graphene nanosheets (wsGNS) as photocatalyst to achieve complete degradation of pollutant organic dye as methylene blue (MB).
Abstract: Herein, a potential approach is described for assessing the ecological importance of the graphitic nanocarbons isolated from dirty, dangerous black pollutant particulate material. A simple experiment of photodegradation and a toxicological test were done using the natural sunlight as a source of energy and the pollutant petrol soot derived water-soluble graphene nanosheets (wsGNS) as photocatalyst to achieve complete degradation of pollutant organic dye as methylene blue (MB). Compared to the artificial source of visible light (60W tungsten bulb), the sunlight-induced photodegradation using wsGNS show ∼1.5 times higher rate of photodegradation. The toxicological test confirmed the nontoxic behavior of wsGNS against the two different types of bacterial strains: Gram-negative and Gram-positive cells, Escherichia coli and Staphylococcus aureus, respectively. Moreover, wsGNS are precisely used for the selective photodegradation of MB without harming the bacterial growth from the pool of MB-bacterial strains. ...

95 citations

Journal ArticleDOI
20 May 2019
TL;DR: In this article, a single-step technique for the synthesis of nitrogen-phosphorus doped fluorescent carbon dots (NP-CD) using a domestic microwave was reported for the quantitative reduction of Cr(VI) to Cr(III) in synthetic contaminated water, in a linear range from 10 ppm (in approximately 10 min) to 2000 ppm by increasing the sunlight irradiation time followed by its removal by precipitation.
Abstract: Cr(VI) is a known toxic and non-biodegradable pollutant that results from multiple industrial processes, and can cause significant environmental damage if it is not removed from wastewater. However, it can be reduced to Cr(III), which is less toxic and can be readily precipitated out and removed. Here, a fast and facile single-step technique is reported for the synthesis of nitrogen–phosphorus doped fluorescent carbon dots (NP-CD) using a domestic microwave, as a potential photocatalytic material. Under natural sunlight, a simple photocatalytic experiment reveals that the NP-CD are highly efficient for the quantitative reduction of Cr(VI) to Cr(III) in synthetic contaminated water, in a linear range from 10 ppm (in approximately 10 min) to 2000 ppm (in approximately 320 min) by increasing the sunlight irradiation time followed by its removal by precipitation. NP-CD exhibit high recyclability of up to six cycles without any apparent loss in photocatalytic activity, demonstrating NP-CD as a potential photocatalyst material for Cr(VI) water treatment.

94 citations

Journal ArticleDOI
14 May 2018
TL;DR: The present finding deals with a simple and low-cost fabrication of surface-passivated, brightly fluorescent zinc-oxide-decorated, red-emitting excitation-independent ultrafluorescent CDs, denoted as “CZnO-Dots”.
Abstract: The present finding deals with a simple and low-cost fabrication of surface-passivated, brightly fluorescent zinc-oxide-decorated, red-emitting excitation-independent ultrafluorescent CDs, denoted as “CZnO-Dots”. Surface doping of zinc oxide significantly improved the quantum yield by up to ∼72%, and these brightly fluorescent red-emitting CZnO-Dots have been employed for the aqueous-phase photoreduction of 100 ppm hexavalent chromium(VI) to trivalent chromium(III) under the influence of sunlight irradiation. The overall utility of the prepared CZnO-Dots can be ascertained by their recyclability over seven cycles.

89 citations


Cited by
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Journal Article
01 Jan 2008-Nature
TL;DR: It is shown that bright fluorescent nanodiamonds can be produced in large quantities by irradiating synthetic diamond nanocrystallites with helium ions, and the fluorescence is sufficiently bright and stable to allow three-dimensional tracking of a single particle within the cell by means of either one- or two-photon-excited fluorescence microscopy.
Abstract: Fluorescent nanodiamond is a new nanomaterial that possesses several useful properties, including good biocompatibility1, excellent photostability1,2 and facile surface functionalizability2,3. Moreover, when excited by a laser, defect centres within the nanodiamond emit photons that are capable of penetrating tissue, making them well suited for biological imaging applications1,2,4. Here, we show that bright fluorescent nanodiamonds can be produced in large quantities by irradiating synthetic diamond nanocrystallites with helium ions. The fluorescence is sufficiently bright and stable to allow three-dimensional tracking of a single particle within the cell by means of either one- or two-photon-excited fluorescence microscopy. The excellent photophysical characteristics are maintained for particles as small as 25 nm, suggesting that fluorescent nanodiamond is an ideal probe for long-term tracking and imaging in vivo, with good temporal and spatial resolution.

643 citations

Journal ArticleDOI
TL;DR: It is concluded that nanotechnology offers a plethora of opportunities, by providing a novel and sustainable alternative in the food and agriculture sectors by providing the potential application of bio-synthesized and bio-inspired nanomaterial for sustainable development.

468 citations

Journal ArticleDOI
TL;DR: Carbon quantum dots as discussed by the authors are a type of spherical or sphere-like nanoparticles of less than 10 nm in size and have been subsequently named as carbon quantum dots or carbon nanodots.
Abstract: Small carbon nanoparticles are an emerging member of the carbonaceous nanomaterial family and have been subsequently named as “carbon quantum dots” or “carbon nanodots”. Generally, carbon quantum dots are a type of spherical or sphere-like nanoparticles of less than 10 nm in size. Due to their unique properties, for example, size-dependent fluorescence, non-toxicity, biocompatibility, and easy accessibility, carbon quantum dots possess a great many potential applications in a range of fields from chemical sensing and imaging to catalysis and drug delivery, and thus are appealing to a number of researchers in nanoscience and nanotechnology. In this review, we give a brief introduction of the synthesis and fundamental properties of carbon quantum dots, then present their applications in metal ion sensing in detail along with illustrating the related mechanisms, and finally come up with some challenges currently faced and future outlooks for this fascinating carbon material. We hope this review could be helpful for readers who are preparing to join and/or have joined the research field of carbon quantum dots.

386 citations

Journal ArticleDOI
TL;DR: In this paper, water soluble carbon quantum dots (wsCQDs) were synthesized from lemon peel waste using a facile and cost effective hydrothermal process and an economic, green and highly sensitive fluorescent probe was designed for the detection of Cr6+ ions with a detection limit of ∼73 nM.
Abstract: In this work, water soluble carbon quantum dots (wsCQDs) were synthesized from lemon peel waste using a facile and cost effective hydrothermal process. As synthesized wsCQDs were 1–3 nm in size with spherical morphology and oxygen rich surface functionalities. These wsCQDs manifest excellent photoluminescence (PL) properties and exhibited quantum yield (QY) ∼14% with high aqueous stability. wsCQDs were further used to design an economic, green and highly sensitive fluorescent probe for the detection of Cr6+ ions with a detection limit of ∼73 nM. This wsCQDs based fluorescent probe could provide a simple, rapid, convenient technique for the sensitive and selective detection of Cr6+ in water purification processes. Further, wsCQDs were immobilized over electrospun TiO2 nanofibers and the photocatalytic activity for such a TiO2–wsCQDs composite was demonstrated using methylene blue (MB) dye as a model pollutant. Photocatalytic activity for the TiO2–wsCQDs composite was found to be ∼2.5 times more than that of TiO2 nanofibers. The synthesis method for wsCQDs could be easily scaled up for gram scale synthesis of carbon quantum dots.

299 citations

Journal ArticleDOI
TL;DR: The cytotoxicity results showed that the CDs exhibit non toxicity within 100μg/mL, indicating that they are promising fluorescent probes for biological imaging and successfully applied for Fe3+ probing in living cells.

241 citations