Anwar Ahniyaz

Bio: Anwar Ahniyaz is an academic researcher from Research Institutes of Sweden. The author has contributed to research in topics: Nanoparticle & Hydrothermal circulation. The author has an hindex of 21, co-authored 47 publications receiving 1519 citations. Previous affiliations of Anwar Ahniyaz include Stockholm University & SP Technical Research Institute of Sweden.

Magnetic Field-Induced Assembly of Oriented Superlattices from Maghemite Nanocubes

Abstract: Tailoring the structure of nanocrystal superlattices is an important step toward controlled design of novel nanostructured materials and devices. We demonstrate how the long-range order and macroscopic dimensions of magnetic nanoparticle arrays can be controlled by the use of a modulated magnetic field. Inducing a dipolar attraction during the initial stage of the drying-mediated self-assembly process was sufficient to assemble the superparamagnetic oleate-capped maghemite nanocubes into large and defect-free superstructures with both translational and orientational order. The characteristic dimensions of the superlattice are controlled by the particle concentration as well as the duration of the applied magnetic field. The superparamagnetic maghemite nanocubes assemble into large and highly oriented thin arrays by applying the magnetic field perpendicular to the substrate surface only during the initial phase of drying-mediated self-assembly. Micrometer-sized and thick three-dimensional mesocrystals are obtained when the drying dispersion is subjected to an external magnetic field of moderate strength for the entire duration of the assembly process. The discovery of how translational and orientation order of nanocrystal superlattices can be induced by a temporal modulation of an anisotropic interparticle force offers new insight on the importance of the initial nucleation stage in the self-assembly process and suggests new routes for controlled self-assembly of dipolar nanocrystals.

Properties and emerging applications of self-assembled structures made from inorganic nanoparticles

Abstract: Just as nanoparticles display properties that differ from those of bulk samples of the same material, ensembles of nanoparticles can have collective properties that are different to those displayed by individual nanoparticles and bulk samples. Self-assembly has emerged as a powerful technique for controlling the structure and properties of ensembles of inorganic nanoparticles. Here we review different strategies for nanoparticle self-assembly, the properties of self-assembled structures of nanoparticles, and potential applications of such structures. Many of these properties and possible applications rely on our ability to control the interactions between the electronic, magnetic and optical properties of the individual nanoparticles. Self-assembly is a powerful technique for controlling the structure and properties of ensembles of inorganic nanoparticles. This article reviews the properties and potential applications of self-assembled structures made from nanoparticles.

Nanoscale Forces and Their Uses in Self‐Assembly

Abstract: The ability to assemble nanoscopic components into larger structures and materials depends crucially on the ability to understand in quantitative detail and subsequently "engineer" the interparticle interactions. This Review provides a critical examination of the various interparticle forces (van der Waals, electrostatic, magnetic, molecular, and entropic) that can be used in nanoscale self-assembly. For each type of interaction, the magnitude and the length scale are discussed, as well as the scaling with particle size and interparticle distance. In all cases, the discussion emphasizes characteristics unique to the nanoscale. These theoretical considerations are accompanied by examples of recent experimental systems, in which specific interaction types were used to drive nanoscopic self-assembly. Overall, this Review aims to provide a comprehensive yet easily accessible resource of nanoscale-specific interparticle forces that can be implemented in models or simulations of self-assembly processes at this scale.

Magnetically Separable Nanocatalysts: Bridges between Homogeneous and Heterogeneous Catalysis

Abstract: Recovery and reuse of expensive catalysts after catalytic reactions are important factors for sustainable process management. The aim of this Review is to highlight the progress in the formation and catalytic applications of magnetic nanoparticles and magnetic nanocomposites. Directed functionalization of the surfaces of nanosized magnetic materials is an elegant way to bridge the gap between heterogeneous and homogeneous catalysis. The introduction of magnetic nanoparticles in a variety of solid matrices allows the combination of well-known procedures for catalyst heterogenization with techniques for magnetic separation.