Author
Aude Rothschild
Bio: Aude Rothschild is an academic researcher from Weizmann Institute of Science. The author has contributed to research in topics: Oxide & Nanotube. The author has an hindex of 8, co-authored 8 publications receiving 806 citations.
Topics: Oxide, Nanotube, Scanning probe microscopy, Transition metal, Plasmon
Papers
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TL;DR: In this paper, a detailed study of the growth mechanism of WS2 nanotubes has been undertaken, which is reported hereby, and a series of experiments were conducted to define the key parameters, which determine the shape of the WS2 Nanotubes.
Abstract: Recently, a method to produce bulk quantities of pure multiwall WS2 nanotubes, which could reach several microns in length, has been developed. A detailed study of the growth mechanism of these WS2 nanotubes has been undertaken, which is reported hereby. A series of experiments were conducted to define the key parameters, which determine the shape of the WS2 nanotubes. An alternative approach for the synthesis of WS2 nanotubes, starting from long WO3-x nanowhiskers, which can be extended for the synthesis of other nanotubes, is described as well.
212 citations
TL;DR: In this paper, a detailed study of the growth mechanism of WS2 nanotubes has been undertaken, which is reported hereby, and a series of experiments were conducted to define the key parameters, which determine the shape of the WS2 Nanotubes.
Abstract: Recently, a method to produce bulk quantities of pure multiwall WS2 nanotubes, which could reach several microns in length, has been developed. A detailed study of the growth mechanism of these WS2 nanotubes has been undertaken, which is reported hereby. A series of experiments were conducted to define the key parameters, which determine the shape of the WS2 nanotubes. An alternative approach for the synthesis of WS2 nanotubes, starting from long WO3-x nanowhiskers, which can be extended for the synthesis of other nanotubes, is described as well.
185 citations
TL;DR: In this article, the reduced tungsten oxide phases were previously studied by a combination of techniques, including high-resolution transmission electron microscopy and X-ray diffraction, combined with the previous two techniques is used to give further detail concerning the structure of the reduced oxide phases.
164 citations
TL;DR: WS2 nanotubes were attached to microfabricated Si tips and tested afterwards in an atomic force microscope by imaging a "replica" of high aspect ratio, ie, deep and narrow grooves as discussed by the authors.
Abstract: WS2 nanotubes a few microns long were attached to microfabricated Si tips and tested afterwards in an atomic force microscope by imaging a “replica” of high aspect ratio, ie, deep and narrow grooves These WS2 nanotube tips provide a considerable improvement in image quality for such structures when compared with commercial ultrasharp Si tips The nanotube tip apex shape was extracted by blind reconstruction from an image of Ti spikes, showing a smooth cylindrical profile up to the end
109 citations
TL;DR: The intriguing fact that, for the anisotropic case, one can relate these modes to the interband transition of the in-plane component of the dielectric tensor and to the bulk-plasmon energy of the out-of- plane component is pointed out.
Abstract: We report on the investigation of surface-plasmon excitation of anisotropic WS(2) hollow nanoparticles in a near-field geometry by means of a scanning transmission electron microscope. The shell thickness influence on the electron-energy-loss-spectroscopy spectra is experimentally observed and is analyzed within a classical dielectric formalism. As for the isotropic case, we evidence one symmetric (tangential) and one antisymmetric (radial) mode. We point out the intriguing fact that, for the anisotropic case, one can relate these modes to the interband transition of the in-plane component of the dielectric tensor and to the bulk-plasmon energy of the out-of-plane component.
63 citations
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TL;DR: This work aims to prepare graphene-like MoS2 and WS2, which are quasi-two-dimensional compounds in which the atoms within the layer are held together by strong covalent forces while van der Waals interaction enables stacking of the layers.
Abstract: Inorganic sheets: Graphene-like MoS2 and WS2 were prepared by three different chemical methods. Examination by microscopic techniques revealed that they consist of one or a few layers (see depicted TEM image of WS2 layers), and an atomic-resolution TEM image showed that layered MoS2 has a hexagonal arrangement of Mo and S atoms (see inset).
1,541 citations
TL;DR: In this paper, a quantum-mechanical description of the interaction between the electrons and the sample is discussed, followed by a powerful classical dielectric approach that can be in practice applied to more complex systems.
Abstract: This review discusses how low-energy, valence excitations created by swift electrons can render information on the optical response of structured materials with unmatched spatial resolution. Electron microscopes are capable of focusing electron beams on sub-nanometer spots and probing the target response either by analyzing electron energy losses or by detecting emitted radiation. Theoretical frameworks suited to calculate the probability of energy loss and light emission (cathodoluminescence) are revisited and compared with experimental results. More precisely, a quantum-mechanical description of the interaction between the electrons and the sample is discussed, followed by a powerful classical dielectric approach that can be in practice applied to more complex systems. We assess the conditions under which classical and quantum-mechanical formulations are equivalent. The excitation of collective modes such as plasmons is studied in bulk materials, planar surfaces, and nanoparticles. Light emission induced by the electrons is shown to constitute an excellent probe of plasmons, combining sub-nanometer resolution in the position of the electron beam with nanometer resolution in the emitted wavelength. Both electron energy-loss and cathodoluminescence spectroscopies performed in a scanning mode of operation yield snap shots of plasmon modes in nanostructures with fine spatial detail as compared to other existing imaging techniques, thus providing an ideal tool for nanophotonics studies.
1,288 citations
TL;DR: In this article, the authors provide an overview of recent research and significant advances reported in the literature, covering from synthesis to properties and to applications especially in energy conversion and storage, such as lithium-ion batteries, solar cells, fuel cells and piezoelectric nanogenerators.
Abstract: Metal sulfide nanomaterials have attracted great attention because of their excellent properties and promising applications in electronic, optical and optoelectronic devices. Well-aligned nanostructure arrays on substrates are highly attractive for their enhanced properties and novel applications. The general solution route and thermal evaporation under controlled conditions have been utilized for oriented growth of various metal sulfide nanostructure arrays and demonstrated their applications in energy conversion and storage. The article provides an overview of recent research and significant advances reported in the literature, covering from synthesis to properties and to applications especially in energy conversion and storage, such as lithium-ion batteries, solar cells, fuel cells and piezoelectric nanogenerators.
546 citations
TL;DR: In this paper, the basic physics of the relevant interfacial forces to nanoparticles and the main measuring techniques are briefly introduced first, then, the theories and important results of the mechanical properties between nanoparticles or the nanoparticles acting on a surface, e.g., hardness, elastic modulus, adhesion and friction, as well as movement laws are surveyed.
Abstract: The special mechanical properties of nanoparticles allow for novel applications in many fields, e.g., surface engineering, tribology and nanomanufacturing/nanofabrication. In this review, the basic physics of the relevant interfacial forces to nanoparticles and the main measuring techniques are briefly introduced first. Then, the theories and important results of the mechanical properties between nanoparticles or the nanoparticles acting on a surface, e.g., hardness, elastic modulus, adhesion and friction, as well as movement laws are surveyed. Afterwards, several of the main applications of nanoparticles as a result of their special mechanical properties, including lubricant additives, nanoparticles in nanomanufacturing and nanoparticle reinforced composite coating, are introduced. A brief summary and the future outlook are also given in the final part. (Some figures may appear in colour only in the online journal)
483 citations
TL;DR: The polar surface-dominated ZnO nanobelts are likely to be an ideal system for understanding piezoelectricity and polarization-induced ferroelectricity at nano-scale and they could have applications as one-dimensional nano- scale sensors, transducers, and resonators.
Abstract: Nanobelt is a quasi-one-dimensional structurally controlled nanomaterial that has well-defined chemical composition, crystallographic structure, and surfaces (e.g., growth direction, top/bottom surface, and side surfaces). This article reviews the nanobelt family of functional oxides, including ZnO, SnO2, In2O3, Ga2O3, CdO, and PbO2 and the relevant hierarchical and complex nanorods and nanowires that have been synthesized by a solid-vapor process. The nanobelts are single crystalline and dislocation free, and their surfaces are atomically flat. The oxides are semiconductors that have been used for fabrication of nanosize functional devices of key importance for nanosystems and biotechnology, such as field-effect transistors, gas sensors, nanoresonators, and nanocantilevers. The structurally controlled ZnO nanobelts that exhibit piezoelectric properties are also reviewed. By controlling growth kinetics, we show the success of growing nanobelt-based novel structures whose surfaces are dominated by the polarized +-(0001) facets. Owing to the positive and negative ionic charges on the zinc- and oxygen-terminated +-(0001) surfaces, respectively, a spontaneous polarization is induced across the nanobelt thickness. As a result, helical nanostructures and nanorings are formed by rolling up single-crystal nanobelts; this phenomenon is a consequence of minimizing the total energy contributed by spontaneous polarization and elasticity. The polar surface-dominated ZnO nanobelts are likely to be an ideal system for understanding piezoelectricity and polarization-induced ferroelectricity at nano-scale and they could have applications as one-dimensional nano-scale sensors, transducers, and resonators.
440 citations