Bei Zhang

Bio: Bei Zhang is an academic researcher from Peking University. The author has contributed to research in topics: Light-emitting diode & Gallium nitride. The author has an hindex of 14, co-authored 56 publications receiving 1808 citations.

Ultraviolet-emitting ZnO nanowires synthesized by a physical vapor deposition approach

Abstract: ZnO nanowires were mass produced using a physical vapor deposition approach. The ZnO nanowire monocrystallites have an average diameter around 60 nm and length up to a few micrometers. The unidirectional growth of the ZnO nanowires was controlled by the conventional vapor-liquid-solid mechanism. Intensive UV light emission peaked around 3.27 eV was observed at room temperature, which was assigned to emission from free exciton under low excitation intensity. The observed room temperature UV emission was ascribed to the decrease in structure defects as compared to bulk ZnO materials, and in particularly to the size effect in the ZnO wires.

GaN-based light-emitting diodes with photonic crystals structures fabricated by porous anodic alumina template

Abstract: In this paper, we propose and demonstrate a convenient and flexible approach for preparation large-area of photonic crystals (PhCs) structures on the GaN-based LED chip. The highly-ordered porous anodic alumina (AAO) with pitch of wavelength scale was adopted as a selective dry etching mask for PhCs-pattern transfer. The PhCs with different pore depths were simultaneously formed on the entire surfaces of GaN-based LED chip including ITO, GaN surrounding contacts and the sidewall of the mesa by one-step reactive ion etching (RIE). The light output power improvement of PhCs-based GaN LED was achieved as high as 94% compared to that of the conventional GaN-based LED.

Improvement of Light Extraction From Patterned Polymer Encapsulated GaN-Based Flip-Chip Light-Emitting Diodes by Imprinting

Abstract: To improve surface light extraction of GaN-based flip-chip light-emitting diodes (FC-LEDs), we employed an imprint approach of thermosetting polymer for patterning microscale surface grating on the polymer encapsulant. One-dimensional (1-D) and two-dimensional (2-D) taper-like polymer gratings with a period of 6 mum were successfully realized on encapsulant above the sapphire backplane of GaN LED. By adopting the 1-D and 2-D taper-like grating encapsulant, the improvement of light extraction from the 1 mm times 1 mm FC-blue LED with a reflective Ag film on the p-side was about 18.5% and 31.9% compared to the LED encapsulated by flat polymer, respectively. To evaluate the concept of a diffraction grating in enhancement of light extraction, we performed a simulation of diffraction based on 1-D rigorous coupled wave analysis with the supporting experiments.

Langmuir−Blodgett Films and Photophysical Properties of a C60−Sarcosine Methyl Ester Derivative, C60(C5H9NO2)

Abstract: A new C60−sarcosine methyl ester derivative, C60(C5H9NO2) (1), was prepared, and its Langmuir films with and without dioctadecyldimethylammonium bromide (DODMAB) were formed at the air/water interface. Pure 1 forms monolayer or multilayer films depending on the experimental conditions. The 1:1 mixed Langmuir film of 1 and DODMAB was transferred onto hydrophilic quartz substrates both in Z and Y type. Macroscopic second-harmonic generation from the mixed LB film was observed, and the second-order molecular susceptibility χ(2) and hyperpolarizability β were evaluated to be (2.1 ± 0.8) × 10-7 and (1.2 ± 0.4) × 10-28 esu. The first observations of room-temperature photoluminescence of 1 from both the mixed LB film and its CHCl3 solution and its fluorescence quenching by concentration and N,N-dimethylaniline (DMA) were reported. Its singlet energy is estimated to be 40.2 kcal/mol. Its fluorescence lifetime in CHCl3 solution is determined to be 1.0 ± 0.3 ns using the frequency-domain method.

Chemistry and properties of nanocrystals of different shapes.

Abstract: The interest in nanoscale materials stems from the fact that new properties are acquired at this length scale and, equally important, that these properties * To whom correspondence should be addressed. Phone, 404-8940292; fax, 404-894-0294; e-mail, mostafa.el-sayed@ chemistry.gatech.edu. † Case Western Reserve UniversitysMillis 2258. ‡ Phone, 216-368-5918; fax, 216-368-3006; e-mail, burda@case.edu. § Georgia Institute of Technology. 1025 Chem. Rev. 2005, 105, 1025−1102

Fundamentals of zinc oxide as a semiconductor

Abstract: In the past ten years we have witnessed a revival of, and subsequent rapid expansion in, the research on zinc oxide (ZnO) as a semiconductor. Being initially considered as a substrate for GaN and related alloys, the availability of high-quality large bulk single crystals, the strong luminescence demonstrated in optically pumped lasers and the prospects of gaining control over its electrical conductivity have led a large number of groups to turn their research for electronic and photonic devices to ZnO in its own right. The high electron mobility, high thermal conductivity, wide and direct band gap and large exciton binding energy make ZnO suitable for a wide range of devices, including transparent thin-film transistors, photodetectors, light-emitting diodes and laser diodes that operate in the blue and ultraviolet region of the spectrum. In spite of the recent rapid developments, controlling the electrical conductivity of ZnO has remained a major challenge. While a number of research groups have reported achieving p-type ZnO, there are still problems concerning the reproducibility of the results and the stability of the p-type conductivity. Even the cause of the commonly observed unintentional n-type conductivity in as-grown ZnO is still under debate. One approach to address these issues consists of growing high-quality single crystalline bulk and thin films in which the concentrations of impurities and intrinsic defects are controlled. In this review we discuss the status of ZnO as a semiconductor. We first discuss the growth of bulk and epitaxial films, growth conditions and their influence on the incorporation of native defects and impurities. We then present the theory of doping and native defects in ZnO based on density-functional calculations, discussing the stability and electronic structure of native point defects and impurities and their influence on the electrical conductivity and optical properties of ZnO. We pay special attention to the possible causes of the unintentional n-type conductivity, emphasize the role of impurities, critically review the current status of p-type doping and address possible routes to controlling the electrical conductivity in ZnO. Finally, we discuss band-gap engineering using MgZnO and CdZnO alloys.

Zinc Oxide-From Synthesis to Application: A Review.

Abstract: Zinc oxide can be called a multifunctional material thanks to its unique physical and chemical properties. The first part of this paper presents the most important methods of preparation of ZnO divided into metallurgical and chemical methods. The mechanochemical process, controlled precipitation, sol-gel method, solvothermal and hydrothermal method, method using emulsion and microemulsion enviroment and other methods of obtaining zinc oxide were classified as chemical methods. In the next part of this review, the modification methods of ZnO were characterized. The modification with organic (carboxylic acid, silanes) and inroganic (metal oxides) compounds, and polymer matrices were mainly described. Finally, we present possible applications in various branches of industry: rubber, pharmaceutical, cosmetics, textile, electronic and electrotechnology, photocatalysis were introduced. This review provides useful information for specialist dealings with zinc oxide.

Light-emitting diodes

Abstract: Light-Emitting Diodes. (Monographs in Electrical and Electronic Engineering.) By A. A. Bergh and P. J. Dean. Pp. viii+591. (Clarendon: Oxford; Oxford University: London, 1976.) £22.