Graphene is a rapidly rising star on the horizon of materials science and condensed-matter physics. This strictly two-dimensional material exhibits exceptionally high crystal and electronic quality, and, despite its short history, has already revealed a cornucopia of new physics and potential applications, which are briefly discussed here. Whereas one can be certain of the realness of applications only when commercial products appear, graphene no longer requires any further proof of its importance in terms of fundamental physics. Owing to its unusual electronic spectrum, graphene has led to the emergence of a new paradigm of 'relativistic' condensed-matter physics, where quantum relativistic phenomena, some of which are unobservable in high-energy physics, can now be mimicked and tested in table-top experiments. More generally, graphene represents a conceptually new class of materials that are only one atom thick, and, on this basis, offers new inroads into low-dimensional physics that has never ceased to surprise and continues to provide a fertile ground for applications.

The rise of graphene

There is, I think, something ethereal about i —the square root of minus one. I remember first hearing about it at school. It seemed an odd beast at that time—an intruder hovering on the edge of reality.

Usually familiarity dulls this sense of the bizarre, but in the case of i it was the reverse: over the years the sense of its surreal nature intensified. It seemed that it was impossible to write mathematics that described the real world in …

I and i

This article reviews the basic theoretical aspects of graphene, a one-atom-thick allotrope of carbon, with unusual two-dimensional Dirac-like electronic excitations. The Dirac electrons can be controlled by application of external electric and magnetic fields, or by altering sample geometry and/or topology. The Dirac electrons behave in unusual ways in tunneling, confinement, and the integer quantum Hall effect. The electronic properties of graphene stacks are discussed and vary with stacking order and number of layers. Edge (surface) states in graphene depend on the edge termination (zigzag or armchair) and affect the physical properties of nanoribbons. Different types of disorder modify the Dirac equation leading to unusual spectroscopic and transport properties. The effects of electron-electron and electron-phonon interactions in single layer and multilayer graphene are also presented.

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The electronic properties of graphene

There is intense interest in graphene in fields such as physics, chemistry, and materials science, among others. Interest in graphene's exceptional physical properties, chemical tunability, and potential for applications has generated thousands of publications and an accelerating pace of research, making review of such research timely. Here is an overview of the synthesis, properties, and applications of graphene and related materials (primarily, graphite oxide and its colloidal suspensions and materials made from them), from a materials science perspective.

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Graphene and Graphene Oxide: Synthesis, Properties, and Applications

This paper reviews recent experimental and theoretical progress concerning many-body phenomena in dilute, ultracold gases. It focuses on effects beyond standard weak-coupling descriptions, such as the Mott-Hubbard transition in optical lattices, strongly interacting gases in one and two dimensions, or lowest-Landau-level physics in quasi-two-dimensional gases in fast rotation. Strong correlations in fermionic gases are discussed in optical lattices or near-Feshbach resonances in the BCS-BEC crossover.

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Many-Body Physics with Ultracold Gases

Metal–insulator transition in a weakly interacting many-electron system with localized single-particle states

The focusing of electric current by a single p-n junction in graphene is theoretically predicted. Precise focusing may be achieved by fine-tuning the densities of carriers on the n- and p-sides of the junction to equal values. This finding may be useful for the engineering of electronic lenses and focused beam splitters using gate-controlled n-p-n junctions in graphene-based transistors.

http://science.sciencemag.org/content/sci/315/5816/1252.full.pdf

The focusing of electron flow and a Veselago lens in graphene p-n junctions.

Because of the chiral nature of electrons in a monolayer of graphite (graphene) one can expect weak antilocalization and a positive weak-field magnetoresistance in it. However, trigonal warping (which breaks $\mathbf{p}\ensuremath{\rightarrow}\ensuremath{-}\mathbf{p}$ symmetry of the Fermi line in each valley) suppresses antilocalization, while intervalley scattering due to atomically sharp scatterers in a realistic graphene sheet or by edges in a narrow wire tends to restore conventional negative magnetoresistance. We show this by evaluating the dependence of the magnetoresistance of graphene on relaxation rates associated with various possible ways of breaking a ``hidden'' valley symmetry of the system.

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Weak-localization magnetoresistance and valley symmetry in graphene.

Interaction effects in disordered Fermi systems are considered in the metallic regime. In two dimensions, logarithmic corrections are obtained for conductivity, density of states, specific heat, and Hall constant. These results are compared with a recent theory of localization as well as some experiments.

Interaction Effects in Disordered Fermi Systems in Two Dimensions

The efficiency of the future devices for quantum information processing will be limited mostly by the finite decoherence rates of the individual qubits and quantum gates. Recently, substantial progress was achieved in enhancing the time within which a solid-state qubit demonstrates coherent dynamics. This progress is based mostly on a successful isolation of the qubits from external decoherence sources obtained by clever engineering. Under these conditions, the material-inherent sources of noise start to play a crucial role. In most cases, quantum devices are affected by noise decreasing with frequency, f, approximately as 1/f. According to the present point of view, such noise is due to material- and device-specific microscopic degrees of freedom interacting with quantum variables of the nanodevice. The simplest picture is that the environment that destroys the phase coherence of the device can be thought of as a system of two-state fluctuators, which experience random hops between their states. If the hopping times are distributed in a exponentially broad domain, the resulting fluctuations have a spectrum close to 1/f in a large frequency range. In this paper we review the current state of the theory of decoherence due to degrees of freedom producing 1/f noise. We discuss basic mechanisms of such noises in various nanodevices and then review several models describing the interaction of the noise sources with quantum devices. The main focus of the review is to analyze how the 1/f noise destroys their coherent operation. We start from individual qubits concentrating mostly on the devices based on superconductor circuits, and then discuss some special issues related to more complicated architectures. Finally, we consider several strategies for minimizing the noise-induced decoherence.

Boris L. Altshuler

Papers

Metal–insulator transition in a weakly interacting many-electron system with localized single-particle states

The focusing of electron flow and a Veselago lens in graphene p-n junctions.

Weak-localization magnetoresistance and valley symmetry in graphene.

Interaction Effects in Disordered Fermi Systems in Two Dimensions

1 / f noise: Implications for solid-state quantum information