C Naumann

TL;DR: In this article, the authors define three types of thiolato-complexes: terminal, monomeric, and sterically hindered, and three-dimensional clusters with tetrahedral metal centres.

TL;DR: Improved understanding of the mechanisms of LDL oxidation by copper ions should facilitate the establishment of any physiological role of the metal in LDL modification, and assist in the interpretation of studies in which copper systems of LDL modification are used in vitro to evaluate potential antioxidants.

TL;DR: In this article, a review of the nature of Cu(II)-thiolate bonding present in different metalloproteins, difficulties involved in the synthesis of Cu-II-thiolates and ways to surmount them are discussed.

TL;DR: A strong splitting was observed in the spectra of Cu-(trifluoroacetylacetonate)2 and Cu-(biuret)2Cl2 were Cu(II) is exclusively bound to oxygen having a formal double bond.