C
Caio C. Oliveira
Researcher at State University of Campinas
Publications - 28
Citations - 1069
Caio C. Oliveira is an academic researcher from State University of Campinas. The author has contributed to research in topics: Enantioselective synthesis & Aryl. The author has an hindex of 9, co-authored 24 publications receiving 819 citations. Previous affiliations of Caio C. Oliveira include University of Basel & Federal University of Bahia.
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Catalytic Enantioselective Transformations Involving C-H Bond Cleavage by Transition-Metal Complexes.
TL;DR: This analysis comprehensively review all asymmetric transition-metal-catalyzed methodologies that are believed to proceed via an inner-sphere-type mechanism, with an emphasis on the nature of stereochemistry generation.
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Intermolecular Enantioselective Heck–Matsuda Arylations of Acyclic Olefins: Application to the Synthesis of β-Aryl-γ-lactones and β-Aryl Aldehydes
TL;DR: This new enantioselective Heck-Matsuda arylation of acyclic allylic alcohols allowed the synthesis of β-aryl-γ-lactones and β- Daryl aldehydes, which play a vital role as key intermediates in the synthesisOf the biologically active compounds, such as (R)-baclofen, (R-rolipram, (S-curcumene) and (S)-dehydrocurcumene.
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Quaternary Stereogenic Centers through Enantioselective Heck Arylation of Acyclic Olefins with Aryldiazonium Salts: Application in a Concise Synthesis of (R)-Verapamil.
TL;DR: The potential of this new method is demonstrated by the straightforward synthesis of several O-methyl lactols and lactones containing quaternary stereocenters, together with a concise enantioselective total synthesis of the calcium channel blocker verapamil.
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The first examples of the enantioselective Heck–Matsuda reaction: arylation of unactivated cyclic olefins using chiral bisoxazolines
TL;DR: In this article, the authors used chiral bisoxazolines as ligands for Heck-Matsuda arylation with cyclic nonactivated olefins and achieved enantioselective Heck products in 63% isolated yields and in enantiomeric excesses of 54% up to 84%.
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Stereoselective Synthesis of Aryl Cyclopentene Scaffolds by Heck–Matsuda Desymmetrization of 3‐Cyclopentenol
Ricardo A. Angnes,Juliana M. Oliveira,Caio C. Oliveira,Nelson Martins,Carlos Roque D. Correia +4 more
TL;DR: A new enantioselective Heck-Matsuda desymmetrization reaction was accomplished by using 3-cyclopentenol to produce chiral five-membered 4-aryl cyclopentenols scaffolds in good yields and high ee's.