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Carmen Mijangos

Bio: Carmen Mijangos is an academic researcher from Spanish National Research Council. The author has contributed to research in topics: Vinyl chloride & Chemical modification. The author has an hindex of 40, co-authored 204 publications receiving 5765 citations. Previous affiliations of Carmen Mijangos include Ikerbasque & University of the Basque Country.


Papers
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Journal ArticleDOI
15 Dec 2000-Polymer
TL;DR: In this article, a broad range of degrees of crosslinking, from 1.7 up to 74% of reacted hydroxyl groups, was achieved, and the variation of the thermal and mechanical properties of PVA with the crosslink density show an initial decrease due to the diminution of the crystallinity of the system, caused by the cross-linking.

480 citations

Journal ArticleDOI
19 Jul 2013-Polymer
TL;DR: In this paper, the authors review previous works on polymer confined crystallization employing strategies that allow confinement to go from the micron to the nanometer scale: droplets, blends, block copolymers and infiltration into alumina nanopores.

178 citations

Journal ArticleDOI
09 Mar 2012-Polymer
TL;DR: In this article, the chemistry and physics relevant for the design of these nanostructured materials are discussed and recent advances emphasized, highlighting the effects of nanoconfinement on material behavior and putting somewhat greater emphasis on molecular motions.

177 citations

Journal ArticleDOI
TL;DR: In this paper, an anchored surface layer that internally is highly mobile and not glassy as heavily promoted in the literature is found, where the polymer dynamics in confinement is determined by two phases, one fully equal to the bulk polymer and another that is partly anchored at the surface.
Abstract: We present neutron spin echo experiments that address the much debated topic of dynamic phenomena in polymer melts that are induced by interacting with a confining surface. We find an anchored surface layer that internally is highly mobile and not glassy as heavily promoted in the literature. The polymer dynamics in confinement is, rather, determined by two phases, one fully equal to the bulk polymer and another that is partly anchored at the surface. By strong topological interaction, this phase confines further chains with no direct contact to the surface. These form the often invoked interphase, where the full chain relaxation is impeded through the interaction with the anchored chains.

157 citations

Journal ArticleDOI
TL;DR: In this article, the authors present new insights in the fabrication methods of polymer nanostructures from hard porous AAO templates, with emphasis on the study of polymer structure/property relationships on the nanometric length scale, stressing potential interests in relevant applications.

144 citations


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Book
01 Jan 1996
TL;DR: A review of the collected works of John Tate can be found in this paper, where the authors present two volumes of the Abel Prize for number theory, Parts I, II, edited by Barry Mazur and Jean-Pierre Serre.
Abstract: This is a review of Collected Works of John Tate. Parts I, II, edited by Barry Mazur and Jean-Pierre Serre. American Mathematical Society, Providence, Rhode Island, 2016. For several decades it has been clear to the friends and colleagues of John Tate that a “Collected Works” was merited. The award of the Abel Prize to Tate in 2010 added impetus, and finally, in Tate’s ninety-second year we have these two magnificent volumes, edited by Barry Mazur and Jean-Pierre Serre. Beyond Tate’s published articles, they include five unpublished articles and a selection of his letters, most accompanied by Tate’s comments, and a collection of photographs of Tate. For an overview of Tate’s work, the editors refer the reader to [4]. Before discussing the volumes, I describe some of Tate’s work. 1. Hecke L-series and Tate’s thesis Like many budding number theorists, Tate’s favorite theorem when young was Gauss’s law of quadratic reciprocity. When he arrived at Princeton as a graduate student in 1946, he was fortunate to find there the person, Emil Artin, who had discovered the most general reciprocity law, so solving Hilbert’s ninth problem. By 1920, the German school of algebraic number theorists (Hilbert, Weber, . . .) together with its brilliant student Takagi had succeeded in classifying the abelian extensions of a number field K: to each group I of ideal classes in K, there is attached an extension L of K (the class field of I); the group I determines the arithmetic of the extension L/K, and the Galois group of L/K is isomorphic to I. Artin’s contribution was to prove (in 1927) that there is a natural isomorphism from I to the Galois group of L/K. When the base field contains an appropriate root of 1, Artin’s isomorphism gives a reciprocity law, and all possible reciprocity laws arise this way. In the 1930s, Chevalley reworked abelian class field theory. In particular, he replaced “ideals” with his “idèles” which greatly clarified the relation between the local and global aspects of the theory. For his thesis, Artin suggested that Tate do the same for Hecke L-series. When Hecke proved that the abelian L-functions of number fields (generalizations of Dirichlet’s L-functions) have an analytic continuation throughout the plane with a functional equation of the expected type, he saw that his methods applied even to a new kind of L-function, now named after him. Once Tate had developed his harmonic analysis of local fields and of the idèle group, he was able prove analytic continuation and functional equations for all the relevant L-series without Hecke’s complicated theta-formulas. Received by the editors September 5, 2016. 2010 Mathematics Subject Classification. Primary 01A75, 11-06, 14-06. c ©2017 American Mathematical Society

2,014 citations

Journal ArticleDOI
TL;DR: The phenomenology of exchange bias and related effects in nanostructures is reviewed in this paper, where the main applications of exchange biased nanostructure are summarized and the implications of the nanometer dimensions on some of the existing exchange bias theories are briefly discussed.

1,721 citations

Journal ArticleDOI
TL;DR: In this article, the authors present an overview of the key requirements for the proton exchange membranes (PEM) used in fuel cell applications, along with a description of the membrane materials currently being used and their ability to meet these requirements.

1,715 citations

Journal Article

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1,682 citations

Journal ArticleDOI
TL;DR: This work presents a new mesoporous composite material suitable for high-performance liquid chromatography and shows good chiral recognition ability and high uniformity in various racemates.
Abstract: Dingcai Wu,*,† Fei Xu,† Bin Sun,† Ruowen Fu,† Hongkun He,‡ and Krzysztof Matyjaszewski*,‡ †Materials Science Institute, Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, People's Republic of China ‡Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213, United States

1,455 citations