Chandra Mohan Sinnathambi

Bio: Chandra Mohan Sinnathambi is an academic researcher from Universiti Teknologi Petronas. The author has contributed to research in topics: Refinery & Enhanced oil recovery. The author has an hindex of 6, co-authored 20 publications receiving 162 citations. Previous affiliations of Chandra Mohan Sinnathambi include Petronas.

Comparison of various advanced oxidation processes used in remediation of industrial wastewater laden with recalcitrant pollutants

Abstract: Due to the scarcity of water, it has become a necessity to improve the quality of wastewater that is discharged into the environment. Conventional wastewater treatment can be either a physical, chemical, and/or biological processes, or in some cases a combination of these operations. The main purpose of wastewater treatment is to eliminate nutrients, solids, and organic compounds from effluents. Current wastewater treatment technologies are deemed ineffective in the complete removal of pollutants, particularly organic matter. In many cases, these organic compounds are resistant to conventional treatment methods, thus creating the necessity for tertiary treatment. Advanced oxidation process (AOP), constitutes as a promising treatment technology for the management of wastewater. AOPs are characterised by a common chemical feature, where they utilize the highly reactive hydroxyl radicals for achieving complete mineralization of the organic pollutants into carbon dioxide and water. This paper delineates advanced oxidation processes currently used for the remediation of water and wastewater. It also provides the cost estimation of installing and running an AOP system. The costs are separated into three categories: capital, operational, and operating & maintenance.

Recent advancement of hybrid materials used in chemical enhanced oil recovery (CEOR): A review

Abstract: Depletion of natural oil reserves has forced oil industries to focus on tertiary recovery methods to extract residual oil after exhausting the primary and secondary methods. Among the Enhance Oil Recovery (EOR) technologies, Chemical EOR (CEOR) is gaining popularity. Despite research efforts to increase the recovery using CEOR, increasing complexity in extraction methods are encountered. With changes in reservoir conditions (high temperature, pressure and salinity) and crude oil properties, existing chemicals used in CEOR, such as alkali, polymers and surfactants do not function desirably. These conditions have detrimental effects on the performance of EOR chemicals, like precipitation, degradation, etc. Development and utilization of effective EOR hybrids such as surfactant-polymer, polymer-nanomaterial, surfactant-nanomaterial and polymer-surfactant-nanomaterial had prevailed the effects of harsh reservoir conditions, and their applications in oil fields in recent years have increased the success of EOR. The synergistic effects between the hybrid components play major roles in improving the properties that could withstand the effect of extreme reservoir conditions and changes in crude oil properties. Therefore, this paper is aimed at reviewing recent advances in CEOR hybrid technologies, and discusses the basic concept, applications, advancement and limitations of different hybrid materials used in CEOR processes.

An overview of the present stability and performance of EOR-foam

Abstract: Foam flooding technique, commonly known as foam assisted water alternating gas method (FAWAG) has been identified as an effective chemical enhanced oil recovery (CEOR) technique. The ability of EOR-foam to sweep oil in low permeable zones makes it important displacement fluid in the oil industry. However, extreme reservoir conditions such as temperature, pressure and salinity have detrimental effects on the stability and the overall performance of the EOR-foam. Consequently, understanding foam stability and performance under different conditions is crucial for long term oil field application. This paper discusses the current status of the EOR-foam stability, performance and challenges from laboratory studies to field application perspective. The paper also highlights the knowledge gaps which require further research for successful field application.

Thermodynamics Analysis of Refinery Sludge Gasification in Adiabatic Updraft Gasifier

Abstract: Limited information is available about the thermodynamic evaluation for biomass gasification process using updraft gasifier. Therefore, to minimize errors, the gasification of dry refinery sludge (DRS) is carried out in adiabatic system at atmospheric pressure under ambient air conditions. The objectives of this paper are to investigate the physical and chemical energy and exergy of product gas at different equivalent ratios (ER). It will also be used to determine whether the cold gas, exergy, and energy efficiencies of gases may be maximized by using secondary air injected to gasification zone under various ratios (0, 0.5, 1, and 1.5) at optimum ER of 0.195. From the results obtained, it is indicated that the chemical energy and exergy of producer gas are magnified by 5 and 10 times higher than their corresponding physical values, respectively. The cold gas, energy, and exergy efficiencies of DRS gasification are in the ranges of 22.9–55.5%, 43.7–72.4%, and 42.5–50.4%, respectively. Initially, all 3 efficiencies increase until they reach a maximum at the optimum ER of 0.195; thereafter, they decline with further increase in ER values. The injection of secondary air to gasification zone is also found to increase the cold gas, energy, and exergy efficiencies. A ratio of secondary air to primary air of 0.5 is found to be the optimum ratio for all 3 efficiencies to reach the maximum values.

Laboratory characterization of crude oil and sandstone reservoir for chemical enhanced oil recovery

Abstract: Purpose Because of the increasing global oil demand, efforts have been made to further extract oil using chemical enhanced oil recovery (CEOR) methods. However, unlike water flooding, understanding the physicochemical properties of crude oil and its sandstone reservoir makeup is the first step before embarking to CEOR projects. These properties play major roles in the area of EOR technologies and are important for the development of reliable chemical flooding agents; also, they are key parameters used to evaluate the economic and technical feasibilities of production and refining processes in the oil industries. Consequently, this paper aims to investigate various important physicochemical properties of crude oil (specific gravity; American Petroleum Institute [API]; viscosity; pour point; basic sediment and water; wax; and saturate, aromatic, resins and asphaltenes components) and sandstone reservoir makeup (porosity, permeability, bulk volume and density, grain volume and density, morphology and mineral composition and distributions) obtained from Malaysian oil field (MOF) for oil recovery prediction and design of promising chemical flooding agents. Design/methodology/approach Three reservoir sandstones from different depths (CORE 1; 5601, CORE 2; 6173 and CORE 3; 6182 ft) as well as its crude oil were obtained from the MOF, and various characterization instruments, such as high temperature gas chromatography and column chromatography for crude’s fractions identification; GC-simulated distillation for boiling point distribution; POROPERM for porosity and permeability; CT-Scan and scanning electron microscopy-energy dispersive X-ray for morphology and mineral distribution; wax instrument (wax content); pour point analyser (pour point); and visco-rheometre (viscosity), were used for the characterizations. Findings Experimental data gathered from this study show that the field contains low viscous (0.0018-0.014 Pa.s) sweet and light-typed crude because of low sulfur content (0.03 per cent), API gravity (43.1o), high proportion of volatile components (51.78 per cent) and insignificant traces of heavy components (0.02 per cent). Similarly, the rock permeability trend with depth was found in the order of CORE 1 < CORE 2 < CORE 3, and other parameters such as pore volume (Vp), bulk volume (Vb) and grain volume (Vg) also decrease in general. For grain density, the variation is small and insignificant, but for bulk density, CORE 2 records lower than CORE 3 by more than 1 per cent. In the mineral composition analysis, the CORE 2 contains the highest identified mineral content, with the exception of quarts where it was higher in the CORE 3. Thus, a good flow crude characteristic, permeability trend and the net mineral concentrations identified in this reservoir would not affect the economic viability of the CEOR method and predicts the validation of the MOF as a potential field that could respond to CEOR method successfully. Originality/value This paper is the first of its kind to combine the two important oil field properties to scientifically predict the evaluation of an oil field (MOF) as a step forward toward development of novel chemical flooding agents for application in EOR. Hence, information obtained from this paper would help in the development of reliable chemical flooding agents and designing of EOR methods.

Introduction to Spectroscopy

Abstract: Spectroscopy is the study of matter interacting with electromagnetic radiation (e.g., light). The electromagnetic spectrum in Figure 1 illustrates the many different types of electromagnetic radiation, including gamma rays (γ-rays), X-rays, ultraviolet (UV) radiation, visible light, infrared (IR) radiation, microwaves, and radio waves. The frequency (ν) and wavelength (λ) ranges associated with each form of radiant energy are also indicated in Figure 1.

Review on Methylene Blue: Its Properties, Uses, Toxicity and Photodegradation

Abstract: The unavailability of clean drinking water is one of the significant health issues in modern times. Industrial dyes are one of the dominant chemicals that make water unfit for drinking. Among these dyes, methylene blue (MB) is toxic, carcinogenic, and non-biodegradable and can cause a severe threat to human health and environmental safety. It is usually released in natural water sources, which becomes a health threat to human beings and living organisms. Hence, there is a need to develop an environmentally friendly, efficient technology for removing MB from wastewater. Photodegradation is an advanced oxidation process widely used for MB removal. It has the advantages of complete mineralization of dye into simple and nontoxic species with the potential to decrease the processing cost. This review provides a tutorial basis for the readers working in the dye degradation research area. We not only covered the basic principles of the process but also provided a wide range of previously published work on advanced photocatalytic systems (single-component and multi-component photocatalysts). Our study has focused on critical parameters that can affect the photodegradation rate of MB, such as photocatalyst type and loading, irradiation reaction time, pH of reaction media, initial concentration of dye, radical scavengers and oxidising agents. The photodegradation mechanism, reaction pathways, intermediate products, and final products of MB are also summarized. An overview of the future perspectives to utilize MB at an industrial scale is also provided. This paper identifies strategies for the development of effective MB photodegradation systems.