Solubility Parameters - An Introduction C.M. Hansen Hildebrand Parameters and Basic Polymer Solution Thermodynamics Hansen Solubility Parameters Methods and Problems in the Determination of Partial Solubility Parameters Calculation of the Dispersion Solubility Parameter deltad Calculation of the Polar Solubility Parameter deltap Calculation of the Hydrogen Bonding Solubility Parameter deltah Supplementary Calculations And Procedures Hansen Solubility Parameters for Water Theory - The Prigogine Corresponding States Theory, the c12 Interaction Parameter, and the Hansen Solubility Parameters C.M. Hansen Hansen Solubility Parameters (HSP) Resemblance Between Predictions of Hansen Solubility Parameters and Corresponding States Theories The c12Parameter and Hansen Solubility Parameters Comparison of Calculated and Experimental c12 Parameters General Discussion Postscript Statistical Thermodynamic Calculations of the Hydrogen Bonding, Dipolar, and Dispersion Solubility Parameters C. Panayiotou Theory Applications Discussion and Conclusions Appendix I: The Acid Dimerization Appendix II: An Alternative Form of the Polar Term Appendix III: A Group-Contribution Method for the Prediction of delta and deltaD Hansen Solubility Parameters (HSP) in Thermodynamic Models for Polymer Solutions G.M. Kontogeorgis Group Contribution Methods for Estimating Properties of Polymers Activity Coefficients Models Using the HSP Conclusions and Future Challenges Appendix I: An Expression of the FH Model for Multicomponent Mixture Methods of Characterization - Polymers C.M. Hansen Calculation of Polymer HSP Solubility - Examples Swelling - Examples Melting Point Determinations - Effect of Temperature Environmental Stress Cracking Intrinsic Viscosity Measurements Other Measurement Techniques Methods of Characterization - Surfaces C.M. Hansen Hansen Solubility Parameter Correlations with Surface Tension (Surface Free Energy) Method to Evaluate the Cohesion Energy Parameters for Surfaces A Critical View of the Critical Surface Tensions A Critical View of the Wetting Tension Additional Hansen Solubility Parameter Surface Characterizations and Comparisons Self-Stratifying Coatings Maximizing Physical Adhesion Methods of Characterization for Pigments, Fillers, and Fibers C.M. Hansen Methods to Characterize Pigment, Filler, and Fiber Surfaces Discussion - Pigments, Fillers, and Fibers Hansen Solubility Parameter Correlation of Zeta Potential for Blanc Fixe Carbon Fiber Surface Characterization Controlled Adsorption (Self-Assembly) Applications - Coatings and Other Filled Polymer Systems C.M. Hansen Solvents Techniques for Data Treatment Solvents and Surface Phenomena in Coatings (Self-Assembly) Polymer Compatibility Hansen Solubility Parameter Principles Applied to Understanding Other Filled Polymer Systems Hansen Solubility Parameters of Asphalt, Bitumen and Crude Oils P. Redelius Models of Bitumen Asphaltenes Molecular Weight Polarity Solubility Parameters of Bitumen Testing of Bitumen Solubility Hildebrand Solubility Parameters Hansen Solubility Parameters (HSP) The Solubility Sphere Computer Program for Calculation and Plotting of the Hansen 3D Pseudosphere Components of Bitumen Bitumen and Polymers Crude Oil Turbidimetric Titrations BISOM Test Determination of Hansen Solubility Parameter Values for Carbon Dioxide L.L. Williams Methodology One-Component Hildebrand Parameter as a Function of Temperature and Pressure Three-Component (Hansen) Solubility Parameters - Pure CO2 Temperature and Pressure Effects on HSPs: deltad Temperature and Pressure Effects on HSPs: deltap Temperature and Pressure Effects on HSPs: deltah Addendum Appendix I: Ideal Solubility of Gases in Liquids and Published CO2 Solubility Data Use of Hansen Solubility Parameters to Identify Cleaning Applications for "Designer" Solvents J. Durkee A Variety of Solvents Pathology of Soils HSP of Multiple-Component Soils Method for Calculating HSP of Composites (Soils or Solvents) More Realistic View About Evaluating HSP of Composite Soils Method for Choice of Suitable Solvents Reference Soils for Comparison Identification of Designer Solvents An Open Question - Answered Limiting RA Value For Expected Good Cleaning Performance Application of HSP Methodology to Cleaning Operations Analysis of Capability of Designer Solvents Applications - Chemical Resistance C.M. Hansen Chemical Resistance - Acceptable-or-Not Data Effects of Solvent Molecular Size Chemical Resistance - Examples Special Effects with Water Applications - Barrier Polymers C.M. Hansen Concentration-Dependent Diffusion Solubility Parameter Correlations Based on Permeation Phenomena Solubility Parameter Correlation of Polymer Swelling Solubility Parameter Correlation of Permeation Coefficients for Gases General Considerations Applications - Environmental Stress Cracking in Polymers C.M. Hansen ESC Interpreted Using HSP ESC With Nonabsorbing Stress Cracking Initiators Hansen Solubility Parameters - Biological Materials C.M. Hansen and T. Svenstrup Poulsen Hydrophobic Bonding and Hydrophilic Bonding (Self-Association) DNA Cholesterol Lard Human Skin Proteins - Blood Serum and Zein Chlorophyll and Lignin Wood Chemicals and Polymers Urea Water Surface Mobility Chiral Rotation, Hydrogen Bonding, and Nanoengineering Absorption and Diffusion in Polymers C.M. Hansen Steady State Permeation The Diffusion Equation Surface Resistance Side Effects Film Formation by Solvent Evaporation Anomalous Diffusion (Case II, Super Case II) Applications - Safety and Environment C.M. Hansen Substitution Alternative Systems Solvent Formulation And Personal Protection For Least Risk The Danish Mal System - The Fan Selection of Chemical Protective Clothing Uptake of Contents by a Plastic Container Skin Penetration Transport Phenomena The Future Hansen Solubility Parameter Data and Data Quality Group Contribution Methods Polymers as Points - Solvents as Spheres Characterizing Surfaces Materials and Processes Suggested for Further Attention Theoretical Problems Awaiting Future Resolution Appendices Hansen Solubility Parameters for Selected Solvents with the major contribution of Hanno Priebe Hansen Solubility Parameters for Selected Correlations Solubility Data for the Original 33 Polymers and 88 Solvents Index * Each Chapter contains an Abstract, an Introduction, and a Conclusion. Many chapters may also include Acknowledgements, Additional Discussions or General Comments/Considerations, and chapter-specific Key Words, Abbreviations, and Symbols

Hansen Solubility Parameters: A User's Handbook

Isolated graphene, a nanometer-thick two-dimensional analog of fullerenes and carbon nanotubes, has recently sparked great excitement in the scientific community given its excellent mechanical and electronic properties. Particularly attractive is the availability of bulk quantities of graphene as both colloidal dispersions and powders, which enables the facile fabrication of many carbon-based materials. The fact that such large amounts of graphene are most easily produced via the reduction of graphene oxide--oxygenated graphene sheets covered with epoxy, hydroxyl, and carboxyl groups--offers tremendous opportunities for access to functionalized graphene-based materials. Both graphene oxide and graphene can be processed into a wide variety of novel materials with distinctly different morphological features, where the carbonaceous nanosheets can serve as either the sole component, as in papers and thin films, or as fillers in polymer and/or inorganic nanocomposites. This Review summarizes techniques for preparing such advanced materials via stable graphene oxide, highly reduced graphene oxide, and graphene dispersions in aqueous and organic media. The excellent mechanical and electronic properties of the resulting materials are highlighted with a forward outlook on their applications.

Graphene oxide, highly reduced graphene oxide, and graphene: versatile building blocks for carbon-based materials.

羟氨苄青霉素引起大疱性类天疱疮样疹

This Review focuses on noncovalent functionalization of graphene and graphene oxide with various species involving biomolecules, polymers, drugs, metals and metal oxide-based nanoparticles, quantum dots, magnetic nanostructures, other carbon allotropes (fullerenes, nanodiamonds, and carbon nanotubes), and graphene analogues (MoS2, WS2). A brief description of π–π interactions, van der Waals forces, ionic interactions, and hydrogen bonding allowing noncovalent modification of graphene and graphene oxide is first given. The main part of this Review is devoted to tailored functionalization for applications in drug delivery, energy materials, solar cells, water splitting, biosensing, bioimaging, environmental, catalytic, photocatalytic, and biomedical technologies. A significant part of this Review explores the possibilities of graphene/graphene oxide-based 3D superstructures and their use in lithium-ion batteries. This Review ends with a look at challenges and future prospects of noncovalently modified graph...

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Noncovalent Functionalization of Graphene and Graphene Oxide for Energy Materials, Biosensing, Catalytic, and Biomedical Applications

We report that homogeneous colloidal suspensions of chemically modified graphene sheets were readily produced in a wide variety of organic solvent systems. Two different sets of solubility parameters are used to rationalize when stable colloidal suspensions of graphene oxide sheets and, separately, of reduced graphene oxide sheets in a given solvent type are possible and when they are not. As an example of the utility of such colloidal suspensions, “paperlike” materials generated by very simple filtration of the reduced graphene oxide sheets had electrical conductivity values as high as 16 000 S/m.

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Colloidal Suspensions of Highly Reduced Graphene Oxide in a Wide Variety of Organic Solvents

Hansen solubility parameters (HSPs) are used to predict molecular affinities, solubility, and solubility-related phenomena. Revised and updated throughout, Hansen Solubility Parameters: A User's Handbook, Second Edition features the three Hansen solubility parameters for over 1200 chemicals and correlations for over 400 materials including p

Charles M. Hansen

Papers

Hansen Solubility Parameters: A User's Handbook

Hansen Solubility Parameters : A User's Handbook, Second Edition

The Universality of the Solubility Parameter

50 Years with solubility parameters—past and future ☆

Using Hansen solubility parameters to correlate solubility of C60 fullerene in organic solvents and in polymers