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Showing papers by "Chizuko Kabuto published in 2013"


Journal ArticleDOI
TL;DR: Tetraaminothiacalixarene 3 as discussed by the authors exhibits inclusion properties different from those of compound 2 towards small organic molecules upon crystallisation from neat solvents or guest solutions.
Abstract: Tetraaminothiacalixarene 3, bearing four amino groups instead of the hydroxy groups of p-tert-butylthiacalix[4]arene 2, exhibits inclusion properties different from those of compound 2 towards small organic molecules upon crystallisation from neat solvents or guest solutions. X-ray crystallographic analyses reveal that nitromethane and acetonitrile are included into the cone-shaped cavity of compound 3, as is often seen in inclusion crystals of compound 2, whereas dichloromethane occupies a space between two distal benzene rings of compound 3, adopting a 1,3-alternate conformation. Acetic acid, which forms a dimer, fills a pore surrounded by four host molecules with a pinched cone conformation. Furthermore, guest-free crystals of compound 3 with a 1,3-alternate conformation absorb acetonitrile to give inclusion crystals with the same crystal structure as that obtained by the crystallisation. Thus, compound 3 flexibly changes its conformation according to the structures of guest compounds.

7 citations