Author
Choong-Nyeon Park
Bio: Choong-Nyeon Park is an academic researcher from Chonnam National University. The author has contributed to research in topics: Alloy & Hydrogen storage. The author has an hindex of 21, co-authored 57 publications receiving 1099 citations.
Topics: Alloy, Hydrogen storage, Hydride, Electrode, Hydrogen
Papers published on a yearly basis
Papers
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TL;DR: The urea assisted facile co-precipitation synthesis of spinel NiCo2O4 is reported and its application as an anode material for LIBs with the advantages of unique performance and facile preparation.
Abstract: To fulfill the high power and high energy density demands for Li-ion batteries (LIBs) new anode materials need to be explored to replace conventional graphite. Herein, we report the urea assisted facile co-precipitation synthesis of spinel NiCo2O4 and its application as an anode material for LIBs. The synthesized NiCo2O4 exhibited an urchin-like microstructure and polycrystalline and mesoporous nature. In addition, the mesoporous NiCo2O4 electrode exhibited an initial discharge capacity of 1095 mA h g−1 and maintained a reversible capacity of 1000 mA h g−1 for 400 cycles at 0.5 C-rate. The reversible capacity of NiCo2O4 could still be maintained at 718 mA h g−1, even at 10 C. The mesoporous NiCo2O4 exhibits great potential as an anode material for LIBs with the advantages of unique performance and facile preparation.
119 citations
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TL;DR: The CGPE as a protection layer for the Li metal electrode in a Li-O2 cell was effective in blocking the contamination of the Li electrode by oxygen gas or impurities diffused from the cathode side while suppressing the Li dendrites.
Abstract: A composite gel polymer electrolyte (CGPE) based on poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) polymer that includes Al-doped Li0.33La0.56TiO3 (A-LLTO) particles covered with a modified SiO2 (m-SiO2) layer was fabricated through a simple solution-casting method followed by activation in a liquid electrolyte. The obtained CGPE possessed high ionic conductivity, a large electrochemical stability window, and interfacial stability–all superior to that of the pure gel polymer electrolyte (GPE). In addition, under a highly polarized condition, the CGPE effectively suppressed the growth of Li dendrites due to the improved hardness of the GPE by the addition of inorganic A-LLTO/m-SiO2 particles. Accordingly, the Li-ion polymer and Li–O2 cells employing the CGPE exhibited remarkably improved cyclability compared to cells without CGPE. In particular, the CGPE as a protection layer for the Li metal electrode in a Li–O2 cell was effective in blocking the contamination of the Li electrode by oxygen gas o...
113 citations
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TL;DR: In this article, a facile synthetic route is introduced for producing nanometer-sized Ge crystallites interconnected by carbon (GEC) via thermal decomposition of a Ge-citrate complex followed by a calcination process in an inert atmosphere.
Abstract: Germanium (Ge) possesses a great potential as a high-capacity anode material for lithium ion batteries but suffers from its poor capacity retention and rate capability due to significant volume expansion by lithiation. Here, a facile synthetic route is introduced for producing nanometer-sized Ge crystallites interconnected by carbon (GEC) via thermal decomposition of a Ge-citrate complex followed by a calcination process in an inert atmosphere. The GEC electrode shows outstanding electrochemical performance, i.e., an almost 98.8% capacity retention of 1232 mAh g−1, even after 1000 cycles at the rate of C/2. Importantly, a high discharge capacity of 880 mAh g−1 is maintained at the very high rate of 10 C. The excellent anode performance of GEC stems from both effective buffering of carbon anchored to the Ge nanocrystals and the high open porosity of the GEC aggregated powder with an average pore diameter of 32 nm. Furthermore, the interfacial layer formed between Ge and carbon plays an essential role in prolonging the cycle life. The GEC electrode can be successfully employed as an anode for next generation lithium ion batteries.
80 citations
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TL;DR: The superior performance of the GeO 2/C electrode enables the amorphous GeO2/C to be a potential anode material for secondary Li-ion batteries.
Abstract: In this study, a novel method has been proposed for synthesizing amorphous GeO2/C composites. The amorphous GeO2/C composite without carbon black as an electrode for Li-ion batteries exhibited a high specific capacity of 914 mA h g−1 at the rate of C/2 and enhanced rate capability. The amorphous GeO2/C electrode exhibited excellent electrochemical stability with a 95.3% charge capacity retention after 400 charge–discharge cycles, even at a high current charge–discharge of C/2. Furthermore, a full cell employing the GeO2/C anode and the LiCoO2 cathode displayed outstanding cycling performance. The superior performance of the GeO2/C electrode enables the amorphous GeO2/C to be a potential anode material for secondary Li-ion batteries.
56 citations
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TL;DR: In this paper, the hydrogen absorption and desorption characteristics of bcc alloys have been investigated at 303 K. The compositions of alloys were chosen for alloys to have equal lattice parameters of about 3.03 A by a linear combination of each element.
56 citations
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TL;DR: This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth, summarizing the theoretical and experimental achievements and endeavors to realize the practical applications of lithium metal batteries.
Abstract: The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applicatio...
3,812 citations
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TL;DR: The physicochemical characteristics of spinels such as their compositions, structures, morphologies, defects, and substrates have been rationally regulated through various approaches and can yield spinels with improved ORR/OER catalytic activities, which can further accelerate the speed, prolong the life, and narrow the polarization of fuel cells, metal-air batteries, and water splitting devices.
Abstract: Spinels with the formula of AB2O4 (where A and B are metal ions) and the properties of magnetism, optics, electricity, and catalysis have taken significant roles in applications of data storage, biotechnology, electronics, laser, sensor, conversion reaction, and energy storage/conversion, which largely depend on their precise structures and compositions. In this review, various spinels with controlled preparations and their applications in oxygen reduction/evolution reaction (ORR/OER) and beyond are summarized. First, the composition and structure of spinels are introduced. Then, recent advances in the preparation of spinels with solid-, solution-, and vapor-phase methods are summarized, and new methods are particularly highlighted. The physicochemical characteristics of spinels such as their compositions, structures, morphologies, defects, and substrates have been rationally regulated through various approaches. This regulation can yield spinels with improved ORR/OER catalytic activities, which can furth...
1,036 citations
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TL;DR: An up-to-date review of the behavior of lithium ions upon deposition/dissolution, and the failure mechanisms of lithium-metal anodes is presented.
Abstract: Lithium-metal batteries (LMBs), as one of the most promising next-generation high-energy-density storage devices, are able to meet the rigid demands of new industries. However, the direct utilization of metallic lithium can induce harsh safety issues, inferior rate and cycle performance, or anode pulverization inside the cells. These drawbacks severely hinder the commercialization of LMBs. Here, an up-to-date review of the behavior of lithium ions upon deposition/dissolution, and the failure mechanisms of lithium-metal anodes is presented. It has been shown that the primary causes consist of the growth of lithium dendrites due to large polarization and a strong electric field at the vicinity of the anode, the hyperactivity of metallic lithium, and hostless infinite volume changes upon cycling. The recent advances in liquid organic electrolyte (LOE) systems through modulating the local current density, anion depletion, lithium flux, the anode-electrolyte interface, or the mechanical strength of the interlayers are highlighted. Concrete strategies including tailoring the anode structures, optimizing the electrolytes, building artificial anode-electrolyte interfaces, and functionalizing the protective interlayers are summarized in detail. Furthermore, the challenges remaining in LOE systems are outlined, and the future perspectives of introducing solid-state electrolytes to radically address safety issues are presented.
836 citations
01 Apr 2014
TL;DR: In this article, a mesoporous nitrogen-doped carbon (MPNC)-sulfur nanocomposite is reported as a novel cathode for advanced Li-S batteries.
Abstract: As one important component of sulfur cathodes, the carbon host plays a key role in the electrochemical performance of lithium-sulfur (Li-S) batteries. In this paper, a mesoporous nitrogen-doped carbon (MPNC)-sulfur nanocomposite is reported as a novel cathode for advanced Li-S batteries. The nitrogen doping in the MPNC material can effectively promote chemical adsorption between sulfur atoms and oxygen functional groups on the carbon, as verifi ed by X-ray absorption near edge structure spectroscopy, and the mechanism by which nitrogen enables the behavior is further revealed by density functional theory calculations. Based on the advantages of the porous structure and nitrogen doping, the MPNC-sulfur cathodes show excellent cycling stability (95% retention within 100 cycles) at a high current density of 0.7 mAh cm −2 with a high sulfur loading (4.2 mg S cm −2 ) and a sulfur content (70 wt%). A high areal capacity (≈3.3 mAh cm −2 ) is demonstrated by using the novel cathode, which is crucial for the practical application of Li-S batteries. It is believed that the important role of nitrogen doping promoted chemical adsorption can be extended for development of other high performance carbon-sulfur composite cathodes for Li-S batteries.
826 citations
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TL;DR: Reduction/Evolution Catalysts for Low-Temperature Electrochemical Devices Dengjie Chen, ⊥,∇ Chi Chen,†,⊥ Zarah Medina Baiyee,‡,§ and Francesco Ciucci*,†.
Abstract: Reduction/Evolution Catalysts for Low-Temperature Electrochemical Devices Dengjie Chen,†,⊥,∇ Chi Chen,†,⊥ Zarah Medina Baiyee,† Zongping Shao,‡,§ and Francesco Ciucci*,†,∥ †Department of Mechanical and Aerospace Engineering, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China ‡State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry & Chemical Engineering, Nanjing Tech University, No. 5 Xin Mofan Road, Nanjing 210009, China Department of Chemical Engineering, Curtin University, Perth, Western Australia 6845, Australia Department of Chemical and Biomolecular Engineering, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China
726 citations