Christopher B. Murray

Bio: Christopher B. Murray is an academic researcher from University of Pennsylvania. The author has contributed to research in topics: Nanocrystal & Quantum dot. The author has an hindex of 88, co-authored 336 publications receiving 54410 citations. Previous affiliations of Christopher B. Murray include Universal Display Corporation & Lawrence Berkeley National Laboratory.

Flexible, High-Speed CdSe Nanocrystal Integrated Circuits.

Abstract: We report large-area, flexible, high-speed analog and digital colloidal CdSe nanocrystal integrated circuits operating at low voltages. Using photolithography and a newly developed process to fabricate vertical interconnect access holes, we scale down device dimensions, reducing parasitic capacitances and increasing the frequency of circuit operation, and scale up device fabrication over 4 in. flexible substrates. We demonstrate amplifiers with ∼7 kHz bandwidth, ring oscillators with <10 μs stage delays, and NAND and NOR logic gates.

Enhanced thermal stability and magnetic properties in NaCl-type FePt-MnO binary nanocrystal superlattices.

Abstract: We report the growth of NaCl-type binary nanocrystal (NC) superlattice membranes by coassembly of FePt and MnO NCs at the liquid–air interface. The constituent FePt NCs were converted into the hard magnetic L10 phase by thermal annealing at 650 °C without degradation of the long-range NC ordering. In contrast, both FePt-only NC superlattices and FePt–MnO disordered NC mixtures showed substantial FePt sintering under the same annealing conditions. Our results demonstrate that the incorporation of FePt NCs into binary superlattices can solve the problems of FePt sintering during conversion to the L10 phase, opening a new route to the fabrication of ordered ferromagnetic NC arrays on a desired substrate for high-density data storage applications.

Synthesis of N-Type Plasmonic Oxide Nanocrystals and the Optical and Electrical Characterization of their Transparent Conducting Films

Abstract: We present a general synthesis for a family of n-type transparent conducting oxide nanocrystals through doping with aliovalent cations. These monodisperse nanocrystals exhibit localized surface plasmon resonances tunable in the mid- and near-infrared with increasing dopant concentration. We employ a battery of electrical measurements to demonstrate that the plasmonic resonance in isolated particles is consistent with the electronic properties of oxide nanocrystal thin films. Hall and Seebeck measurements show that the particles form degenerately doped n-type solids with free electron concentrations in the range of 1019 to 1021 cm–3. These heavily doped oxide nanocrystals are used as the building blocks of conductive, n-type thin films with high visible light transparency.

Deposition of Wafer-Scale Single-Component and Binary Nanocrystal Superlattice Thin Films Via Dip-Coating

Abstract: E. A. Gaulding, Z. J. Vrtis, Prof. C. R. Kagan, Prof. C. B. Murray Department of Materials Science and Engineering University of Pennsylvania Philadelphia , PA 19104 , USA E-mail: cbmurray@sas.upenn.edu B. T. Diroll, E. D. Goodwin, Prof. C. R. Kagan, Prof. C. B. Murray Department of Chemistry University of Pennsylvania Philadelphia , PA 19104 , USA Prof. C. R. Kagan Department of Electrical and Systems Engineering University of Pennsylvania Philadelphia , PA 19104 , USA

Tunable Optical Anisotropy of Seeded CdSe/CdS Nanorods

Abstract: We demonstrate structurally tunable optical anisotropy of seeded-growth CdSe/CdS dot-in-rod heterostructures using polarized excitation spectroscopy. The elongated anisotropic CdS shell confers optical anisotropy to the electronic transitions of the CdSe core. Although a rod-shaped shell geometry is a necessary precondition to observing polarized optical properties, the degree of linear polarization is not a strong function of aspect ratio. Rather, tuning the local anisotropy of the emissive core materials by changing the thickness of the anisotropic shell changes the degree of optical anisotropy more dramatically. As the diameter of the core material comprises a greater share (>90%) of the dot-in-rod diameter, the anisotropy of the CdSe core states doubles compared to those for which the core represents <50% of the heterostructure diameter.

疟原虫var基因转换速率变化导致抗原变异[英]／Paul H, Robert P, Christodoulou Z, et al//Proc Natl Acad Sci U S A

Abstract: 抗原变异可使得多种致病微生物易于逃避宿主免疫应答。表达在感染红细胞表面的恶性疟原虫红细胞表面蛋白1（PfPMP1）与感染红细胞、内皮细胞、树突状细胞以及胎盘的单个或多个受体作用，在黏附及免疫逃避中起关键的作用。每个单倍体基因组var基因家族编码约60种成员，通过启动转录不同的var基因变异体为抗原变异提供了分子基础。

Semiconductor Clusters, Nanocrystals, and Quantum Dots

Abstract: Current research into semiconductor clusters is focused on the properties of quantum dots-fragments of semiconductor consisting of hundreds to many thousands of atoms-with the bulk bonding geometry and with surface states eliminated by enclosure in a material that has a larger band gap. Quantum dots exhibit strongly size-dependent optical and electrical properties. The ability to join the dots into complex assemblies creates many opportunities for scientific discovery.

Quantum Dot Bioconjugates for Ultrasensitive Nonisotopic Detection

Abstract: Highly luminescent semiconductor quantum dots (zinc sulfide-capped cadmium selenide) have been covalently coupled to biomolecules for use in ultrasensitive biological detection. In comparison with organic dyes such as rhodamine, this class of luminescent labels is 20 times as bright, 100 times as stable against photobleaching, and one-third as wide in spectral linewidth. These nanometer-sized conjugates are water-soluble and biocompatible. Quantum dots that were labeled with the protein transferrin underwent receptor-mediated endocytosis in cultured HeLa cells, and those dots that were labeled with immunomolecules recognized specific antibodies or antigens.