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D. Brunel

Bio: D. Brunel is an academic researcher from University of Nice Sophia Antipolis. The author has contributed to research in topics: Crossover & Deconvolution. The author has an hindex of 3, co-authored 4 publications receiving 71 citations.

Papers
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Journal ArticleDOI
TL;DR: In this article, a software is described enabling kinetic analysis under non-isothermal or isothermal conditions from DSC, or from TG data, with thirteen methods of kinetic analysis, three for isothermal analysis and two for TG, with eight different functions for the choice of the proper mechanism for each of them.
Abstract: A software is described enabling kinetic analysis under non-isothermal or isothermal conditions from DSC, or from TG data. The program offers thirteen methods of kinetic analysis for DSC, three for isothermal analysis and two for TG, with eight different functions for the choice of the proper mechanism for each of them.

60 citations

Journal ArticleDOI
TL;DR: In this paper, feed-forward neural networks have been used for kinetic parameters determination and signal filtering in differential scanning calorimetry and the proper learning function was chosen and the network topology was optimized using an empiric procedure.
Abstract: Feedforward neural networks have been used for kinetic parameters determination and signal filtering in differential scanning calorimetry. The proper learning function was chosen and the network topology was optimized, using an empiric procedure. The learning process was achieved using simulated thermoanalytical curves. The resilient-propagation algorithm have led to the best minimization of the error computed over all the patterns. Relative errors on the thermodynamic and kinetic parameters were evaluated and compared to those obtained with the usual thermal analysis methods (single scan methods). The errors are much lower, especially in presence of noisy signals. Then, our program was adapted to simulate thermal effects with known thermodynamic and kinetic parameters, generated electrically, using a PC computer and an electronic interface on the serial port. These thermal effects have been generated by using an inconel thread.

16 citations

Journal ArticleDOI
TL;DR: The goal of the present study consists in developing and optimizing a genetic determination of the parameters at a given temperature and selecting the general architecture of the procedure and implementing it in the main software of calculation of flame temperature.
Abstract: A program is described which enables performing of genetic algorithms for the determination of two positive real parameters. These new types of procedures are tested on a software of determination of flame temperatures previously developed in a fully classic way. The genetic operators used are crossover and mutation. They perform operations on a binary coded form of the parameters. The goal of the present study consists in developing and optimizing a genetic determination of the parameters at a given temperature. We succeed in selecting the general architecture of the procedure and implementing it in our main software of calculation of flame temperature. We have chosen this pyrotechnic field of application because we knew the behaviour of the real parameters, so the debugging operations were easier.

3 citations

Journal ArticleDOI
TL;DR: In this article, a program is described which enables data processing of theoretical temperatures of flames of pyrotechnic reactions with simplified mathematics and a very large database of thermodynamic characteristics allows a very important number of different calculations of temperatures.
Abstract: A program is described which enables data processing of theoretical temperatures of flames of pyrotechnic reactions. This software has been developed with simplified mathematics. A very large database of thermodynamic characteristics allows a very important number of different calculations of temperatures. The program takes into account the phenomena of dissociation of the most important species present in the reactions that we have to use. The results that we obtained with this computer program are very satisfying.

1 citations


Cited by
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Journal ArticleDOI
TL;DR: In this paper, the authors present a review of the use of thermal analysis for the analysis of polymorphism and pseudo-polymorphism in drug substances and excipients, including solvates and impurities.

464 citations

Journal ArticleDOI
TL;DR: In this paper, it was shown that the assumption of a constant activation energy is a key parameter that must be considered in the case of a complex reaction mechanism leading to a great variation of the effective activation energy on conversion.

198 citations

Journal ArticleDOI
TL;DR: In this article, the curing reaction of stoichiometric and off-stoichiometric diglycidyl ether of bisphenol A (DGEBA) and 1,3-phenylene diamine (m -PDA) mixtures was studied by differential scanning calorimetry, thermogravimetric analysis and rheological measurements.

193 citations

Journal ArticleDOI
TL;DR: In this paper, peak maximum evolution methods and isoconversional methods are compared, and specific characteristics of each method are shown, from a mathematical viewpoint and by using simulated data, and a convenient way of correcting the activation energy of the Ozawa method is proposed.

153 citations

Journal ArticleDOI
TL;DR: In this article, the curing kinetics of polyfunctional benzoxazine resins based on arylamine, i.e., BA-a and BA-35x, were investigated.

140 citations