Dae-Woon Lim

Bio: Dae-Woon Lim is an academic researcher from Yonsei University. The author has contributed to research in topics: Metal-organic framework & Hydrogen storage. The author has an hindex of 16, co-authored 45 publications receiving 4635 citations. Previous affiliations of Dae-Woon Lim include Kyoto University & Seoul National University.

Fabrication of metal nanoparticles in metal–organic frameworks

Abstract: In this review, we highlight various preparative strategies and characterization methods for metal nanoparticles fabricated in porous metal–organic frameworks (MOFs) or porous coordination polymers (PCPs), and their applications in hydrogen storage and heterogeneous catalysis.

Proton Transport in Metal-Organic Frameworks.

Abstract: Solid-state proton conductors (SSPCs), which are a key component for the safety and efficiency of fuel cells, have received much attention due to their broad application in electrochemical devices....

A new SLM OFDM scheme with low complexity for PAPR reduction

Abstract: The authors introduce a new selected mapping (SLM) orthogonal frequency division multiplexing (OFDM) scheme with low computational complexity. The proposed SLM scheme transforms an input symbol sequence into a set of OFDM signals by multiplying the phase sequences to the signal after a certain intermediate stage of inverse fast Fourier transform (IFFT). Then, the OFDM signal with the lowest peak-to-average power ratio (PAPR) is selected for transmission. The new SLM OFDM scheme reduces the computational complexity, while it shows almost the same performance of PAPR reduction as that of the conventional SLM OFDM scheme.

Proton transfer in hydrogen-bonded degenerate systems of water and ammonia in metal–organic frameworks

Abstract: Porous crystalline metal–organic frameworks (MOFs) or porous coordination polymers (PCPs) are emerging as a new class of proton conductors with numerous investigations. Some of the MOFs exhibit an excellent proton-conducting performance (higher than 10−2 S cm−1) originating from the interesting hydrogen(H)-bonding networks with guest molecules, where the conducting medium plays a crucial role. In the overwhelming majority of MOFs, the conducting medium is H2O because of its degenerate conjugate acid–base system (H3O+ + H2O ⇔ H2O + H3O+ or OH− + H2O ⇔ H2O + OH−) and the efficient H-bonding ability through two proton donor and two acceptor sites with a tetrahedral geometry. Considering the systematic molecular similarity to water, ammonia (NH3; NH4+ + NH3 ⇔ NH3 + NH4+) is promising as the next proton-conducting medium. In addition, there are few reports on NH3-mediated proton conductivity in MOFs. In this perspective, we provide overviews of the degenerate water (hydronium or hydroxide)- or ammonia (ammonium)-mediated proton conduction system, the design strategies for proton-conductive MOFs, and the conduction mechanisms.

The Chemistry and Applications of Metal-Organic Frameworks

Abstract: Crystalline metal-organic frameworks (MOFs) are formed by reticular synthesis, which creates strong bonds between inorganic and organic units. Careful selection of MOF constituents can yield crystals of ultrahigh porosity and high thermal and chemical stability. These characteristics allow the interior of MOFs to be chemically altered for use in gas separation, gas storage, and catalysis, among other applications. The precision commonly exercised in their chemical modification and the ability to expand their metrics without changing the underlying topology have not been achieved with other solids. MOFs whose chemical composition and shape of building units can be multiply varied within a particular structure already exist and may lead to materials that offer a synergistic combination of properties.

Luminescent metal–organic frameworks for chemical sensing and explosive detection

Abstract: Metal–organic frameworks (MOFs) are a unique class of crystalline solids comprised of metal cations (or metal clusters) and organic ligands that have shown promise for a wide variety of applications Over the past 15 years, research and development of these materials have become one of the most intensely and extensively pursued areas A very interesting and well-investigated topic is their optical emission properties and related applications Several reviews have provided a comprehensive overview covering many aspects of the subject up to 2011 This review intends to provide an update of work published since then and focuses on the photoluminescence (PL) properties of MOFs and their possible utility in chemical and biological sensing and detection The spectrum of this review includes the origin of luminescence in MOFs, the advantages of luminescent MOF (LMOF) based sensors, general strategies in designing sensory materials, and examples of various applications in sensing and detection

Covalent organic frameworks (COFs): from design to applications

Abstract: Covalent organic frameworks (COFs) represent an exciting new type of porous organic materials, which are ingeniously constructed with organic building units via strong covalent bonds. The well-defined crystalline porous structures together with tailored functionalities have offered the COF materials superior potential in diverse applications, such as gas storage, adsorption, optoelectricity, and catalysis. Since the seminal work of Yaghi and co-workers in 2005, the rapid development in this research area has attracted intensive interest from researchers with diverse expertise. This critical review describes the state-of-the-art development in the design, synthesis, characterisation, and application of the crystalline porous COF materials. Our own opinions on further development of the COF materials are also presented for discussion (155 references).