Approaches, Derivatives and Applications Vasilios Georgakilas,† Michal Otyepka,‡ Athanasios B. Bourlinos,‡ Vimlesh Chandra, Namdong Kim, K. Christian Kemp, Pavel Hobza,‡,§,⊥ Radek Zboril,*,‡ and Kwang S. Kim* †Institute of Materials Science, NCSR “Demokritos”, Ag. Paraskevi Attikis, 15310 Athens, Greece ‡Regional Centre of Advanced Technologies and Materials, Department of Physical Chemistry, Faculty of Science, Palacky University Olomouc, 17. listopadu 12, 771 46 Olomouc, Czech Republic Center for Superfunctional Materials, Department of Chemistry, Pohang University of Science and Technology, San 31, Hyojadong, Namgu, Pohang 790-784, Korea Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, v.v.i., Flemingovo naḿ. 2, 166 10 Prague 6, Czech Republic

Functionalization of Graphene: Covalent and Non-Covalent Approaches, Derivatives and Applications

Graphene has attracted tremendous research interest in recent years, owing to its exceptional properties. The scaled-up and reliable production of graphene derivatives, such as graphene oxide (GO) and reduced graphene oxide (rGO), offers a wide range of possibilities to synthesize graphene-based functional materials for various applications. This critical review presents and discusses the current development of graphene-based composites. After introduction of the synthesis methods for graphene and its derivatives as well as their properties, we focus on the description of various methods to synthesize graphene-based composites, especially those with functional polymers and inorganic nanostructures. Particular emphasis is placed on strategies for the optimization of composite properties. Lastly, the advantages of graphene-based composites in applications such as the Li-ion batteries, supercapacitors, fuel cells, photovoltaic devices, photocatalysis, as well as Raman enhancement are described (279 references).

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Graphene-based composites

Graphene based materials: Past, present and future

Recent advances in graphene based polymer composites

http://staff.ulsu.ru/moliver/ref/polymers/pott11.pdf

Graphene-based polymer nanocomposites

Graphene, flat carbon nanosheets, has generated huge activity in many areas of science and engineering due to its unprecedented physical and chemical properties. With the development of wide-scale applicability including facile synthesis and high yield, this exciting material is ready for its practical application in the preparation of polymer nanocomposites. Here we report that nanocomposites based on fully exfoliated graphene nanosheets and poly(vinyl alcohol) (PVA) are prepared via a facial aqueous solution. A significant enhancement of mechanical properties of the graphene/PVA composites is obtained at low graphene loading; that is, a 150% improvement of tensile strength and a nearly 10 times increase of Young’s modulus are achieved at a graphene loading of 1.8 vol %. The comparison between the experimental results and theoretical simulation for Young’s modulus indicates that the graphene nanosheets in polymer matrix are mostly dispersed randomly in the nanocomposite films.

Enhanced Mechanical Properties of Graphene-Based Poly(vinyl alcohol) Composites

Despite great recent progress with graphene-based materials, the development of strong and cost-efficient multifunctional graphene-filled polymer composites has not yet to be achieved. A key challenge in the fabrication of nanoplatelet-filled polymer composites is the ability to realize the nanometer-level dispersion and the planar orientation of nanosheets in polymer matrices. In this report, ultrathin multilayer (PVA/GO)n films were successfully fabricated by bottom-up layer-by-layer (LBL) assembly of poly(vinyl alcohol) (PVA) and exfoliated graphene oxide (GO), in which exfoliated GO nanosheets were used as the building blocks. Typical tapping-mode atomic force microscope (AFM) and field emission scanning electron microscope (FESEM) images demonstrate an ordered arrangement of organic and inorganic layers. A significant enhancement of mechanical properties has been achieved, that is, a 98.7% improvement of elastic modulus (Er) and a 240.4% increase of hardness. This may be attributed to the well-define...

Alternate Multilayer Films of Poly(vinyl alcohol) and Exfoliated Graphene Oxide Fabricated via a Facial Layer-by-Layer Assembly

We have developed a facile and efficient methodology to prepare iron phthalocyanine-coated nanofibers by combining electrospinning and Cu(I)-catalyzed 1,3-dipolar Huisgen cycloaddition of azides an...

“Click” Chemistry for Facile Immobilization of Iron Phthalocyanines onto Electrospun Nanofiber Surface

In this paper, 6061-T6 aluminum alloy and 30CrMnSiA steel are bonded by inertia radial friction welding (IRFW). The formation mechanism of the aluminum/steel friction welded joints and the effect of the welding parameters on the mechanical properties are investigated through the microstructure, microzone composition, and mechanical property analysis. The results show that no visible intermetallic compound layers (IMCs) are detected on the aluminum/steel welding interface, which may be due to Si element aggregating in the welding interface and then forming a Al−Fe−Si phase, preventing the formation and growth of an Al−Fe IMCs. Eventually, a micron ultrathin interface reaction layer composed of Al0.7Fe3Si0.3, FeAl, and Fe3Al phases is formed at the aluminum/steel welding interface. The maximum average shear strength of the joint is 176 MPa. The shear fracture is a typical ductile fracture. Properly reducing the friction speed and increasing the upsetting pressure can improve the bonding strength of aluminum/steel joints.

/pdf/study-of-microstructure-and-properties-of-aluminum-steel-3olm3xcc.pdf

Dajun Chen

Papers

Enhanced Mechanical Properties of Graphene-Based Poly(vinyl alcohol) Composites

Alternate Multilayer Films of Poly(vinyl alcohol) and Exfoliated Graphene Oxide Fabricated via a Facial Layer-by-Layer Assembly

“Click” Chemistry for Facile Immobilization of Iron Phthalocyanines onto Electrospun Nanofiber Surface

Study of Microstructure and Properties of Aluminum/Steel Inertia Radial Friction Welding