Daniela Rubatto

Bio: Daniela Rubatto is an academic researcher from University of Bern. The author has contributed to research in topics: Zircon & Metamorphism. The author has an hindex of 56, co-authored 156 publications receiving 13175 citations. Previous affiliations of Daniela Rubatto include Australian National University & University of Lausanne.

Zircon and monazite response to prograde metamorphism in the Reynolds Range, central Australia

Abstract: We report an extensive field-based study of zircon and monazite in the metamorphic sequence of the Reynolds Range (central Australia), where greenschist- to granulite-facies metamorphism is recorded over a continuous crustal section. Detailed cathodoluminescence and back-scattered electron imaging, supported by SHRIMP U–Pb dating, has revealed the different behaviours of zircon and monazite during metamorphism. Monazite first recorded regional metamorphic ages (1576 ± 5 Ma), at amphibolite-facies grade, at ∼600 °C. Abundant monazite yielding similar ages (1557 ± 2 to 1585 ± 3 Ma) is found at granulite-facies conditions in both partial melt segregations and restites. New zircon growth occurred between 1562 ± 4 and 1587 ± 4 Ma, but, in contrast to monazite, is only recorded in granulite-facies rocks where melt was present (≥700 °C). New zircon appears to form at the expense of pre-existing detrital and inherited cores, which are partly resorbed. The amount of metamorphic growth in both accessory minerals increases with temperature and metamorphic grade. However, new zircon growth is influenced by rock composition and driven by partial melting, factors that appear to have little effect on the formation of metamorphic monazite. The growth of these accessory phases in response to metamorphism extends over the 30 Ma period of melt crystallisation (1557–1587 Ma) in a stable high geothermal regime. Rare earth element patterns of zircon overgrowths in leucosome and restite indicate that, during the protracted metamorphism, melt-restite equilibrium was reached. Even in the extreme conditions of long-lasting high temperature (750–800 °C) metamorphism, Pb inheritance is widely preserved in the detrital zircon cores. A trace of inheritance is found in monazite, indicating that the closure temperature of the U–Pb system in relatively large monazite crystals can exceed 750–800 °C.

Exhumation as fast as subduction

Abstract: We produced a pressure-temperature-time path in order to determine the exhumation rate of the deepest subducted Alpine rocks. In situ dating of peak-metamorphic titanite in an eclogite facies calc-silicate rock indicates that subduction to pressures of ∼3.5 GPa was reached at 35.1 ± 0.9 Ma. Titanite formed during two decompression stages, at 1 ± 0.15 GPa and ∼0.4–0.5 GPa, and yielded ages of 32.9 ± 0.9 Ma and 31.8 ± 0.5 Ma, respectively. Combining the age data and making assumptions about the conversion of pressure to depth yield mean exhumation rates of 3.4 cm/yr and 1.6 cm/yr. These rates imply that exhumation acted at plate tectonic speeds similar to subduction, and was significantly faster than erosion. We suggest that fast exhumation is driven by a combination of tectonic processes involving buoyancy and normal faulting.

The Composition of Zircon and Igneous and Metamorphic Petrogenesis

Abstract: Zircon is the main mineral in the majority of igneous and metamorphic rocks with Zr as an essential structural constituent. It is a host for significant fractions of the whole-rock abundance of U, Th, Hf, and the REE (Sawka 1988, Bea 1996, O’Hara et al. 2001). These elements are important geochemically as process indicators or parent isotopes for age determination. The importance of zircon in crustal evolution studies is underscored by its predominant use in U-Th-Pb geochronology and investigations of the temporal evolution of both the crust and lithospheric mantle. In the past decade an increasing interest in the composition of zircon, trace-elements in particular, has been motivated by the effort to better constrain in situ microprobe-acquired isotopic ages. Electron-beam compositional imaging and isotope-ratio measurement by in situ beam techniques—and the micrometer-scale spatial resolution that is possible—has revealed in many cases that single zircon crystals contain a record of multiple geologic events. Such events can either be zircon-consuming, alteration, or zircon-forming and may be separated in time by millions or billions of years. In many cases, calculated zircon isotopic ages do not coincide with ages of geologic events determined from other minerals or from whole-rock analysis. To interpret the geologic validity and significance of multiple ages, and ages unsupported by independent analysis of other isotopic systems, has been the impetus for most past investigations of zircon composition. Some recent compositional investigations of zircon have not been directly related to geochronology, but to the ability of zircon to influence or record petrogenetic processes in igneous and metamorphic systems. Sedimentary rocks may also contain a significant fraction of zircon. Although authigenic zircon has been reported (Saxena 1966, Baruah et al. 1995, Hower et al. 1999), it appears to be very rare and may in fact be related to …

Atlas of Zircon Textures

Abstract: The mineral zircon is extremely variable both in terms of external morphology and internal textures. These features reflect the geologic history of the mineral, especially the relevant episode(s) of magmatic or metamorphic crystallization (and recrystallization), strain imposed both by external forces and by internal volume expansion caused by metamictization, and chemical alteration. The paper presents a selection of both the most typical, but also of the less common, features seen in zircon, categorized according to the different geological processes responsible for their formation. The atlas is intended as a general guide for the interpretation of zircon characteristics, and of related isotopic data. Zircon has become one of the most widely used minerals for the extraction of information on the prehistory and genesis of magmatic, metamorphic and sedimentary rocks. Much of the geological usefulness of zircon stems from its suitability as a geochronometer based on the decay of U (and Th) to Pb, but in addition it is also the major host of the radiogenic isotopic tracer Hf, and it is used to determine oxygen isotopic compositions and REE and other trace element abundances, all of which yield useful clues concerning the history of the host rock, and in some case, the parent rock in which the precursor zircon crystallized. One of the major advantages of zircon is its ability to survive magmatic, metamorphic and erosional processes that destroy most other common minerals. Zircon-forming events tend to be preserved as distinct structural entities on a pre-existing zircon grain. Because of this ability, quite commonly zircon consists of distinct segments, each preserving a particular period of zircon-formation (or consumption). A long experience and modern instrumentation and techniques have provided the “zircon community” the means to image and interpret preserved textures, and hence to decipher the history and evolution of a rock. One …

Continental and Oceanic Crust Recycling-induced Melt^Peridotite Interactions in the Trans-North China Orogen: U^Pb Dating, Hf Isotopes and Trace Elements in Zircons from Mantle Xenoliths

Abstract: We present the first finding of continental crust-derived Precambrian zircons in garnet/spinel pyroxenite veins within mantle xenoliths carried by the Neogene Hannuoba basalt in the central zone of the North China Craton (NCC). Petrological and geochemical features indicate that these mantle-derived composite xenoliths were formed by silicic melt^lherzolite interaction. The Precambrian zircon ages can be classified into three age groups of 2·4^2·5 Ga, 1·6^2·2 Ga and 0·6^1·2 Ga, coinciding with major geological events in the NCC. These Precambrian zircons fall in the field of continental granitoid rocks in plots of U/Yb vs Hf and Y. Their igneous-type REE patterns and metamorphic zircon type CL images indicate that they were not crystallized during melt^peridotite interaction and subsequent high-pressure metamorphism.The 2·5 Ga zircons have positive eHf(t) values (2·9^10·6), whereas the younger Precambrian zircons are dominated by negative eHf(t) values, indicating an ancient continental crustal origin.These observations suggest that the Precambrian zircons were xenocrysts that survived melting of recycled continental crustal rocks and were then injected with silicate melt into the host peridotite. In addition to the Precambrian zircons, igneous zircons of 315 3 Ma (2 ), 80^170 Ma and 48^64 Ma were separated from the garnet/spinel pyroxenite veins; these provide evidence for lower continental crust and oceanic crust recycling-induced multi-episodic melt^peridotite interactions in the central zone of the NCC. The combination of the positive eHf(t) values (2·91^24·6) of the 315 Ma zircons with the rare occurrence of 302^324 Ma subduction-related diorite^granite plutons in the northern margin of the NCC implies that the 315 Ma igneous zircons might record melt^peridotite interactions in the lithospheric mantle induced by Palaeo-Asian oceanic crust subduction. Igneous zircons of age 80^170 Ma generally coexist with the Precambrian metamorphic zircons and have lower Ce/Yb and Th/U ratios, higher U/Yb ratios and greater negative Eu anomalies.The eHf(t) values of these zircons vary greatly from ^47·6 to 24·6.The 170^110 Ma zircons are generally characterized by negative eHf(t) values, whereas the 110^100 Ma zircons have positive eHf(t) values.These observations suggest that melt^peridotite interactions at 80^170 Ma were induced by partial melting of recycled continental crust. The 48^64 Ma igneous zircons are characterized by negligible Ce anomalies, unusually high REE, U and Th contents, and positive eHf(t) values.These features imply that the melt^peridotite interactions at 48^64 Ma could be associated with a depleted mantle-derived carbonate melt or fluid.