Materials for hydrogen-based energy storage – past, recent progress and future outlook

Magnesium based materials for hydrogen based energy storage: Past, present and future

Thermodynamics and kinetics of phase transformation in rare earth–magnesium alloys: A critical review

Mg-based materials are promising candidates for high capacity hydrogen storage. However, their poor hydrogenation/dehydrogenation kinetics and high desorption temperature are the main obstacles to their applications. This paper reports a method for in situ formation of cycle stable CeH2.73-MgH2-Ni nanocomposites, from the hydrogenation of as-melt Mg80Ce18Ni2 alloy, with excellent hydrogen storage performance. The nanocomposites demonstrate reversible hydrogen storage capacity of more than 4.0 wt %, at a low desorption temperature with fast kinetics and long cycle life. The temperature for the full hydrogenation/dehydrogenation cycle of the composites is significantly decreased to 505 K, which is about 100 K lower than that for pure Mg. The hydrogen desorption activation energy is 63 ± 3 kJ/mol H2 for the composites, which is significantly lower than those of Mg3Ce alloy and pure Mg (104 ± 7 and 158 ± 2 kJ/mol H2, respectively). X-ray diffraction and transmission electron microscopy have been used to revea...

Enhanced Hydrogen Storage Kinetics and Stability by Synergistic Effects of in Situ Formed CeH2.73 and Ni in CeH2.73-MgH2‑Ni Nanocomposites

This paper presents a review of the experimental achievements related to the development of high-power gyrotron oscillators for long-pulse or CW operation and pulsed gyrotrons for many applications. In addition, this work gives a short overview on the present development status of frequency step-tunable and multi-frequency gyrotrons, coaxial-cavity multi-megawatt gyrotrons, gyrotrons for technological and spectroscopy applications, relativistic gyrotrons, large orbit gyrotrons (LOGs), quasi-optical gyrotrons, fast- and slow-wave cyclotron autoresonance masers (CARMs), gyroklystrons, gyro-TWT amplifiers, gyrotwystron amplifiers, gyro-BWOs, gyro-harmonic converters, gyro-peniotrons, magnicons, free electron masers (FEMs), and dielectric vacuum windows for such high-power mm-wave sources. Gyrotron oscillators (gyromonotrons) are mainly used as high-power millimeter wave sources for electron cyclotron resonance heating (ECRH), electron cyclotron current drive (ECCD), stability control, and diagnostics of magnetically confined plasmas for clean generation of energy by controlled thermonuclear fusion. The maximum pulse length of commercially available 140 GHz, megawatt-class gyrotrons employing synthetic diamond output windows is 30 min (CPI and European KIT-SPC-THALES collaboration). The world record parameters of the European tube are as follows: 0.92 MW output power at 30-min pulse duration, 97.5% Gaussian mode purity, and 44% efficiency, employing a single-stage depressed collector (SDC) for energy recovery. A maximum output power of 1.5 MW in 4.0-s pulses at 45% efficiency was generated with the QST-TOSHIBA (now CANON) 110-GHz gyrotron. The Japan 170-GHz ITER gyrotron achieved 1 MW, 800 s at 55% efficiency and holds the energy world record of 2.88 GJ (0.8 MW, 60 min) and the efficiency record of 57% for tubes with an output power of more than 0.5 MW. The Russian 170-GHz ITER gyrotron obtained 0.99 (1.2) MW with a pulse duration of 1000 (100) s and 53% efficiency. The prototype tube of the European 2-MW, 170-GHz coaxial-cavity gyrotron achieved in short pulses the record power of 2.2 MW at 48% efficiency and 96% Gaussian mode purity. Gyrotrons with pulsed magnet for various short-pulse applications deliver Pout = 210 kW with τ = 20 μs at frequencies up to 670 GHz (η ≅ 20%), Pout = 5.3 kW at 1 THz (η = 6.1%), and Pout = 0.5 kW at 1.3 THz (η = 0.6%). Gyrotron oscillators have also been successfully used in materials processing. Such technological applications require tubes with the following parameters: f > 24 GHz, Pout = 4–50 kW, CW, η > 30%. The CW powers produced by gyroklystrons and FEMs are 10 kW (94 GHz) and 36 W (15 GHz), respectively. The IR FEL at the Thomas Jefferson National Accelerator Facility in the USA obtained a record average power of 14.2 kW at a wavelength of 1.6 μm. The THz FEL (NOVEL) at the Budker Institute of Nuclear Physics in Russia achieved a maximum average power of 0.5 kW at wavelengths 50–240 μm (6.00–1.25 THz).

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State-of-the-Art of High-Power Gyro-Devices and Free Electron Masers

Hydrogen storage properties of Mg–Ce–Ni nanocomposite induced from amorphous precursor with the highest Mg content

In this paper, a multigap extended output cavity was designed by 3-D simulations, which served as the output cavity for a W-band sheet-beam extended interaction klystron (SBEIK). In our numerical design, the circuit dimensions were systematically optimized by parametric finite-difference time-domain simulations, and the equivalent circuit for the output cavity was also analyzed. The proper external loading was selected by using a region of loss in 3-D, and the output power was optimized. The results were verified by using the coupler and the waveguide. The 2π mode of the optimized five-gap extended output cavities had an ohmic Q (Q0) of 1343.5, an external Q (Qe) of 501.6, and a loaded Q (QL) of 365.2 at 94.5 GHz. The 3-D particle-in-cell simulations predict that the output cavity of the SBEIK (75 kV and 4 A) can stably produce more than 50 kW of output power using a prebunched beam.

Particle-in-Cell Simulation and Optimization of Multigap Extended Output Cavity for a W-Band Sheet-Beam EIK

This paper reports the research work of an X-band sheet beam klystron with the aim of principle verification, which is fulfilled at the Institute of Electronics, Chinese Academy of Sciences. This paper includes two phases. The first phase is planned to build the sheet beam electron optics prototype tube using the closed periodically cusped magnetic focusing. The measured data shows that the rectangular beam with the cross section of 50 mm × 4 mm can propagate through ~ 300 mm from the cathode surface to the collector with the transmission of 92.4% at the voltage of 110 kV. This foregoing work successfully solves the beam formation and transportation and becomes the basis for developing the sheet beam klystron. In the second phase, the high-frequency interaction structure is designed and cold tested. The X-band sheet beam klystron is constructed and hot tested in the full voltage. The amplification characteristic can be observed near the voltage of 125 kV. For the drive power of 0.71 kW and the working frequency of 11.69 GHz, the output power of 2.8 MW is achieved with the 3 dB bandwidth of 30 MHz, and, correspondingly, the gain and the efficiency are 35.96 dB and 32.52%, respectively. At the same time, the beam transmission is 73.3%. An over 93% transmission is realized at the voltage of 135 kV, whereas the oscillation occurs in the tube. This research exhibits that the sheet beam klystron is a promising device for the high-power applications, whereas seeking the measures to overcome the oscillation is still an arduous task in the future.

Researches on an $X$ -Band Sheet Beam Klystron

The Ka -band extended interaction klystrons (EIK) have been developed at the Institute of Electronics, Chinese Academy of Sciences (IECAS), to satisfy the requirement for the high-power millimeter-wave sources in scientific researches. In this work, two kinds of high compression electron gun with the solid or hollow beams, the derivative electron optics systems using the compact permanent magnet uniform focusing and the shared efficient interaction circuit based on the multigap ladder cavity, have been studied in detail and well designed through a mass of calculations. After the mechanical design, finely manufacturing, and a series of technical processes, the Ka -band EIK prototype tubes have been successfully built and tested. For the solid beam scheme, the maximum output power achieves 20 kW in the bandwidth of 60 MHz, and, correspondingly, the gain of 53 dB and the efficiency of 24% are observed. The measured −1 and −3 dB bandwidths are about 220 and 350 MHz, respectively. Meanwhile, the beam transmission is excellent, that is over 97% in dc state and over 90% in RF operation. For the hollow beam case, an over 91% dc transmission test has finished.

Demonstration of a High-Power Ka -Band Extended Interaction Klystron

Theoretical analyses and numerical calculations have demonstrated that a closed periodic cusped magnetic (PCM) field can effectively confine a sheet electron beam in two transverse directions (i.e., in the wide and narrow dimensions, simultaneously) for stable long distance transport in which the sizes of the beam cross section are set by referring to the present state of the art. Moreover, the method for matching the transverse magnetic focusing force and the inner space charge force in the wide dimension of the sheet electron beam is given, and the longitudinal periodic length and the cross sectional shape of the closed PCM focusing structure can be determined. Calculations also demonstrate that the optimum focusing state can be attained by adjusting the wide dimension on the transverse section of the closed PCM structure independently. The work presented in this paper indicates that the closed PCM structure is very promising for the confinement of the sheet electron beam, and it can be helpful for guiding practical engineering design.

Ding Zhao

Papers

Hydrogen storage properties of Mg–Ce–Ni nanocomposite induced from amorphous precursor with the highest Mg content

Particle-in-Cell Simulation and Optimization of Multigap Extended Output Cavity for a W-Band Sheet-Beam EIK

Researches on an $X$ -Band Sheet Beam Klystron

Demonstration of a High-Power Ka -Band Extended Interaction Klystron

Validity of closed periodic magnetic focusing for sheet electron beams