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Dominique Mandon

Researcher at University of Strasbourg

Publications -  76
Citations -  1976

Dominique Mandon is an academic researcher from University of Strasbourg. The author has contributed to research in topics: Ligand & Porphyrin. The author has an hindex of 26, co-authored 76 publications receiving 1870 citations. Previous affiliations of Dominique Mandon include Centre national de la recherche scientifique & Delft University of Technology.

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Models for peroxidase compound I: generation and spectroscopic characterization of new oxoferryl porphyrin .pi. cation radical species

TL;DR: In this article, the triflato complexes of (tetrakis(2,6-dichlorophenyl)porphyrinato]- and (tetsarithm(2.4,6,trimethoxyphenyl)PORphrinato]-iron(III) in methylene chloride/methanol-d 4 4 have been characterized by a variety of spectroscopic techniques.
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Compound I and Compound II Analogues from Porpholactones.

TL;DR: The observation that Fe-O frequencies in the resonance Raman spectra of the porpholactone analogues of compounds I and II are not substantially different from those of porphyrins and by the axial appearance of the EPR signals of the high-spin ferric complexes is consistent with reports that the Fe=O unit of oxidized porphirins and chlorins is relatively insensitive to alteration of macrocycle symmetry.
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Trigonal Bipyramidal Geometry and Tridentate Coordination Mode of the Tripod in FeCl2 Complexes with Tris(2-pyridylmethyl)amine Derivatives Bis-α-Substituted with Bulky Groups. Structures and Spectroscopic Comparative Studies

TL;DR: Electric conductivity measurements show that, for all complexes, the measured values lie within the same range, significantly below those expected for ionic complexes, which strongly suggests that the coordination mode of the tripod is retained in solution.