Increasing quantities of pharmaceutical pollutants have been found in aquatic ecosystems. The treatment of pharmaceutical pollutants has been a major task that people have been committed to in recent years. The removal of pharmaceutical pollutants can be achieved by adsorption and advanced oxidation processes (AOPs). Compared with other carbon materials, biochar has a strong adsorption capacity and persulfate activation ability, and more importantly, biochar is cheap and easy to obtain; thus, it has higher economic benefits. This study firstly reviews the application of biochar in the removal of drugs (tetracycline (TC), sulfamethoxazole (SMX), acetaminophen (ACT), cephalexin (CPX), levofloxacin (LEV), etc.) through adsorption and persulfate-based AOPs. In addition, we summarize the adsorption mechanism of biochar for various pharmaceutical pollutants and the main attack sites on different pharmaceutical pollutants in persulfate-based AOPs catalyzed by biochar. Finally, the challenges and prospects of biochar with respect to the removal of pharmaceutical pollutants are put forward.

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A Review on Application of Biochar in the Removal of Pharmaceutical Pollutants through Adsorption and Persulfate-Based AOPs

A feasible biochar derived from biogas residue and its application in the efficient adsorption of tetracycline from an aqueous solution.

The recovery of carbon materials from biogas residue (BR) could efficiently promote the efficient utilization of waste and the preparation of novel materials. In this study, a green and feasible reagent of citric acid was introduced and applied in the modification of biogas residue biochar (BRC). The modified biogas residue biochar (CABRC) showed a superior adsorption ability due to its higher specific surface area (approximately 6 times that of the BRC). Additionally, the adsorption capacities of CABRC and BRC for TC were 58.25 mg/g and 20.77 mg/g, respectively, while the TC adsorption performance of CABRC was 2.8 times that of BRC. The adsorption of TC by both BRC and CABRC was primarily controlled by physical adsorption and chemical adsorption (including pore filling, hydrogen bonding, π-π DEA interaction, and electrostatic interaction). Therefore, CABRC should be considered an environmentally friendly material due to its higher adsorption performance, which could expand its application in wastewater treatment. 

A feasible biochar derived from biogas residue and its application in the efficient adsorption of tetracycline from an aqueous solution

Wheat straw derived biochar with hierarchically porous structure for bisphenol A removal: Preparation, characterization, and adsorption properties

Performance and mechanism of sycamore flock based biochar in removing oxytetracycline hydrochloride

High mesoporosity phosphorus-containing biochar fabricated from Camellia oleifera shells: Impressive tetracycline adsorption performance and promotion of pyrophosphate-like surface functional groups (C-O-P bond)

Dongmei Li

Papers

High mesoporosity phosphorus-containing biochar fabricated from Camellia oleifera shells: Impressive tetracycline adsorption performance and promotion of pyrophosphate-like surface functional groups (C-O-P bond)