Author
E. R. Polovtseva
Bio: E. R. Polovtseva is an academic researcher from Russian Academy of Sciences. The author has contributed to research in topics: Absorption spectroscopy & Spectral line. The author has an hindex of 8, co-authored 26 publications receiving 7623 citations.
Papers
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Harvard University1, University of Reims Champagne-Ardenne2, College of William & Mary3, Old Dominion University4, University of Lisbon5, University of Burgundy6, California Institute of Technology7, Centre national de la recherche scientifique8, Université catholique de Louvain9, University of York10, University College London11, National Institute of Standards and Technology12, University of Waterloo13, National Center for Atmospheric Research14, University of Cologne15, Karlsruhe Institute of Technology16, Langley Research Center17
TL;DR: The new HITRAN is greatly extended in terms of accuracy, spectral coverage, additional absorption phenomena, added line-shape formalisms, and validity, and molecules, isotopologues, and perturbing gases have been added that address the issues of atmospheres beyond the Earth.
Abstract: This paper describes the contents of the 2016 edition of the HITRAN molecular spectroscopic compilation. The new edition replaces the previous HITRAN edition of 2012 and its updates during the intervening years. The HITRAN molecular absorption compilation is composed of five major components: the traditional line-by-line spectroscopic parameters required for high-resolution radiative-transfer codes, infrared absorption cross-sections for molecules not yet amenable to representation in a line-by-line form, collision-induced absorption data, aerosol indices of refraction, and general tables such as partition sums that apply globally to the data. The new HITRAN is greatly extended in terms of accuracy, spectral coverage, additional absorption phenomena, added line-shape formalisms, and validity. Moreover, molecules, isotopologues, and perturbing gases have been added that address the issues of atmospheres beyond the Earth. Of considerable note, experimental IR cross-sections for almost 300 additional molecules important in different areas of atmospheric science have been added to the database. The compilation can be accessed through www.hitran.org. Most of the HITRAN data have now been cast into an underlying relational database structure that offers many advantages over the long-standing sequential text-based structure. The new structure empowers the user in many ways. It enables the incorporation of an extended set of fundamental parameters per transition, sophisticated line-shape formalisms, easy user-defined output formats, and very convenient searching, filtering, and plotting of data. A powerful application programming interface making use of structured query language (SQL) features for higher-level applications of HITRAN is also provided.
7,638 citations
University of Paris1, Université Paris-Saclay2, Pierre-and-Marie-Curie University3, University of Reims Champagne-Ardenne4, College of William & Mary5, Centre national de la recherche scientifique6, California Institute of Technology7, University of Grenoble8, University of Paris-Sud9, University College London10, Université catholique de Louvain11, university of lille12, University of Massachusetts Lowell13, University of Leicester14, University of Science and Technology of China15, University of Castilla–La Mancha16, Russian Academy of Sciences17, University of Colorado Boulder18, Tomsk Polytechnic University19, University of Cologne20, University of Oslo21, Karlsruhe Institute of Technology22, University of Lethbridge23, University College Cork24, Université libre de Bruxelles25
TL;DR: The GEISA database (Gestion et Etude des Informations Spectroscopiques Atmospheriques: Management and Study of Atmospheric Spectroscopic Information) has been developed and maintained by the ARA/ABC(t) group at LMD since 1974.
347 citations
TL;DR: In this paper, the parent isotopologue of the hydrogen sulfide molecule, H232S, is collated from 33 publications into a single database and reviewed critically, based on this information, rotation-vibration energy levels are determined for the ground electronic state using the Measured Active Rotational-Vibrational Energy Levels (Marvel ) technique.
Abstract: 44 325 measured and assigned transitions of H232S, the parent isotopologue of the hydrogen sulfide molecule, are collated from 33 publications into a single database and reviewed critically. Based on this information, rotation-vibration energy levels are determined for the ground electronic state using the Measured Active Rotational-Vibrational Energy Levels ( Marvel ) technique. The ortho and para principal components of the measured spectroscopic network of H232S are considered separately. The verified set of 25 293 ortho- and 18 778 para- H232S transitions determine 3969 ortho and 3467 para energy levels. The Marvel results are compared with alternative data compilations, including a theoretical variational linelist.
39 citations
12 Jan 2004
TL;DR: In this article, a high-resolution FT absorption spectrum of H2S from 5700 to 6600 cm-1 was experimentally recorded and theoretically treated and 1100 precise energy levels were derived for the 2nd hexad interacting states of H232S, H233S, and H234S isotope species including the highly excited (050) state.
Abstract: High resolution FT absorption spectrum of H2S from 5700 to 6600 cm-1 was experimentally recorded and theoretically treated. As a result of the spectrum assignment 1100 precise energy levels were derived for the 2nd hexad interacting states of H232S, H233S, and H234S isotope species including the highly excited (050) state. These energy levels were modeled using Watson-type rotational Hamiltonian and taking into account Coriolis, Darling-Dennison and weak Fermi-resonance interactions inside polyad of interacting states. An average accuracy of the energy levels fitting is of 0.0019 cm-1 for the main isotope species. New evaluation of the band origin of the dark (012) state Ev = 6385.299cm-1 is obtained from the fitting process which agrees well with recent prediction by Naumenko et al . (J. Mol. Spectrosc . 50 , 100-110 (2001)). Precise line intensity measurements were performed for more than 1200 absorption lines with accuracy varying from 1 to 7%. These intensities were modeled within 3.3% using wavefunctions derived in the process of the energy levels fitting. The transformed transition moment expansion with 29 terms for 1088 intensities was used. Detailed and accurate H2S absorption line list was generated in the HITRAN format for the analyzed spectral region.© (2004) COPYRIGHT SPIE--The International Society for Optical Engineering. Downloading of the abstract is permitted for personal use only.
16 citations
TL;DR: A unique instrumentation complex of the Institute of Atmospheric Optics SB RAS is presented in this article, which makes possible simultaneous measurements of a great number of optical, meteorological, and radiative parameters of the atmosphere, as well as characteristics of aerosol and gas composition.
Abstract: A unique instrumentation complex of the Institute of Atmospheric Optics SB RAS is presented. The complex has no analogues anywhere in the world, and makes possible simultaneous measurements of a great number of optical, meteorological, and radiative parameters of the atmosphere, as well as characteristics of aerosol and gas composition. The instrumentation complex is based on permanent stations recording numerous parameters of the atmosphere, namely, TOR (Tropospheric Ozone Research) station, Aerosol Monitoring Station, BEC (Basic Experimental Complex), Fonovaya (Background) Station, and stations for receiving satellite images (NOAA, MODIS/TERRA, MODIS/AQUA). An important part of the complex is the Tu-134 aircraft laboratory enabling measurement of atmospheric parameters in the altitude range up to 7 km. In addition, the following instruments are used in experiments: weather balloons, lidars, sodars, sun photometers, Fourier spectrometers, and others. Satellite data are also used for interpretation of dat...
15 citations
Cited by
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Harvard University1, University of Reims Champagne-Ardenne2, College of William & Mary3, Old Dominion University4, University of Lisbon5, University of Burgundy6, California Institute of Technology7, Centre national de la recherche scientifique8, Université catholique de Louvain9, University of York10, University College London11, National Institute of Standards and Technology12, University of Waterloo13, National Center for Atmospheric Research14, University of Cologne15, Karlsruhe Institute of Technology16, Langley Research Center17
TL;DR: The new HITRAN is greatly extended in terms of accuracy, spectral coverage, additional absorption phenomena, added line-shape formalisms, and validity, and molecules, isotopologues, and perturbing gases have been added that address the issues of atmospheres beyond the Earth.
Abstract: This paper describes the contents of the 2016 edition of the HITRAN molecular spectroscopic compilation. The new edition replaces the previous HITRAN edition of 2012 and its updates during the intervening years. The HITRAN molecular absorption compilation is composed of five major components: the traditional line-by-line spectroscopic parameters required for high-resolution radiative-transfer codes, infrared absorption cross-sections for molecules not yet amenable to representation in a line-by-line form, collision-induced absorption data, aerosol indices of refraction, and general tables such as partition sums that apply globally to the data. The new HITRAN is greatly extended in terms of accuracy, spectral coverage, additional absorption phenomena, added line-shape formalisms, and validity. Moreover, molecules, isotopologues, and perturbing gases have been added that address the issues of atmospheres beyond the Earth. Of considerable note, experimental IR cross-sections for almost 300 additional molecules important in different areas of atmospheric science have been added to the database. The compilation can be accessed through www.hitran.org. Most of the HITRAN data have now been cast into an underlying relational database structure that offers many advantages over the long-standing sequential text-based structure. The new structure empowers the user in many ways. It enables the incorporation of an extended set of fundamental parameters per transition, sophisticated line-shape formalisms, easy user-defined output formats, and very convenient searching, filtering, and plotting of data. A powerful application programming interface making use of structured query language (SQL) features for higher-level applications of HITRAN is also provided.
7,638 citations
Journal Article•
TL;DR: In this article, the authors present a document, redatto, voted and pubblicato by the Ipcc -Comitato intergovernativo sui cambiamenti climatici - illustra la sintesi delle ricerche svolte su questo tema rilevante.
Abstract: Cause, conseguenze e strategie di mitigazione Proponiamo il primo di una serie di articoli in cui affronteremo l’attuale problema dei mutamenti climatici. Presentiamo il documento redatto, votato e pubblicato dall’Ipcc - Comitato intergovernativo sui cambiamenti climatici - che illustra la sintesi delle ricerche svolte su questo tema rilevante.
4,187 citations
TL;DR: In this paper, a new molecular spectroscopic database for high-temperature modeling of the spectra of molecules in the gas phase is described, called HITEMP, which is analogous to the HITRAN database but encompasses many more bands and transitions than HitRAN for the absorbers H2O, CO2, CO, NO and OH.
Abstract: A new molecular spectroscopic database for high-temperature modeling of the spectra of molecules in the gas phase is described. This database, called HITEMP, is analogous to the HITRAN database but encompasses many more bands and transitions than HITRAN for the absorbers H2O, CO2, CO, NO, and OH. HITEMP provides users with a powerful tool for a great many applications: astrophysics, planetary and stellar atmospheres, industrial processes, surveillance, non-local thermodynamic equilibrium problems, and investigating molecular interactions, to name a few. The sources and implementation of the spectroscopic parameters incorporated into HITEMP are discussed.
1,715 citations
TL;DR: This paper presented an up-to-date, comprehensive tabulation of EF for known pyrogenic species based on measurements made in smoke that has cooled to ambient temperature, but not yet undergone significant photochemical processing.
Abstract: . Biomass burning (BB) is the second largest source of trace gases and the largest source of primary fine carbonaceous particles in the global troposphere. Many recent BB studies have provided new emission factor (EF) measurements. This is especially true for non-methane organic compounds (NMOC), which influence secondary organic aerosol (SOA) and ozone formation. New EF should improve regional to global BB emissions estimates and therefore, the input for atmospheric models. In this work we present an up-to-date, comprehensive tabulation of EF for known pyrogenic species based on measurements made in smoke that has cooled to ambient temperature, but not yet undergone significant photochemical processing. All EFs are converted to one standard form (g compound emitted per kg dry biomass burned) using the carbon mass balance method and they are categorized into 14 fuel or vegetation types. Biomass burning terminology is defined to promote consistency. We compile a large number of measurements of biomass consumption per unit area for important fire types and summarize several recent estimates of global biomass consumption by the major types of biomass burning. Post emission processes are discussed to provide a context for the emission factor concept within overall atmospheric chemistry and also highlight the potential for rapid changes relative to the scale of some models or remote sensing products. Recent work shows that individual biomass fires emit significantly more gas-phase NMOC than previously thought and that including additional NMOC can improve photochemical model performance. A detailed global estimate suggests that BB emits at least 400 Tg yr−1 of gas-phase NMOC, which is almost 3 times larger than most previous estimates. Selected recent results (e.g. measurements of HONO and the BB tracers HCN and CH3CN) are highlighted and key areas requiring future research are briefly discussed.
1,472 citations
TL;DR: In this article, the authors present the basis for each technique, recent developments in methods and performance limitations, and present a performance comparison of different techniques, taking data reported over the preceding decade, and draw conclusions from this benchmarking.
Abstract: The detection and measurement of gas concentrations using the characteristic optical absorption of the gas species is important for both understanding and monitoring a variety of phenomena from industrial processes to environmental change. This study reviews the field, covering several individual gas detection techniques including non-dispersive infrared, spectrophotometry, tunable diode laser spectroscopy and photoacoustic spectroscopy. We present the basis for each technique, recent developments in methods and performance limitations. The technology available to support this field, in terms of key components such as light sources and gas cells, has advanced rapidly in recent years and we discuss these new developments. Finally, we present a performance comparison of different techniques, taking data reported over the preceding decade, and draw conclusions from this benchmarking.
1,293 citations