Author
Eite Drent
Other affiliations: Royal Dutch Shell, University of York
Bio: Eite Drent is an academic researcher from Leiden University. The author has contributed to research in topics: Catalysis & Palladium. The author has an hindex of 25, co-authored 55 publications receiving 3278 citations. Previous affiliations of Eite Drent include Royal Dutch Shell & University of York.
Topics: Catalysis, Palladium, Carbonylation, Phosphine, Allyl alcohol
Papers published on a yearly basis
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836 citations
TL;DR: In this paper, a homogeneous palladium catalyst system was developed for the production of perfectly alternating copolymers of carbon monoxide with ethylene, where C 3 units randomly replace ethylene units along the chain.
464 citations
TL;DR: In this paper, copolymerisation of ethene and alkylacrylates is catalysed by palladium modified with di(2-methoxyphenyl)phosphinobenzene-2-sulfonic acid (DOPPBS); a linear polymer is produced in which acrylate units are incorporated into the polyethylene backbone.
383 citations
TL;DR: In this paper, a review of the mechanisms proposed for the isomerisation of allylic alcohols is given while some catalyst systems are singled out to discuss mechanistic research, such as the synthesis of enols and enolates, chiral carbonyl compounds and silyl substituted ketones.
228 citations
TL;DR: In this article, a homogeneous palladium catalysts for the selective production of methyl methacrylate by methoxycarbonylation of propyne was developed. But the performance of these catalysts was limited by the fact that the 2-pyridylphosphine ligand plays an essential role both as a chelating PN ligand and as a monocoordinated ligand in the rate-determining step.
226 citations
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2,770 citations
1,358 citations
1,124 citations
TL;DR: The functionalized magnetically retrievable catalysts or nanocatalysts that are increasingly being used in catalysis, green chemistry and pharmaceutically significant reactions are summarized in this review.
Abstract: Surface functionalization of nano-magnetic nanoparticles is a well-designed way to bridge the gap between heterogeneous and homogeneous catalysis. The introduction of magnetic nanoparticles (MNPs) in a variety of solid matrices allows the combination of well-known procedures for catalyst heterogenization with techniques for magnetic separation. Magnetite is a well-known material, also known as ferrite (Fe3O4), and can be used as a versatile support for functionalization of metals, organocatalysts, N-heterocyclic carbenes, and chiral catalysts. It is used as a support for important homogeneous catalytically active metals such as Pd, Pt, Cu, Ni, Co, Ir, etc. to obtain stable and magnetically recyclable heterogeneous catalysts. Homogeneous organocatalysts can be successfully decorated with linkers/ligands on the surface of magnetite or alternatively the organocatalysts can be directly immobilized on the surface of magnetite. The functionalized magnetically retrievable catalysts or nanocatalysts that are increasingly being used in catalysis, green chemistry and pharmaceutically significant reactions are summarized in this review.
1,057 citations
TL;DR: Photochemical Electron-Transfer Reactions with a Catalytic Sensitizer 1068 6.1.1 Photochemical Extrusion of Small Molecules 1067 6.2.2 Photochemical Rearrangings 1061 4.4.3.
Abstract: 2.3. [4 + 4] Cycloadditions 1058 2.4. Photocycloadditions of Aromatic Compounds 1058 2.4.1. Benzene Derivatives 1058 2.4.2. Condensed Aromatic Compounds 1060 3. Photochemical Rearrangements 1061 4. Cyclizations 1064 4.1. Pericyclizations 1064 4.2. Norrish−Yang Reaction 1066 5. Photochemical Extrusion of Small Molecules 1067 6. Photochemical Electron Transfer 1068 6.1. Photochemical Electron-Transfer Reactions with a Catalytic Sensitizer 1068
1,046 citations