Emily M. Klein

Bio: Emily M. Klein is an academic researcher from Duke University. The author has contributed to research in topics: Basalt & Mid-ocean ridge. The author has an hindex of 24, co-authored 57 publications receiving 4569 citations. Previous affiliations of Emily M. Klein include Columbia University.

Global correlations of ocean ridge basalt chemistry with axial depth and crustal thickness

Abstract: Regional averages of the major element chemistry of ocean ridge basalts, corrected for low-pressure fractionation, correlate with regional averages of axial depth for the global system of ocean ridges, including hot spots, cold spots, and back arc basins, as well as “normal” ocean ridges. Quantitative consideration of the variations of each major element during melting of the mantle suggests that the global major element variations can be accounted for by ∼8–20% melting of the mantle at associated mean pressures of 5–16 kbar. The lowest extents of melting occur at shallowest depths in the mantle and are associated with the deepest ocean ridges. Calculated mean primary magmas show a range in composition from 10 to 15 wt % MgO, and the primary magma compositions correlate with depth. Data for Sm, Yb, Sc, and Ni are consistent with the major elements, but highly incompatible elements show more complicated behavior. In addition, some hot spots have anomalous chemistry, suggesting major element heterogeneity. Thermal modeling of mantle ascending adiabatically beneath the ridge is consistent with the chemical data and melting calculations, provided the melt is tapped from throughout the ascending mantle column. The thermal modeling independently predicts the observed relationships among basalt chemistry, ridge depth, and crustal thickness resulting from temperature variations in the mantle. Beneath the shallowest and deepest ridge axes, temperature differences of approximately 250°C in the subsolidus mantle are required to account for the global systematics.

Petrological systematics of mid-ocean ridge basalts: Constraints on melt generation beneath ocean ridges

Abstract: Mid-ocean ridge basalts (MORB) are a consequence of pressure-release melting beneath ocean ridges, and contain much information concerning melt formation, melt migration and heterogeneity within the upper mantle. MORB major element chemical systematics can be divided into global and local aspects, once they have been corrected for low pressure fractionation and interlaboratory biases. Regional average compositions for ridges unaffected by hot spots ("normal" ridges) can be used to define the global correlations among normalized Na20, FeO, TiO2 and Si02 contents, CaO/Al 203 ratios, axial depth and crustal thickness. Back-arc basins show similar correlations, but are offset to lower FeO and TiO2 contents. Some hot spots, such as the Azores and Galapagos, disrupt the systematics of nearby ridges and have the opposite relationships between FeO, Na 20 and depth over distances of 1000 km. Local variations in basalt chemistry from slowand fast-spreading ridges are distinct from one another. On slow-spreading ridges, correlations among the elements cross the global vector of variability at a high angle. On the fast-spreading East Pacific Rise (EPR), correlations among the elements are distinct from both global and slow-spreading compositional vectors, and involve two components of variation. Spreading rate does not control the global correlations, but influences the standard deviations of axial depth, crustal thickness, and MgO contents of basalts. Global correlations are not found in very incompatible trace elements, even for samples far from hot spots. Moderately compatible trace elements for normal ridges, however, correlate with the major elements. Trace element systematics are significantly different for the EPR and the mid-Atlantic Ridge (MAR). Normal portions of the MAR are very depleted in REE, with little variability; hot spots cause large long wavelength variations in REE abundances. Normal EPR basalts are significantly more enriched than MAR basalts from normal ridges, and still more enriched basalts can erupt sporadically along the entire length of the EPR. This leads to very different histograms of distribution for the data sets as a whole, and a very different distribution of chemistry along strike for the two ridges. Despite these differences, the mean Ce/Sm ratios from the two ridges are identical. Existing methods for calculating the major element compositions of mantle melts [Klein and Langmuir, 1987; McKenzie and Bickle, 1988; Niu and Batiza, 1991] are critically examined. New quantitative methods for mantle melting and high pressure fractionation are developed to evaluate the chemical consequences of melting and fractionation processes and mantle heterogeneity. The new methods rely on new equations for partition coefficients for the major elements between mantle minerals and melts. The melting calculations can be used to investigate the chemical compositions produced by small extents of melting or high pressures of melting that cannot yet be determined experimentally. Application of the new models to the observations described above leads to two major conclusions: (1) The global correlations for normal ridges are caused by variations in mantle temperature, as suggested by Klein and Langmuir [1987] and not by mantle heterogeneity. (2) Local variations are caused by melting processes, but are not yet quantitatively accounted for. On slower spreading ridges, local variations are controlled by the melting regime in the mantle. On the EPR, local variations are predominantly controlled by ubiquitous, small scale heterogeneites. Volatile content may be an important and as yet undetermined factor in affecting the observed variations in major elements. We propose a hypothesis, similar to one proposed by Allegre et al [1984] for isotopic data, to explain the differences between the Atlantic and Pacific local trends, and the trace element systematics of the two ocean basins, as consequences of spreading rate and a different distribution of enriched components from hot spots in the two ocean basins. In the Atlantic, the hot spot influence is in discrete areas, and produces clear depth and chemical anomalies. Ridge segments far from hot spots do not contain enriched

Isotope evidence of a mantle convection boundary at the Australian-Antarctic Discordance

Abstract: Basalts from the Southeast Indian Ridge south of Australia form two geographically and isotopically distinct groups that show affinities with either Indian Ocean or Pacific/Atlantic Ocean isotope compositions. The data raise the possibility that there is a sharp boundary between the Indian and Pacific Ocean isotope provinces. The isotope boundary occurs over less than 200km within the Australian–Antarctic Discordance, a technically complex region believed to overlie a zone of downwelling mantle flow.

Ocean-ridge basalts with convergent-margin geochemical affinities from the Chile Ridge

Abstract: COLLISIONS between active spreading centres and subduction zones have occurred frequently throughout Earth history1. Of the few sites of ridge subduction active today, the southern Chile Ridge has the simplest tectonic history2. We report here that basalts recovered from the Chile Ridge adjacent to the Chile Trench have geochemical characteristics unlike those of mid-ocean-ridge basalts sampled elsewhere, and show affinities with arc volcanics. The observed chemical variations are consistent with contamination of depleted sub-oceanic mantle by marine sediments and altered oceanic crust, which may have been derived from the adjacent subduction zone. Although some ocean islands show evidence of crustal recycling3–5, the Chile Ridge lavas are the first ocean-ridge basalts to exhibit such extreme geochemical characteristics, and may thus offer the opportunity to study the development of one type of mantle heterogeneity as it occurs. The discovery of ocean-ridge basalts with convergent-margin chemical characteristics suggests that caution is warranted in using trace-element systematics to identify the provenance (mid-ocean ridge or supra-subduction zone) of ophiolites6,7.

Magmatism at rift zones: The generation of volcanic continental margins and flood basalts

Abstract: When continents rift to form new ocean basins, the rifting is sometimes accompanied by massive igneous activity. We show that the production of magmatically active rifted margins and the effusion of flood basalts onto the adjacent continents can be explained by a simple model of rifting above a thermal anomaly in the underlying mantle. The igneous rocks are generated by decompression melting of hot asthenospheric mantle as it rises passively beneath the stretched and thinned lithosphere. Mantle plumes generate regions beneath the lithosphere typically 2000 km in diameter with temperatures raised 100–200°C above normal. These relatively small mantle temperature increases are sufficient to cause the generation of huge quantities of melt by decompression: an increase of 100°C above normal doubles the amount of melt whilst a 200°C increase can quadruple it. In the first part of this paper we develop our model to predict the effects of melt generation for varying amounts of stretching with a range of mantle temperatures. The melt generated by decompression migrates rapidly upward, until it is either extruded as basalt flows or intruded into or beneath the crust. Addition of large quantities of new igneous rock to the crust considerably modifies the subsidence in rifted regions. Stretching by a factor of 5 above normal temperature mantle produces immediate subsidence of more than 2 km in order to maintain isostatic equilibrium. If the mantle is 150°C or more hotter than normal, the same amount of stretching results in uplift above sea level. Melt generated from abnormally hot mantle is more magnesian rich than that produced from normal temperature mantle. This causes an increase in seismic velocity of the igneous rocks emplaced in the crust, from typically 6.8 km/s for normal mantle temperatures to 7.2 km/s or higher. There is a concomitant density increase. In the second part of the paper we review volcanic continental margins and flood basalt provinces globally and show that they are always related to the thermal anomaly created by a nearby mantle plume. Our model of melt generation in passively upwelling mantle beneath rifting continental lithosphere can explain all the major rift-related igneous provinces. These include the Tertiary igneous provinces of Britain and Greenland and the associated volcanic continental margins caused by opening of the North Atlantic in the presence of the Iceland plume; the Parana and parts of the Karoo flood basalts together with volcanic continental margins generated when the South Atlantic opened; the Deccan flood basalts of India and the Seychelles-Saya da Malha volcanic province created when the Seychelles split off India above the Reunion hot spot; the Ethiopian and Yemen Traps created by rifting of the Red Sea and Gulf of Aden region above the Afar hot spot; and the oldest and probably originally the largest flood basalt province of the Karoo produced when Gondwana split apart. New continental splits do not always occur above thermal anomalies in the mantle caused by plumes, but when they do, huge quantities of igneous material are added to the continental crust. This is an important method of increasing the volume of the continental crust through geologic time.

Mantle geochemistry: the message from oceanic volcanism

Abstract: Basaltic volcanism 'samples' the Earth's mantle to great depths, because solid-state convection transports deep material into the (shallow) melting region. The isotopic and trace-element chemistry of these basalts shows that the mantle contains several isotopically and chemically distinct components, which reflect its global evolution. This evolution is characterized by upper-mantle depletion of many trace elements, possible replenishment from the deeper, less depleted mantle, and the recycling of oceanic crust and lithosphere, but of only small amounts of continental material.