Water scarcity is a particularly severe challenge in arid and desert climates. While a substantial amount of water is present in the form of vapour in the atmosphere, harvesting this water by state-of-the-art dewing technology can be extremely energy intensive and impractical, particularly when the relative humidity (RH) is low (i.e., below ~40% RH). In contrast, atmospheric water generators that utilise sorbents enable capture of vapour at low RH conditions and can be driven by the abundant source of solar-thermal energy with higher efficiency. Here, we demonstrate an air-cooled sorbent-based atmospheric water harvesting device using the metal−organic framework (MOF)-801 [Zr6O4(OH)4(fumarate)6] operating in an exceptionally arid climate (10–40% RH) and sub-zero dew points (Tempe, Arizona, USA) with a  thermal efficiency (solar input to water conversion) of ~14%. We predict that this device delivered over 0.25 L of water per kg of MOF for a single daily cycle.

/pdf/adsorption-based-atmospheric-water-harvesting-device-for-l657hzd1js.pdf

Adsorption-based atmospheric water harvesting device for arid climates.

Energy-efficient production of water from desert air has not been developed. A proof-of-concept device for harvesting water at low relative humidity was reported; however, it used external cooling and was not desert-tested. We report a laboratory-to-desert experiment where a prototype using up to 1.2 kg of metal-organic framework (MOF)-801 was tested in the laboratory and later in the desert of Arizona, USA. It produced 100 g of water per kilogram of MOF-801 per day-and-night cycle, using only natural cooling and ambient sunlight as a source of energy. We also report an aluminum-based MOF-303, which delivers more than twice the amount of water. The desert experiment uncovered key parameters pertaining to the energy, material, and air requirements for efficient production of water from desert air, even at a subzero dew point.

Practical water production from desert air.

United States. Dept. of Energy. Office of Basic Energy Sciences (Solid-State Solar-Thermal Energy Conversion Center)

Condensation heat transfer on superhydrophobic surfaces

The Earth’s atmosphere holds approximately 12 900 billion tons of fresh water distributed all over the world with fast replenishment. Atmospheric water harvesting is emerging as a promising strategy for clean water production in arid regions, land-locked areas, and remote communities. The water vapor sorbent is the key component for atmospheric water harvesting devices based on absorbing-releasing process. In this work, a flexible hybrid photothermal water sorbent composed of deliquescent salt and hydrogel was rationally fabricated. It possesses superior water sorption capacity even in low humidity air thanks to the deliquescent salt and maintains a solid form after it sorbs a large amount of water owing to the hydrogel platform. The harvested water could be easily released under regular sunlight via the photothermal effect, and it can be directly reused without noticeable capacity fading. An “easy-to-assemble-at-household” prototype device with 35 g of the dry hydrogel was tested outdoors under field con...

https://pubs.acs.org/doi/pdf/10.1021/acs.est.8b02852

Hybrid Hydrogel with High Water Vapor Harvesting Capacity for Deployable Solar-Driven Atmospheric Water Generator

Producing affordable freshwater has been considered as a great societal challenge, and most conventional desalination technologies are usually accompanied with large energy consumption and thus struggle with the trade-off between water and energy, i.e., the water-energy nexus. In recent decades, the fast development of state-of-the-art photothermal materials has injected new vitality into the field of freshwater production, which can effectively harness abundant and clean solar energy via the photothermal effect to fulfill the blue dream of low-energy water purification/harvesting, so as to reconcile the water-energy nexus. Driven by the opportunities offered by photothermal materials, tremendous effort has been made to exploit diverse photothermal-assisted water purification/harvesting technologies. At this stage, it is imperative and important to review the recent progress and shed light on the future trend in this multidisciplinary field. Here, a brief introduction of the fundamental mechanism and design principle of photothermal materials is presented, and the emerging photothermal applications such as photothermal-assisted water evaporation, photothermal-assisted membrane distillation, photothermal-assisted crude oil cleanup, photothermal-enhanced photocatalysis, and photothermal-assisted water harvesting from air are summarized. Finally, the unsolved challenges and future perspectives in this field are emphasized. It is envisioned that this work will help arouse future research efforts to boost the development of solar-driven low-energy water purification/harvesting.

/pdf/harnessing-solar-driven-photothermal-effect-toward-the-water-38vhngvh2u.pdf

Harnessing Solar-Driven Photothermal Effect toward the Water-Energy Nexus.

Landfill gas-powered atmospheric water harvesting for oilfield operations in the United States

Electrowetting-based enhancement of droplet growth dynamics and heat transfer during humid air condensation

Modeling humid air condensation in waste natural gas-powered atmospheric water harvesting systems

Natural gas worth tens of billions of dollars is flared annually, which leads to resource waste and environmental issues. This work introduces and analyzes a novel concept for flared gas utilization, wherein the gas that would have been flared is instead used to condense atmospheric moisture. Natural gas, which is currently being flared, can alternatively power refrigeration systems to generate the cooling capacity for large scale atmospheric water harvesting (AWH). This approach solves two pressing issues faced by the oil–gas industry, namely gas flaring, and sourcing water for oilfield operations like hydraulic fracturing, drilling and water flooding. Multiple technical pathways to harvest atmospheric moisture by using the energy of natural gas are analyzed. A modeling framework is developed to quantify the dependence of water harvest rates on flared gas volumes and ambient weather. Flaring patterns in the Eagle Ford Shale in Texas and the Bakken Shale in North Dakota are analyzed to quantify the benefits of AWH. Overall, the gas currently flared annually in Texas and North Dakota can harvest enough water to meet 11% and 65% of the water consumption in the Eagle Ford and the Bakken, respectively. Daily harvests of upto 30 000 and 18 000 gallons water can be achieved using the gas currently flared per well in Texas and North Dakota, respectively. In fifty Bakken sites, the water required for fracturing or drilling a new well can be met via onsite flared gas-based AWH in only 3 weeks, and 3 days, respectively. The benefits of this concept are quantified for the Eagle Ford and Bakken Shales. Assessments of the global potential of this concept are presented using data from countries with high flaring activity. It is seen that this waste-to-value conversion concept offers significant economic benefits while addressing critical environmental issues pertaining to oil–gas production.

https://iopscience.iop.org/article/10.1088/1748-9326/11/3/034024/pdf

Enakshi Wikramanayake

Papers

Landfill gas-powered atmospheric water harvesting for oilfield operations in the United States

Electrowetting-based enhancement of droplet growth dynamics and heat transfer during humid air condensation

Modeling humid air condensation in waste natural gas-powered atmospheric water harvesting systems

Flared natural gas-based onsite atmospheric water harvesting (AWH) for oilfield operations

Statistical modeling of electrowetting-induced droplet coalescence for condensation applications