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Showing papers by "Enrique J. Baran published in 2012"


Journal ArticleDOI
TL;DR: The oxovanadium(IV) complex of oxodiacetic acid (H2ODA) and o-phenanthroline of stoichiometry [VO(ODA)(ophen)]⋅1.5H2O, which presents the interesting tridentate OOO coordination, was thoroughly characterized by infrared, Raman, and electronic spectroscopies.
Abstract: The oxovanadium(IV) complex of oxodiacetic acid (H2ODA) and o-phenanthroline of stoichiometry [VO(ODA)(ophen)]⋅1.5H2O, which presents the interesting tridentate OOO coordination, was thoroughly characterized by infrared, Raman, and electronic spectroscopies. The biological activity of the complex on the cell proliferation was tested on osteoblast-like cells (MC3T3E1 osteoblastic mouse calvaria-derived cells and UMR106 rat osteosarcoma-derived cells) in culture. The complex caused inhibition of cellular proliferation in both osteoblast cell lines in culture, but the cytotoxicity was stronger in the normal (MC3T3E1) than in the tumoral (UMR106) osteoblasts.

17 citations


Journal ArticleDOI
TL;DR: The FTIR and FT-Raman spectra of a Cu(II) complex of ornithine of composition of composition [Cu(L-ornithinato)(2)Cl(2)]·2H(2)O were recorded and analyzed in relation to its structural peculiarities and by comparison with theSpectra of Ornithine hydrochloride and of other bis(amino acid) complexes of Cu( II).