Increasing demand for fuels and chemicals, driven by factors including over-population, the threat of global warming and the scarcity of fossil resources, strains our resource system and necessitates the development of sustainable and innovative strategies for the chemical industry. Our society is currently experiencing constraints imposed by our resource system, which drives industry to increase its overall efficiency by improving existing processes or finding new uses for waste. Food supply chain waste emerged as a resource with a significant potential to be employed as a raw material for the production of fuels and chemicals given the abundant volumes globally generated, its contained diversity of functionalised chemical components and the opportunity to be utilised for higher value applications. The present manuscript is aimed to provide a general overview of the current and most innovative uses of food supply chain waste, providing a range of worldwide case-studies from around the globe. These studies will focus on examples illustrating the use of citrus peel, waste cooking oil and cashew shell nut liquid in countries such as China, the UK, Tanzania, Spain, Greece or Morocco. This work emphasises 2nd generation food waste valorisation and re-use strategies for the production of higher value and marketable products rather than conventional food waste processing (incineration for energy recovery, feed or composting) while highlighting issues linked to the use of food waste as a sustainable raw material. The influence of food regulations on food supply chain waste valorisation will also be addressed as well as our society's behavior towards food supply chain waste. “There was no ways of dealing with it that have not been known for thousands of years. These ways are essentially four: dumping it, burning it, converting it into something that can be used again, and minimizing the volume of material goods – future garbage – that is produced in the first place.” William Rathje on waste (1945–2012) – Director of the Tucson Garbage project.

Food waste as a valuable resource for the production of chemicals, materials and fuels. Current situation and global perspective

The recent energy independence and climate change policies encourage development and utilization of renewable energy such as bioenergy. Biofuels in solid, liquid, and gaseous forms have been intensively researched, produced, and used over the past 15 years. This paper reviews the worldwide history, current status, and predictable future trend of bioenergy and biofuels. Bioenergy has been utilized for cooking, heating, and lighting since the dawn of humans. The energy stored in annually produced biomass by terrestrial plants is 3–4 times greater than the current global energy demand. Solid biofuels include firewood, wood chips, wood pellets, and wood charcoal. The global consumption of firewood and charcoal has been remaining relatively constant, but the use of wood chips and wood pellets for electricity (biopower) generation and residential heating doubled in the past decade and will increase steadily into the future. Liquid biofuels cover bioethanol, biodiesel, pyrolysis bio-oil, and drop-in transportation fuels. Commercial production of bioethanol from lignocellulosic materials has just started, supplementing the annual supply of 22 billion gallons predominantly from food crops. Biodiesel from oil seeds reached the 5670 million gallons/yr production capacity, with further increases depending on new feedstock development. Bio-oil and drop-in biofuels are still in the development stage, facing cost-effective conversion and upgrading challenges. Gaseous biofuels extend to biogas and syngas. Production of biogas from organic wastes by anaerobic digestion has been rapidly increasing in Europe and China, with the potential to displace 25% of the current natural gas consumption. In comparison, production of syngas from gasification of woody biomass is not cost-competitive and therefore, narrowly practiced. Overall, the global development and utilization of bioenergy and biofuels will continue to increase, particularly in the biopower, lignocellulosic bioethanol, and biogas sectors. It is expected that by 2050 bioenergy will provide 30% of the world’s demanded energy.

Bioenergy and biofuels: History, status, and perspective

Review of the effects of biodiesel on NOx emissions

Due to the finite stock of fossil fuels and its negative impact on the environment, many countries across the world are now leaning toward renewable sources energies like solar energy, wind energy, biofuel, hydropower, geothermal and ocean energy to ensure energy for the countries development security. Biodiesel is one kind of biofuel that is renewable, biodegradable and has similar properties of fossil diesel fuel. The aim of this paper is to provide the substantial information on biodiesel to the researchers, engineers and policy makers. To achieve the goal, this paper summarizes the information on biofuel development, feedstocks around the world, oil extraction technic, biodiesel production processes. Furthermore, this paper will also discuss the advantages of biodiesel compared to fossil fuel. Finally, the combustion behavior of biodiesel in an internal combustion engine is discussed and it will help the researchers and policy maker and manufacturer. To determine the future and goal of automotive technology the study found that, feedstock selection for biodiesel production is very important as it associates 75% production cost. Moreover, the test of fuel properties is very important before using in the engine which depends on the type of feedstocks, origin country, and production process. Most of the researchers reported that the use of biodiesel in diesel engine reduces engine power slightly but reduces the harmful emission significantly. Finally, the study concludes that biodiesel has the potential to be used as a diesel fuel substitute in diesel engines to solve the energy and environment crisis.

Production, characterization and performance of biodiesel as an alternative fuel in diesel engines – A review

The quest for sustainable polyesters – insights into the future

Biodiesel is a renewable transportation fuel consisting of fatty acid methyl esters (FAME), generally produced by transesterification of vegetable oils and animal fats. In this review, the fatty acid (FA) profiles of 12 common biodiesel feedstocks were summarized. Considerable compositional variability exists across the range of feedstocks. For example, coconut, palm and tallow contain high amounts of saturated FA; while corn, rapeseed, safflower, soy, and sunflower are dominated by unsaturated FA. Much less information is available regarding the FA profiles of algal lipids that could serve as biodiesel feedstocks. However, some algal species contain considerably higher levels of poly-unsaturated FA than is typically found in vegetable oils. Differences in chemical and physical properties among biodiesel fuels can be explained largely by the fuels’ FA profiles. Two features that are especially influential are the size distribution and the degree of unsaturation within the FA structures. For the 12 biodiesel types reviewed here, it was shown that several fuel properties – including viscosity, specific gravity, cetane number, iodine value, and low temperature performance metrics – are highly correlated with the average unsaturation of the FAME profiles. Due to opposing effects of certain FAME structural features, it is not possible to define a single composition that is optimum with respect to all important fuel properties. However, to ensure satisfactory in-use performance with respect to low temperature operability and oxidative stability, biodiesel should contain relatively low concentrations of both long-chain saturated FAME and poly-unsaturated FAME.

Eric Ceniceros

Papers

Review of biodiesel composition, properties, and specifications

Effects of Biodiesel Fuels Upon Criteria Emissions