The solar chemical composition is an important ingredient in our understanding of the formation, structure, and evolution of both the Sun and our Solar System. Furthermore, it is an essential refer ...

The Chemical Composition of the Sun

A model for the photochemistry of the global troposphere constrained by observed concentrations of H2O, O3, CO, CH4, NO, NO2, and HNO3 is presented. Data for NO and NO2 are insufficient to define the global distribution of these gases but are nonetheless useful in limiting several of the more uncertain parameters of the model. Concentrations of OH, HO2, H2O2, NO, NO2, NO3, N2O5, HNO2, HO2NO2, CH3O2, CH3OOH, CH2O, and CH3CCl3 are calculated as functions of altitude, latitude, and season. Results imply that the source for nitrogen oxides in the remote troposphere is geographically dispersed and surprisingly small, less than 107 tons N yr−1. Global sources for CO and CH4 are 1.5 × 109 tons C yr−1 and 4.5 × 108 tons C yr−1, respectively. Carbon monoxide is derived from combustion of fossil fuel (15%) and oxidation of atmospheric CH4 (25%), with the balance from burning of vegetation and oxidation of biospheric hydrocarbons. Production of CO in the northern hemisphere exceeds that in the southern hemisphere by about a factor of 2. Industrial and agricultural activities provide approximately half the global source of CO. Oxidation of CO and CH4 provides sources of tropospheric O3 similar in magnitude to loss by in situ photochemistry. Observations of CH3CCl3 could offer an important check of the tropospheric model and results shown here suggest that computed concentrations of OH should be reliable within a factor of 2. A more definitive test requires better definition of release rates for CH3CCl3 and improved measurements for its distribution in the atmosphere.

/pdf/tropospheric-chemistry-a-global-perspective-29u7u1il4s.pdf

Tropospheric chemistry: A global perspective

We study a class of metric-variation $f(R)$ models that accelerates the expansion without a cosmological constant and satisfies both cosmological and solar-system tests in the small-field limit of the parameter space. Solar-system tests alone place only weak bounds on these models, since the additional scalar degree of freedom is locked to the high-curvature general-relativistic prediction across more than 25 orders of magnitude in density, out through the solar corona. This agreement requires that the galactic halo be of sufficient extent to maintain the galaxy at high curvature in the presence of the low-curvature cosmological background. If the galactic halo and local environment in $f(R)$ models do not have substantially deeper potentials than expected in $\ensuremath{\Lambda}\mathrm{CDM}$, then cosmological field amplitudes $|{f}_{R}|\ensuremath{\gtrsim}{10}^{\ensuremath{-}6}$ will cause the galactic interior to evolve to low curvature during the acceleration epoch. Viability of large-deviation models therefore rests on the structure and evolution of the galactic halo, requiring cosmological simulations of $f(R)$ models, and not directly on solar-system tests. Even small deviations that conservatively satisfy both galactic and solar-system constraints can still be tested by future, percent-level measurements of the linear power spectrum, while they remain undetectable to cosmological-distance measures. Although we illustrate these effects in a specific class of models, the requirements on $f(R)$ are phrased in a nearly model-independent manner.

/pdf/models-of-f-r-cosmic-acceleration-that-evade-solar-system-34tszjthua.pdf

Models of f(R) Cosmic Acceleration that Evade Solar-System Tests

Radiation forces on small particles in the solar system

We present an overview of solar flares and associated phenomena, drawing upon a wide range of observational data primarily from the RHESSI era Following an introductory discussion and overview of the status of observational capabilities, the article is split into topical sections which deal with different areas of flare phenomena (footpoints and ribbons, coronal sources, relationship to coronal mass ejections) and their interconnections We also discuss flare soft X-ray spectroscopy and the energetics of the process The emphasis is to describe the observations from multiple points of view, while bearing in mind the models that link them to each other and to theory The present theoretical and observational understanding of solar flares is far from complete, so we conclude with a brief discussion of models, and a list of missing but important observations

An Observational Overview of Solar Flares

The described investigation is concerned with the solution of the non-LTE optically thick transfer equations for hydrogen, carbon, and other constituents to determine semiempirical models for six components of the quiet solar chromosphere. For a given temperature-height distribution, the solution is obtained of the equations of statistical equilibrium, radiative transfer for lines and continua, and hydrostatic equilibrium to find the ionization and excitation conditions for each atomic constituent. The emergent spectrum is calculated, and a trial and error approach is used to adjust the temperature distribution so that the emergent spectrum is in best agreement with the observed one. The relationship between semiempirical models determined in this way and theoretical models based on radiative equilibrium is discussed by Avrett (1977). Harvard Skylab EUV observations are used to determine models for a number of quiet-sun regions.

Structure of the solar chromosphere. III. Models of the EUV brightness components of the quiet sun

Semiempirical model atmospheres are presented for the darkest parts of large sunspot umbrae, regions have called umbral cores. The approach is based on general-purpose computational procedures that are applicable to different types of stellar atmospheres. It is shown that recent umbral intensity measurements of the spectral energy distribution may be accounted for by an umbral core atmospheric model that varies with time during the solar cycle; the observed center-limb variation can be accounted for by the properties of the model. Three umbral core models are presented, corresponding to the early, middle, and late phases of the solar cycle. These three models also may be regarded as having the properties of dark, average, and bright umbral cores respectively. The effects of atomic, opacity, and abundance data uncertainties on the model calculations are briefly discussed. For comparison, a new reference model for the average quiet solar photosphere is given.

A new sunspot umbral model and its variation with the solar cycle

We present the results of optically thick non-LTE radiative transfer calculations of lines and continua of H, C I-IV, and O I-VI and other elements using a new one-dimensional, time-independent model corresponding to the average quiet-Sun chromosphere and transition region. The model is based principally on the Curdt et al. SUMER atlas of the extreme ultraviolet spectrum. Our model of the chromosphere is a semiempirical one, with the temperature distribution adjusted to obtain optimum agreement between calculated and observed continuum intensities, line intensities, and line profiles. Our model of the transition region is determined theoretically from a balance between (a) radiative losses and (b) the downward energy flow from the corona due to thermal conduction and particle diffusion, and using boundary conditions at the base of the transition region established at the top of the chromosphere from the semiempirical model. The quiet-Sun model presented here should be considered as a replacement of the earlier model C of Vernazza et al., since our new model is based on an energy-balance transition region, a better underlying photospheric model, a more extensive set of chromospheric observations, and improved calculations. The photospheric structure of the model given here is the same as in Table 3 of Fontenla, Avrett, Thuiller, & Harder. We show comparisons between calculated and observed continua, and between the calculated and observed profiles of all significant lines of H, C I-IV, and O I-VI in the wavelength range 67-173 nm. While some of the calculated lines are not in emission as observed, we find reasonable general agreement, given the uncertainties in atomic rates and cross sections, and we document the sources of the rates and cross sections used in the calculation. We anticipate that future improvements in the atomic data will give improved agreement with the observations.

https://iopscience.iop.org/article/10.1086/523671/pdf

Models of the Solar Chromosphere and Transition Region from SUMER and HRTS Observations: Formation of the Extreme-Ultraviolet Spectrum of Hydrogen, Carbon, and Oxygen

The paper presents a non-LTE empirical model of the quiet solar photosphere and the temperature-minimum region. The continuous spectrum computed from this model is in good overall agreement with available disk-center observations throughout the wavelength range from 0.125 to 500 microns. It is found that (1) absolute-intensity measurements are needed in the range between 1 and 2 microns to establish the structure of the deepest observable layers; (2) absolute-intensity or flux measurements are needed in the range between 20 and 200 microns to determine whether the minimum solar temperature occurring between the photosphere and the chromosphere is as low as indicated by present observations or much higher, as recent theoretical predictions indicate; (3) studies of the far-ultraviolet spectrum based on the assumption of LTE can be substantially in error; and (4) line opacity seems to account for the 'missing opacity' in the ultraviolet.

Structure of the solar chromosphere. II - The underlying photosphere and temperature-minimum region

A procedure is demonstrated that is used to compute a one-component model of the solar atmosphere, including in that model the photosphere, chromosphere, and chromosphere-corona transition zone. In particular, the equations are described that are solved in order to determine this theoretical model.

Eugene H. Avrett

Papers

Structure of the solar chromosphere. III. Models of the EUV brightness components of the quiet sun

A new sunspot umbral model and its variation with the solar cycle

Models of the Solar Chromosphere and Transition Region from SUMER and HRTS Observations: Formation of the Extreme-Ultraviolet Spectrum of Hydrogen, Carbon, and Oxygen

Structure of the solar chromosphere. II - The underlying photosphere and temperature-minimum region

Structure of the Solar Chromosphere. Basic Computations and Summary of the Results