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F. W. Mitchell

Bio: F. W. Mitchell is an academic researcher. The author has an hindex of 1, co-authored 1 publications receiving 190 citations.

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Journal ArticleDOI
TL;DR: Recent studies have illustrated the potential of PPEs for future applications beyond flame retardancy, and provided a coherent vision to implement this classic biopolymer in modern applications that demand biocompatibility and degradability as well as the possibility to adjust the properties to individual needs.
Abstract: Poly(phosphoester)s (PPEs) play an important role in nature. They structure and determine life in the form of deoxy- and ribonucleic acid (DNA and RNA), and, as pyrophosphates, they store up chemical energy in organisms. Polymer chemistry, however, is dominated by the nondegradable polyolefins and degradable poly(carboxylic ester)s (PCEs) that are produced on a large scale today. Recent studies have illustrated the potential of PPEs for future applications beyond flame retardancy, and provided a coherent vision to implement this classic biopolymer in modern applications that demand biocompatibility and degradability as well as the possibility to adjust the properties to individual needs.

176 citations

Journal ArticleDOI
TL;DR: In this article, a new method for the preparation of aromatic phosphonates by reaction of aryl halides with trialkyl phosphites in the presence of catalytic amounts of nickel chloride or bromide is described.
Abstract: Ein neues Verfahren zur Herstellung aromatischer Phosphonsaureester (1–25) durch Reaktion von Arylhalogeniden mit Trialkylphosphiten in Gegenwart katalytischer Mengen Nickel-chlorid oder -bromid wird beschrieben. Analog lassen sich aus Benzolphosphonigsaure-diathylester aromatische Phosphinsauren bzw. deren Ester (26–30) herstellen. Reaction of Aryl Halides with Trialkyl Phosphites and Dialkyl Benzenephosphonites to Aromatic Phosphonates and Phosphinates by Nickel Salt Catalysed Arylation A new method for the preparation of aromatic phosphonates (1–25) by reaction of aryl halides with trialkyl phosphites in the presence of catalytic amounts of nickel chloride or bromide is described. Similarly aromatic phosphinic acids and esters (26–30) are prepared from diethyl benzenephosphonites.

164 citations

Journal ArticleDOI
TL;DR: In this article, the synthesis and characterization of a series of molybdenum, iron, ruthenium, nickel, palladium, and platinum complexes containing new achiral and chiral PNP pincer-type ligands based on the N-heterocyclic diamines 2,6-diaminopyridine, N,N-di-10-undecenyl-2, 6-dimitrihexyl-1,3,5-triazine are reported.

150 citations

Journal ArticleDOI
TL;DR: Faix et al. as mentioned in this paper evaluated hydroxyl groups in Lignins using -9€-, 9€, 9 FTIR and Wet Chemical Methods and found that hydroxy groups in lignins are more stable than other groups.
Abstract: Determination of Hydroxyl Groups in Lignins Evaluation of -9€-, 9 FTIR and Wet Chemical Methods By Oskar Faix, Dimitris S. Argyropoulos, Danielle Robert and Vincent Neirinck Bundesforschungsanstalt für Forstund Holz Wirtschaft, Institut für Holzchemie und chemische Technologie des Holzes, Hamburg, Federal Republic of Germany Pulp and Paper Research Centre, McGill University, Montreal, Canada C.E.N.G., DRFMC, Service d'Etudes des Systemes Moleculaires, Grenoble, France

134 citations

Journal ArticleDOI
TL;DR: In this article, the authors present a method for identifying functional groups present in lignin and carbohydrate samples after phosphitylation with 1,3,2 dioxaphospholanyl chloride.
Abstract: Over the past few years substantial efforts in our laboratory have been devoted toward the development of novel NMR techniques for the analysis of soluble and solid lignocellulosic substances. These efforts were undertaken in order to expand the frontiers of application of NMR for the detection of functional groups present in such materials. Our methodology involves the selective phosphorus-tagging of a variety of functional groups present in lignin and carbohydrates, followed by solution and solid state31P NMR spectroscopies. This paper attempts to review the status of this technique by discussing its development for the analysis of soluble and solid lignocellulosic samples. Solution31P NMR can be used to examine soluble lignin and carbohydrate samples after phosphitylation with 1,3,2 dioxaphospholanyl chloride. This is a novel and powerful means to determine the three principal forms of phenolic hydroxyls present in ligninsi.e. p-hydroxyphenyl, guaiacyl, and syringyl structures. In addition, primary hydroxyls, carboxylic acids, and the two diastereomeric forms of arylglycerol-beta-aryl ether units (β-O-4 structures) present in lignins can also be determined from a single31P NMR experiment. When applied to carbohydrates, the technique gave characteristic signals for thealpha andbeta anomers and the epimeric forms of monosaccharides. Completely resolved31P NMR spectra were also obtained when lignin-carbohydrate model compounds were examined. Solid state31P NMR can be used to determine quinone chromophore groups present in solid lignocellulosic samples. The method is based on literature accounts that describe adduct formation between trimethyl phosphite and quinones followed by solid state31P NMR. This reaction when reexamined in our laboratory showed that the presence of carboxylic acids in high yield pulps significantly affected the solid state31P NMR signal intensity. This realization permitted the development of an experimental protocol that allowed solid state31P NMR signals to be received from high yield pulps that contain information only onortho-quinones and coniferaldehyde chromophores. It was thus found that about 0.7ortho-quinone groups are present in every 100 C9 units within the lignin of a black spruce refiner mechanical pulp sample, in agreement with previously applied independent techniques.

123 citations