Fátima Esteban-Betegón

Bio: Fátima Esteban-Betegón is an academic researcher from Spanish National Research Council. The author has contributed to research in topics: Laser & Ytterbium. The author has an hindex of 14, co-authored 30 publications receiving 954 citations.

Structural, spectroscopic, and tunable laser properties of Yb3+-doped NaGd(WO4)2

Abstract: the two nonequivalent 2b and 2d sites of the I4 ¯ structure, but Yb 3+ and Gd 3+ ions are found preferentially in the 2b site. Optical spectroscopy at low 5K temperature provides additional evidence of the existence of these two sites contributing to the line broadening. The comparison with the 2 F7/2n and 2 F5/2n Stark energy levels calculated using the crystallographic Yb-O bond distances allows to correlate the experimental optical bands with the 2b and 2d sites. As a novel uniaxial laser host for Yb 3+ , NaGdWO42 is characterized also with respect to its transparency, band-edge, refractive indices, and main optical phonons. Continuous-wave Yb 3+ -laser operation is studied at room temperature both under Ti:sapphire and diode laser pumping. A maximum slope efficiency of 77% with respect to the absorbed power is achieved for the polarization by Ti:sapphire laser pumping in a three-mirror cavity with Brewster geometry. The emission is tunable in the 1014– 1079 nm spectral range with an intracavity Lyot filter. Passive mode locking of this laser produces 120 fs long pulses at 1037.5 nm with an average power of 360 mW at 97 MHz repetition rate. Using uncoated samples of Yb: NaGdWO42 at normal incidence in simple two-mirror cavities, output powers as high as 1.45 W and slope efficiencies as high as 51% are achieved with different diode laser pump sources.

Tunable laser operation of ytterbium in disordered single crystals of Yb:NaGd(WO4)2.

Abstract: Lasing of Yb3+ in a disordered single crystal host, NaGd(WO4)2, is reported. Pump efficiencies as high as 20% and slope efficiencies as high as 30% are achieved for both σ- and π-polarizations with Ti:sapphire laser pumping. The emission of Yb:NaGd(WO4)2 is centered near 1030 nm. Tunability between 1016 and 1049 nm is obtained with a Lyot filter.

Growth and continuous-wave laser operation of disordered crystals of Yb3+:NaLa(WO4)2 and Yb3+:NaLa(MoO4)2

Abstract: We acknowledge financial support through Projects MAT2002-4605-C05-05 and CAM-MAT-434-2004 (Spain) and DT-CRYS, NMP3-CT-2003-505580 (EU).

Hydrothermal Yb3+-Doped NaGd(WO4)2 Nano- and Micrometer-Sized Crystals with Preserved Photoluminescence Properties

Abstract: Mild hydrothermal preparations using nitrate and chloride reagents as Gd3+ and Yb3+ sources lead to the synthesis of NaGd1−xYbx(WO4)2 (0001≤ x ≤ 05) particles with tetragonal scheelite-like structure phase Nearly neutral pH ∼75 conditions ensure the stability of this crystalline phase over a wide range of reaction times Synthetical routes with both kind of reagents yield basically the same particle morphology sequences, although using Gd(Yb)-chlorides the presence of nanorods is more evident, whereas using Gd(Yb)-nitrates the faster growth rate favors well-defined micrometer-sized octahedral particles The spectroscopic properties of Yb3+ in NaGd1−xYbx(WO4)2 synthesized micrometer-sized octahedra are equivalent to those obtained in bulk single crystals, showing a single exponential photoluminescence decay and 2F5/2 lifetime τ ≈ 330 μs for 0001 ≤ x ≤ 0005 doped samples The nanoparticles and nanorods formed with Gd(Yb)-nitrates and pH < 7 by short time annealing as well as in Gd(Yb)-chloride prepara

Flexible Nanodielectric Materials with High Permittivity for Power Energy Storage

Abstract: Study of flexible nanodielectric materials (FNDMs) with high permittivity is one of the most active academic research areas in advanced functional materials. FNDMs with excellent dielectric properties are demonstrated to show great promise as energy-storage dielectric layers in high-performance capacitors. These materials, in common, consist of nanoscale particles dispersed into a flexible polymer matrix so that both the physical/chemical characteristics of the nanoparticles and the interaction between the nanoparticles and the polymers have crucial effects on the microstructures and final properties. This review first outlines the crucial issues in the nanodielectric field and then focuses on recent remarkable research developments in the fabrication of FNDMs with special constitutents, molecular structures, and microstructures. Possible reasons for several persistent issues are analyzed and the general strategies to realize FNDMs with excellent integral properties are summarized. The review further highlights some exciting examples of these FNDMs for power-energy-storage applications.

Physical Properties of Composites Near Percolation

Abstract: Dramatic changes in the physical properties of composites occur when filler particles form a percolating network through the composite, particularly when the difference between the properties of the constitutive phases is large. By use of electric conductivity and dielectric properties as examples, recent studies on the physical properties of composites near percolation are reviewed. The effects of geometric factors and intrinsic properties of the fillers and the matrix, and especially of the interface between fillers and matrix, on electric and dielectric properties near percolation are discussed. Contact resistivity at the interface is less desirable for enhancing electrical conductivity. By contrast, an interface with high resistivity suppresses tunneling between adjacent fillers and leads to percolative composites with higher dielectric constant but lower dielectric loss. This review concludes with an outlook on the future possibilities and scientific challenges in the field.

High-k organic, inorganic, and hybrid dielectrics for low-voltage organic field-effect transistors.

Abstract: 2.2. Interface Trapping Effects 211 3. High-k Dielectric Materials for OFETs 212 3.1. Inorganic Dielectrics 212 3.1.1. Aluminum Oxide 213 3.1.2. Tantalum Oxide 215 3.1.3. Titanium Dioxide 216 3.1.4. Hafnium Dioxide 217 3.1.5. Zirconium Dioxide 218 3.1.6. Cerium Dioxide 218 3.2. Organic Dielectrics 218 3.2.1. Polymer Dielectrics 218 3.2.2. Self-Assembled Monoand Multilayers 225 3.3. Hybrid Dielectrics 227 3.3.1. Polymeric-Nanoparticle Composites 227 3.3.2. Inorganic-Organic Bilayers 232 3.3.3. Hybrid Solid Polymer Electrolytes 235 4. Summary 235 5. Acknowledgments 236 6. References 236

Plasmons in nearly touching metallic nanoparticles: singular response in the limit of touching dimers.

Abstract: The response of gold nanoparticle dimers is studied theoretically near and beyond the limit where the particles are touching. As the particles approach each other, a dominant dipole feature is observed that is pushed into the infrared due to interparticle coupling and that is associated with a large pileup of induced charge in the interparticle gap. The redshift becomes singular as the particle separation decreases. The response weakens for very small separation when the coupling across the interparticle gap becomes so strong that dipolar oscillations across the pair are inhibited. Lowerwavelength, higher-order modes show a similar separation dependence in nearly touching dimers. After touching, singular behavior is observed through the emergence of a new infrared absorption peak, also accompanied by huge charge pileup at the interparticle junction, if initial interparticle-contact is made at a single point. This new mode is distinctly different from the lowest mode of the separated dimer. When the junction is made by contact between flat surfaces, charge at the junction is neutralized and mode evolution is continuous through contact. The calculated singular response explains recent experiments on metallic nanoparticle dimers and is relevant in the design of nanoparticle-based sensors and plasmon circuits.