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Author

Frederick H. Rumpf

Bio: Frederick H. Rumpf is an academic researcher from Cabot Corporation. The author has contributed to research in topics: Elastomer & Filler (packaging). The author has an hindex of 8, co-authored 21 publications receiving 562 citations.

Papers
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Patent
25 Mar 1997
TL;DR: In this paper, continuous flow elastomer composites are produced by continuous flow methods and apparatus in which fluid streams of particulate filler and elastomers are fed to the mixing zone of a coagulum reactor to form a mixture in semi-confined flow continuously from the mixing zones through a co-agulum zone to a discharge end of the reactor.
Abstract: Elastomer composites are produced by novel continuous flow methods and apparatus in which fluid streams of particulate filler and elastomer latex are fed to the mixing zone of a coagulum reactor to form a mixture in semi-confined flow continuously from the mixing zone through a coagulum zone to a discharge end of the reactor. The particulate filler fluid is fed under high pressure to the mixing zone, such as to form a jet stream to entrain elastomer latex fluid sufficiently energetically to substantially completely coagulate the elastomer with the particulate filler prior to the discharge end. Highly efficient and effective elastomer coagulation is achieved without the need for a coagulation step involving exposure to acid or salt solution or the like. Novel elastomer composites are produced. Such novel elastomer composites may be cured or uncured, and combine material properties, such as choice of filler, elastomer, level of filler loading, and macro-dispersion, not previously achieved.

353 citations

Patent
25 Mar 1997
TL;DR: In this article, continuous flow elastomer composites are produced by continuous flow methods and apparatus in which fluid streams of particulate filler and elastomers are fed to the mixing zone of a coagulum reactor to form a mixture in semi-confined flow continuously from the mixing zones through a co-agulum zone to a discharge end of the reactor.
Abstract: Elastomer composites are produced by novel continuous flow methods and apparatus in which fluid streams of particulate filler and elastomer latex are fed to the mixing zone of a coagulum reactor to form a mixture in semi-confined flow continuously from the mixing zone through a coagulum zone to a discharge end of the reactor. The particulate filler fluid is fed under high pressure to the mixing zone, such as to form a jet stream to entrain elastomer latex fluid sufficiently energetically to substantially completely coagulate the elastomer with the particulate filler prior to the discharge end. Highly efficient and effective elastomer coagulation is achieved without the need for a coagulation step involving exposure to acid or salt solution or the like. Novel elastomer composites are produced. Such novel elastomer composites may be cured or uncured, and combine material properties, such as choice of filler, elastomer, level of filler loading, and macro-dispersion, not previously achieved.

80 citations

Patent
03 Dec 1999
TL;DR: In this paper, the off-gas from a carbon black furnace is employed as a combustion gas feed stream to the burner or combustion zone of the same or a different carbon black furnaces in accordance with certain embodiments.
Abstract: Off-gas from a carbon black furnace is employed as a combustion gas feed stream to the burner or combustion zone of the same or a different carbon black furnace in accordance with certain embodiments, suitable conduit and valving is provided to pass off-gas, from which carbon black has been substantially removed, from any and all of multiple different carbon black furnaces to the burner. The off-gas is heated, preferably by plasma heating, and dewatered. Carbon dioxide stripping or rather stripping of gas components from the dewatered heated off-gas is found to be unnecessary to achieve economically favorable use of off-gas recirculation.

44 citations

Patent
14 Sep 2011
TL;DR: In this article, an elastomer composite with silica-containing filler is described, along with methods to make the same, and the advantages achieved with the composite and methods are further described.
Abstract: An elastomer composite with silica-containing filler is described, along with methods to make the same. The advantages achieved with the elastomer composite and methods are further described.

17 citations

Patent
11 Aug 1994
TL;DR: In this article, the authors proposed cobalt and molybdenum promoted titania catalysts for converting sulfur in the form of carbon sulfides and nitrogen present as hydrogen cyanide to hydrogen sulfide and ammonia respectively.
Abstract: This invention relates to novel cobalt and molybdenum promoted titania and nickel and molybdenum promoted titania catalysts, and molybdenum promoted titania catalysts containing mixtures of cobalt and nickel. The invention also relates to a process for using the catalysts to convert sulfur in the form of carbon sulfides and nitrogen present as hydrogen cyanide to hydrogen sulfide and ammonia respectively. The catalysts and process of the present invention are effective even when oxygen in concentrations up to about 2 volume %, preferably 1.0 volume %, (dry basis) is present. The catalyst comprises about 0.5 to about 5%, by weight, cobalt oxide (CoO), nickel oxide (NiO), or mixtures thereof; about 1.5 to about 15%, by weight, molybdenum trioxide (MoO 3 ); and about 70 to about 98%, by weight, titanium dioxide (TiO 2 ).

14 citations


Cited by
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Patent
25 Mar 1997
TL;DR: In this paper, continuous flow elastomer composites are produced by continuous flow methods and apparatus in which fluid streams of particulate filler and elastomers are fed to the mixing zone of a coagulum reactor to form a mixture in semi-confined flow continuously from the mixing zones through a co-agulum zone to a discharge end of the reactor.
Abstract: Elastomer composites are produced by novel continuous flow methods and apparatus in which fluid streams of particulate filler and elastomer latex are fed to the mixing zone of a coagulum reactor to form a mixture in semi-confined flow continuously from the mixing zone through a coagulum zone to a discharge end of the reactor. The particulate filler fluid is fed under high pressure to the mixing zone, such as to form a jet stream to entrain elastomer latex fluid sufficiently energetically to substantially completely coagulate the elastomer with the particulate filler prior to the discharge end. Highly efficient and effective elastomer coagulation is achieved without the need for a coagulation step involving exposure to acid or salt solution or the like. Novel elastomer composites are produced. Such novel elastomer composites may be cured or uncured, and combine material properties, such as choice of filler, elastomer, level of filler loading, and macro-dispersion, not previously achieved.

353 citations

Patent
28 Sep 1998
TL;DR: In this article, a wet/dry mixing method and apparatus for elastomer composite blends is presented, where the mixture of elastomers and filler is fed to the mixing zone of a coagulum reactor to form a mixture in semi-confined flow.
Abstract: Elastomer composite blends are produced by novel wet/dry mixing methods and apparatus. In the wet mixing step or stage, fluid streams of particulate filler and elastomer latex are fed to the mixing zone of a coagulum reactor to form a mixture in semi-confined flow continuously from the mixing zone through a coagulum zone to a discharge end of the reactor. The particulate filler fluid is fed under high pressure to the mixing zone, such as to form a jet stream to entrain elastomer latex fluid sufficiently energetically to substantially completely coagulate the elastomer with the particulate filler prior to the discharge end. Highly efficient and effective elastomer coagulation is achieved without the need for a coagulation step involving exposure to acid or salt solution or the like. Elastomer composites are produced. Such elastomer composites may be cured or uncured, and combine material properties, such as choice of filler, elastomer, level of filler loading, and macro-dispersion, not previously achieved. The coagulum produced by such wet mixing step, with or without intermediate processing steps, is then mixed with additional elastomer in a dry mixing step or stage to form elastomer composite blends. The additional elastomer to the coagulum may be the same as or different from the elastomer(s) used in the wet mixing step.

327 citations

Patent
28 Mar 2012
TL;DR: In this paper, a rubber composition for tyres, consisting of at least a diene elastomer, an inorganic reinforcing filler, and a coupling agent linking the inorganic filler and the diene enamel, was described.
Abstract: The invention relates to a rubber composition for tyres, comprising at least a diene elastomer, an inorganic reinforcing filler, and a coupling agent linking the inorganic filler and the diene elastomer. The composition is characterised in that the coupling agent is an azo-silane compound having formula (I) (G1)3-a(G2)aSi-Z-NH-C(0)-N=N-C(0)-NH-Z-Si(G1)3-a(G2)a, wherein: - G1, which may be identical or different, each represent a monovalent hydrocarbon group selected from among optionally substituted, linear or branched alkyls having between 1 and 18 carbon atoms, cycloalkyls or aryls, optionally substituted, having between 5 and 18 carbon atoms; - G2, which may be identical or different, each represent a hydroxyl group or a monovalent group taking the form (G3)n-OG1, in which G3 is a divalent linking group comprising between 1 and 18 carbon atoms and containing one or more heteroatoms selected from among O, S, Si and N, and n is a number greater than or equal to 0 and less than or equal to 18; - Z represents a divalent linking group comprising between 1 and 18 carbon atoms; and - a is equal to 1, 2 or 3.

113 citations

Journal ArticleDOI
TL;DR: In this article, the historical role of plasmas in the gas-phase synthesis of carbon nanostructures and the present plasma technologies for industrial production purposes is reviewed and the advantages and disadvantages with respect to concurrent technologies commonly employed nowadays.
Abstract: Carbon nanostructures have received much attention for a wide range of applications. This paper reviews the historical role of plasmas in the gas-phase synthesis of carbon nanostructures and the present plasma technologies for industrial production purposes. It enumerates the advantages and disadvantages with respect to concurrent technologies commonly employed nowadays. Finally, some carbon nanostructures produced in our laboratory will serve as examples of the plasma processes potential.

91 citations

Patent
25 Mar 1997
TL;DR: In this article, continuous flow elastomer composites are produced by continuous flow methods and apparatus in which fluid streams of particulate filler and elastomers are fed to the mixing zone of a coagulum reactor to form a mixture in semi-confined flow continuously from the mixing zones through a co-agulum zone to a discharge end of the reactor.
Abstract: Elastomer composites are produced by novel continuous flow methods and apparatus in which fluid streams of particulate filler and elastomer latex are fed to the mixing zone of a coagulum reactor to form a mixture in semi-confined flow continuously from the mixing zone through a coagulum zone to a discharge end of the reactor. The particulate filler fluid is fed under high pressure to the mixing zone, such as to form a jet stream to entrain elastomer latex fluid sufficiently energetically to substantially completely coagulate the elastomer with the particulate filler prior to the discharge end. Highly efficient and effective elastomer coagulation is achieved without the need for a coagulation step involving exposure to acid or salt solution or the like. Novel elastomer composites are produced. Such novel elastomer composites may be cured or uncured, and combine material properties, such as choice of filler, elastomer, level of filler loading, and macro-dispersion, not previously achieved.

80 citations