Showing papers by "G. I. Nikishin published in 1962"
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4 citations
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TL;DR: Reaction, initiated by t-butyl peroxide, between normal primary alcohols and unsaturated alcohols with the double bond in the allyl position leads to 1,4-alkanediols, which forms 1∶1 adducts.
Abstract: 1.
Reaction, initiated by t-butyl peroxide, between normal primary alcohols and unsaturated alcohols with the double bond in the allyl position leads to 1,4-alkanediols.
2.
At molar proportions of saturated alcohol: allyl alcohol: peroxide of 20:1: 0.2–0.3, a reaction time of six hours, and a temperature of 160–170° the yields of 1∶1 adducts range from 50 to 60%.